Iron ore microfines and concentrate have very limited uses in sintering processes. They are used in pelletization; however, this process is cost intensive. Furthermore, the microfines of non-coking coal and other carb...Iron ore microfines and concentrate have very limited uses in sintering processes. They are used in pelletization; however, this process is cost intensive. Furthermore, the microfines of non-coking coal and other carbon-bearing materials, e.g., blast-furnace flue dust （BFD） and coke frees, are not used extensively in the metallurgical industry because of operational difficu]ties and handling problems. In the present work, to utilize these microfines, coal composite iron oxide micropellets （2-6 mm in size） were produced through an innovative technique in which lime and molasses were used as binding materials in the micropellets. The micropellets were subsequently treated with CO2 or the industrial waste gas to induce the chemical bond formation. The results show that, at a very high carbon level of 22wt% （38wt% coal）, the cold crushing strength and abrasion index of the micropellets are 2.5-3 kg/cm2 and 5wt%-9wt%, respectively; these values indicate that the pellets are suitable for cold handling. The developed micropellets have strong potential as a heat source in smelting reduction in iron making and sintering to reduce coke breeze. The micropellets produced with BFD and coke fines （8wt%-12wt%） were used in iron ore sin- tering and were observed to reduce the coke breeze consumption by 3%-4%. The quality of the produced sinter was at par with that of the conventional blast-furnace sinter.展开更多
To better understand and assess the effect of microfines on concrete properties, the synergetic effect of methylene blue value and content of microfines on properties of low and high strength concrete was studied and ...To better understand and assess the effect of microfines on concrete properties, the synergetic effect of methylene blue value and content of microfines on properties of low and high strength concrete was studied and then the relationships between the index of modified methylene blue value （MMBV） and concrete properties were investigated. The results show that relationships between MMBV and fresh and hardened properties of concrete can be fully established, and the correlation between MMBV and C60 concrete property is higher than the correlation between MMBV and C30 concrete. With the increase of MMBV, concrete workability and frost resistance decrease while drying shrinkage decreases; however, compressive strength and chloride-ion penetration resistance of C30 concrete have not been negatively affected whereas those of C60 concrete are significantly deteriorated when MMBV exceeds 100. To make use of microfines without remarkably damaging concrete quality, it is suggested that MMBV of microfines in MS used in C30 and C60 concrete be no more than 100.展开更多
Construction industries have started to utilize manufactured sand(MS)as an effective alternative for river sand in concrete.High-grade parent rocks are crushed to obtain MS,which also produces a considerable amount of...Construction industries have started to utilize manufactured sand(MS)as an effective alternative for river sand in concrete.High-grade parent rocks are crushed to obtain MS,which also produces a considerable amount of microfine aggregate(MFA).The higher percentage of MFA could lead to both positive and negative effects on the performance of cement-based mixes.This research was done to examine the influence of varying MFA levels,specifically 0%,3%,6%,9%,and 12%(by weight)as the partial replacements of MS on bleeding and plastic shrinkage cracking of concrete.In addition to the varying MFA levels,some concrete mixes also included fly ash(FA)and superplasticizer to investigate the effect of free-water content in the mixes.The bleeding test data were taken as on-site measurements,while the cracks from the plastic shrinkage cracking test were evaluated using an image processing technique.The results concluded that the MFA replacements and the effective water-to-cement ratio have a significant effect on the selected concrete properties.With the increasing replacement levels,cumulative bleeding and crack initiation life gradually decreased,while a progressive increase was observed for crack width,crack length,and crack area.展开更多
The adsorption of sodium oleate(NaOL)at the microfine hematite/aqueous solution interface was investigated in this paper.Experimental research indicated that negative effects stemmed from the dissolution of the microf...The adsorption of sodium oleate(NaOL)at the microfine hematite/aqueous solution interface was investigated in this paper.Experimental research indicated that negative effects stemmed from the dissolution of the microfine hematite(D50=19.21μm)could be effectively eliminated via the appropriate dosage of NaOL at alkali pH conditions.Solution chemistry calculation and adsorption test results indicated that RCOOand(RCOO)_(2)^(2-) ions were responsible for microfine hematite flotation at pH 8.2.Zeta potential and FTIR measurements confirmed the co-adsorption of molecular and ionic oleate species occurred at pH 8.2.X-ray photoelectron spectroscopy(XPS)results further indicated that oleate species interacted with hematite surfaces mainly through chemisorption,giving rise to molecule/colloid formation of oleate and Fe―OL complex compound.Time-of-flight secondary ion mass spectrometry(ToF-SIMS)results demonstrated that oleate species adsorbed onto the hematite surfaces with a thickness of a few nanometers.Furthermore,the normalized peak intensity of C4H7+ions on the hematite sample at pH 8.2 increased remarkably comparing with corresponding result of hematite sample at pH 6.8.The new findings of the present study well revealed the dissolution of microfine hematite and the pH effects on the hematite flotation,as well as the adsorption characteristics of oleate species.展开更多
