In this study,we present the development of microtubular solid oxide fuel cells(MT-SOFC)with a two-layer cathode:a composite cathode functional layer(CFL)adjacent to the buffer layer(BL)and a cathode current-collectin...In this study,we present the development of microtubular solid oxide fuel cells(MT-SOFC)with a two-layer cathode:a composite cathode functional layer(CFL)adjacent to the buffer layer(BL)and a cathode current-collecting layer(CCCL).CFL consists of a mixture of BL material Ce_(0.9)Sm_(0.2)O_(1.95)(SDC)and perovskite Ba_(0.5)Sr_(0.5)Co_(0.75)Fe_(0.2)Mo_(0.05)O_(3-δ)(BSCFM5),which has a high exchange rate with oxygen.The widely used cathode material La_(0.6)Sr_(0.4)Co_(0.2)Fe_(0.8)O_(3-δ)(LSCF)with high electrical conductivity was used as the CCCL.A significant increase in the peak power density of the MT-SOFC to 1.2 W/cm^(2)at 850℃ was achieved using the proposed two-layer cathode.展开更多
A kind of ferrous particles Which are different from those of chemical deposit amongthe sediments of the dam seepage water at a certain reservoir in China has been observed.Their shapes show hollow tubes, Which perhap...A kind of ferrous particles Which are different from those of chemical deposit amongthe sediments of the dam seepage water at a certain reservoir in China has been observed.Their shapes show hollow tubes, Which perhaps are a kind of biogenic minerals. Thestructure, micrograph and chemical component of this sediment were studied withX-ray diffractometry, infra-red spectrometer, scanning electron microscope(SEM) and ana-lytical transmission electron microscope(AEM). It is determined to be a weakly-crystallinicamakinite.Discovering this tubular amakinite has a new significance in investigatinghypergene ferrogeochemistry, biomineralogy as well as safty and reliablity of rock-soil pro-ject.展开更多
A simple and cost-effective method has been developed for the fabrication of microtubular solid oxide fuel cells (MT-SOFCs). Highly asymmetric electrolyte hollow fibers composed of a thin dense skin layer and a thick ...A simple and cost-effective method has been developed for the fabrication of microtubular solid oxide fuel cells (MT-SOFCs). Highly asymmetric electrolyte hollow fibers composed of a thin dense skin layer and a thick porous substrate are first prepared by a modified phase inversion/sintering technique. The porous substrate is then formed into the anode by deposition of a Ni catalyst via an electroless plating method inside the pores while the thin dense skin layer serves directly as the electrolyte film of the fuel cells. A porous cathode layer is produced on the outer surface of the Ni-deposited hollow fibers by slurry coating and subsequent sintering to form a complete micro tubular fuel cell. The process has been employed to fabricate yttrium stabilized zirconia (YSZ) supported Ni-YSZ-YSZ-La0.6Sr0.4Co0.2Fe0.8O3-(LSCF) microtubular fuel cells. The maximum output of the resulting cells is 159.6 mW cm-2 at 800 °C when using H2 as the fuel feed and air as the oxidant.展开更多
The cortical ciliature microtubular organelles of the ciliated protozoan Euplotes Woodruffi were analyzed with FLUTAX and anti-a-tubulin antibody. It showed that the cortical cytoskeleton was composed of non-ciliature...The cortical ciliature microtubular organelles of the ciliated protozoan Euplotes Woodruffi were analyzed with FLUTAX and anti-a-tubulin antibody. It showed that the cortical cytoskeleton was composed of non-ciliature structure, ciliature structure including adoral zone of membranelles （AZM）, undulating membranes （UM）, frontal-ventral-transverse cirri （FVTC）, caudal cirri （CC）, dorsal kineties, as well as base-associated microtubules. The silverline system is composed of longitudinal and transverse microtubules, concave structure appeared on the cell dorsal side, the base of DK containing rosette-like skeleton structure. All these suggested that the non-ciliature structure, ciliature structure of Euplotes be quite different from that of other species of ciliate, the silverline-system be true pare of cortical microtubute cytoskeleton in Euplotes, rosette structure be part of the basecytoskeleton.展开更多
Microtubular metazoan fossils with multi- branches are found at least 4 times from the Sinian (Ediacarian) Doushantuo Formation at Weng’an, Guizhou, China. Their living mode should be the benthonic colony with higher...Microtubular metazoan fossils with multi- branches are found at least 4 times from the Sinian (Ediacarian) Doushantuo Formation at Weng’an, Guizhou, China. Their living mode should be the benthonic colony with higher ability of asexual re- production. The inner of the tube with cross-walls and chamber shows that these fossils are basal or stem- group cnidarians, similar to extinct tabulates. The multi-branching microtubular fossils are real meta- zoan found from Weng’an biota, which is very im- portant for studying the origin and evolvement of metazoan.展开更多
基金Foundation(project N◦21-79-30051)funded this project.
