温室气体 ,特别是 CO2 的排放和减排问题已经引起了国际社会的极大关注。分析并借鉴化肥生产工艺 ,用氨水喷淋火电站锅炉排烟烟气来吸收 CO2 ,不仅可以达到 CO2 减排的目的 ,还可以获得优质化肥。由于在高于 60℃的环境温度下碳酸氢铵...温室气体 ,特别是 CO2 的排放和减排问题已经引起了国际社会的极大关注。分析并借鉴化肥生产工艺 ,用氨水喷淋火电站锅炉排烟烟气来吸收 CO2 ,不仅可以达到 CO2 减排的目的 ,还可以获得优质化肥。由于在高于 60℃的环境温度下碳酸氢铵会分解为 NH+4和 HCO- 3 ,研究 HCO- 3 中重新返回大气的二氧化碳量是非常必要的 ,进而可以评估这种减排方法的应用价值。展开更多
Tremendous efforts have been devoted to explore energy-efficient strategies of ammonia synthesis to replace Haber-Bosch process which accounts for 1.4% of the annual energy consumption. In this study, atomically dispe...Tremendous efforts have been devoted to explore energy-efficient strategies of ammonia synthesis to replace Haber-Bosch process which accounts for 1.4% of the annual energy consumption. In this study, atomically dispersed Au_1 catalyst is synthesized and applied in electrochemical synthesis of ammonia under ambient conditions. A high NH＋4 Faradaic efficiency of 11.1 % achieved by our Au_1 catalyst surpasses most of reported catalysts under comparable conditions. Benefiting from efficient atom utilization, an NH＋4 yield rate of 1,305 μg h-1 mg-1Au has been reached, which is roughly 22.5 times as high as that by sup- ported Au nanoparticles. We also demonstrate that by employing our Au_1 catalyst, NH＋4 can be electro- chemically produced directly from N_2 and H_2 with an energy utilization rate of 4.02 mmol kJ-1. Our study provides a possibility of replacing the Haber-Bosch process with environmentally benign and energy-efficient electrochemical strategies.展开更多
Greenhouse experiments were conducted to determine the ammonia volatilization loss with or withoutapplication of surface film-forming material (SFFM). Ammonia volatilization loss was estimated by the modeldeveloped by...Greenhouse experiments were conducted to determine the ammonia volatilization loss with or withoutapplication of surface film-forming material (SFFM). Ammonia volatilization loss was estimated by the modeldeveloped by Jayaweera and Mikkelsen. The results showed that the model could estimate and predict wellammonia volatilization loss also in case of SFFM addition. There was an emended factor B introduced tothe model calculation when SFPM was used. Simulated calculation showed that the effect of factor B onNHa loss was obvious. The value of B was governed by SFFM and the environmental conditions. Sensitivityanalysis suggested that pH was the main factor coatrolling NH3 volatilization loss from the floodwater.展开更多
基金supported by the National Key R&D Program of China (2017YFA0208300)the National Natural Science Foundation of China (21522107, 21671180, 21521091, 21390393, U1463202, and 21522305)
文摘Tremendous efforts have been devoted to explore energy-efficient strategies of ammonia synthesis to replace Haber-Bosch process which accounts for 1.4% of the annual energy consumption. In this study, atomically dispersed Au_1 catalyst is synthesized and applied in electrochemical synthesis of ammonia under ambient conditions. A high NH＋4 Faradaic efficiency of 11.1 % achieved by our Au_1 catalyst surpasses most of reported catalysts under comparable conditions. Benefiting from efficient atom utilization, an NH＋4 yield rate of 1,305 μg h-1 mg-1Au has been reached, which is roughly 22.5 times as high as that by sup- ported Au nanoparticles. We also demonstrate that by employing our Au_1 catalyst, NH＋4 can be electro- chemically produced directly from N_2 and H_2 with an energy utilization rate of 4.02 mmol kJ-1. Our study provides a possibility of replacing the Haber-Bosch process with environmentally benign and energy-efficient electrochemical strategies.
文摘Greenhouse experiments were conducted to determine the ammonia volatilization loss with or withoutapplication of surface film-forming material (SFFM). Ammonia volatilization loss was estimated by the modeldeveloped by Jayaweera and Mikkelsen. The results showed that the model could estimate and predict wellammonia volatilization loss also in case of SFFM addition. There was an emended factor B introduced tothe model calculation when SFPM was used. Simulated calculation showed that the effect of factor B onNHa loss was obvious. The value of B was governed by SFFM and the environmental conditions. Sensitivityanalysis suggested that pH was the main factor coatrolling NH3 volatilization loss from the floodwater.