文摘In this study,we present the development of microtubular solid oxide fuel cells(MT-SOFC)with a two-layer cathode:a composite cathode functional layer(CFL)adjacent to the buffer layer(BL)and a cathode current-collecting layer(CCCL).CFL consists of a mixture of BL material Ce_(0.9)Sm_(0.2)O_(1.95)(SDC)and perovskite Ba_(0.5)Sr_(0.5)Co_(0.75)Fe_(0.2)Mo_(0.05)O_(3-δ)(BSCFM5),which has a high exchange rate with oxygen.The widely used cathode material La_(0.6)Sr_(0.4)Co_(0.2)Fe_(0.8)O_(3-δ)(LSCF)with high electrical conductivity was used as the CCCL.A significant increase in the peak power density of the MT-SOFC to 1.2 W/cm^(2)at 850℃ was achieved using the proposed two-layer cathode.
文摘A kind of ferrous particles Which are different from those of chemical deposit amongthe sediments of the dam seepage water at a certain reservoir in China has been observed.Their shapes show hollow tubes, Which perhaps are a kind of biogenic minerals. Thestructure, micrograph and chemical component of this sediment were studied withX-ray diffractometry, infra-red spectrometer, scanning electron microscope(SEM) and ana-lytical transmission electron microscope(AEM). It is determined to be a weakly-crystallinicamakinite.Discovering this tubular amakinite has a new significance in investigatinghypergene ferrogeochemistry, biomineralogy as well as safty and reliablity of rock-soil pro-ject.
基金supported by the National Natural Science Foundation of China (20676073)
文摘A simple and cost-effective method has been developed for the fabrication of microtubular solid oxide fuel cells (MT-SOFCs). Highly asymmetric electrolyte hollow fibers composed of a thin dense skin layer and a thick porous substrate are first prepared by a modified phase inversion/sintering technique. The porous substrate is then formed into the anode by deposition of a Ni catalyst via an electroless plating method inside the pores while the thin dense skin layer serves directly as the electrolyte film of the fuel cells. A porous cathode layer is produced on the outer surface of the Ni-deposited hollow fibers by slurry coating and subsequent sintering to form a complete micro tubular fuel cell. The process has been employed to fabricate yttrium stabilized zirconia (YSZ) supported Ni-YSZ-YSZ-La0.6Sr0.4Co0.2Fe0.8O3-(LSCF) microtubular fuel cells. The maximum output of the resulting cells is 159.6 mW cm-2 at 800 °C when using H2 as the fuel feed and air as the oxidant.
基金This study was supported by Natural Science Foundation of China （No. 30270160）.
文摘The cortical ciliature microtubular organelles of the ciliated protozoan Euplotes Woodruffi were analyzed with FLUTAX and anti-a-tubulin antibody. It showed that the cortical cytoskeleton was composed of non-ciliature structure, ciliature structure including adoral zone of membranelles （AZM）, undulating membranes （UM）, frontal-ventral-transverse cirri （FVTC）, caudal cirri （CC）, dorsal kineties, as well as base-associated microtubules. The silverline system is composed of longitudinal and transverse microtubules, concave structure appeared on the cell dorsal side, the base of DK containing rosette-like skeleton structure. All these suggested that the non-ciliature structure, ciliature structure of Euplotes be quite different from that of other species of ciliate, the silverline-system be true pare of cortical microtubute cytoskeleton in Euplotes, rosette structure be part of the basecytoskeleton.
基金supported by the National Natural Science Foundation of China(Grant No.440272015)the China Geology Survey(Grant No.1212010511607)0pen Laboratory of Chinese Academy of Geological Sciences(Grant No.KL05-4).
文摘Microtubular metazoan fossils with multi- branches are found at least 4 times from the Sinian (Ediacarian) Doushantuo Formation at Weng’an, Guizhou, China. Their living mode should be the benthonic colony with higher ability of asexual re- production. The inner of the tube with cross-walls and chamber shows that these fossils are basal or stem- group cnidarians, similar to extinct tabulates. The multi-branching microtubular fossils are real meta- zoan found from Weng’an biota, which is very im- portant for studying the origin and evolvement of metazoan.