基金financially supported by the Ministry of Steel,Government of India
文摘Iron ore microfines and concentrate have very limited uses in sintering processes. They are used in pelletization; however, this process is cost intensive. Furthermore, the microfines of non-coking coal and other carbon-bearing materials, e.g., blast-furnace flue dust （BFD） and coke frees, are not used extensively in the metallurgical industry because of operational difficu]ties and handling problems. In the present work, to utilize these microfines, coal composite iron oxide micropellets （2-6 mm in size） were produced through an innovative technique in which lime and molasses were used as binding materials in the micropellets. The micropellets were subsequently treated with CO2 or the industrial waste gas to induce the chemical bond formation. The results show that, at a very high carbon level of 22wt% （38wt% coal）, the cold crushing strength and abrasion index of the micropellets are 2.5-3 kg/cm2 and 5wt%-9wt%, respectively; these values indicate that the pellets are suitable for cold handling. The developed micropellets have strong potential as a heat source in smelting reduction in iron making and sintering to reduce coke breeze. The micropellets produced with BFD and coke fines （8wt%-12wt%） were used in iron ore sin- tering and were observed to reduce the coke breeze consumption by 3%-4%. The quality of the produced sinter was at par with that of the conventional blast-furnace sinter.
基金Funded by National Natural Science Foundation of China(No.51372185)
文摘To better understand and assess the effect of microfines on concrete properties, the synergetic effect of methylene blue value and content of microfines on properties of low and high strength concrete was studied and then the relationships between the index of modified methylene blue value （MMBV） and concrete properties were investigated. The results show that relationships between MMBV and fresh and hardened properties of concrete can be fully established, and the correlation between MMBV and C60 concrete property is higher than the correlation between MMBV and C30 concrete. With the increase of MMBV, concrete workability and frost resistance decrease while drying shrinkage decreases; however, compressive strength and chloride-ion penetration resistance of C30 concrete have not been negatively affected whereas those of C60 concrete are significantly deteriorated when MMBV exceeds 100. To make use of microfines without remarkably damaging concrete quality, it is suggested that MMBV of microfines in MS used in C30 and C60 concrete be no more than 100.
基金The authors are grateful to INSEE Siam City,Sri Lanka for providing the necessary binding materials to conduct this study.Furthermore,the authors wish to thank all technical staffs of the Department of Civil Engineering,University of Sri Jayewardenepura for their support on the experimental work.
文摘Construction industries have started to utilize manufactured sand(MS)as an effective alternative for river sand in concrete.High-grade parent rocks are crushed to obtain MS,which also produces a considerable amount of microfine aggregate(MFA).The higher percentage of MFA could lead to both positive and negative effects on the performance of cement-based mixes.This research was done to examine the influence of varying MFA levels,specifically 0%,3%,6%,9%,and 12%(by weight)as the partial replacements of MS on bleeding and plastic shrinkage cracking of concrete.In addition to the varying MFA levels,some concrete mixes also included fly ash(FA)and superplasticizer to investigate the effect of free-water content in the mixes.The bleeding test data were taken as on-site measurements,while the cracks from the plastic shrinkage cracking test were evaluated using an image processing technique.The results concluded that the MFA replacements and the effective water-to-cement ratio have a significant effect on the selected concrete properties.With the increasing replacement levels,cumulative bleeding and crack initiation life gradually decreased,while a progressive increase was observed for crack width,crack length,and crack area.
基金supported by the Natural Science Foundation of China (No. 52164021)the Natural Science Foundation of Yunnan Province (No. 2019FB078)
文摘The adsorption of sodium oleate(NaOL)at the microfine hematite/aqueous solution interface was investigated in this paper.Experimental research indicated that negative effects stemmed from the dissolution of the microfine hematite(D50=19.21μm)could be effectively eliminated via the appropriate dosage of NaOL at alkali pH conditions.Solution chemistry calculation and adsorption test results indicated that RCOOand(RCOO)_(2)^(2-) ions were responsible for microfine hematite flotation at pH 8.2.Zeta potential and FTIR measurements confirmed the co-adsorption of molecular and ionic oleate species occurred at pH 8.2.X-ray photoelectron spectroscopy(XPS)results further indicated that oleate species interacted with hematite surfaces mainly through chemisorption,giving rise to molecule/colloid formation of oleate and Fe―OL complex compound.Time-of-flight secondary ion mass spectrometry(ToF-SIMS)results demonstrated that oleate species adsorbed onto the hematite surfaces with a thickness of a few nanometers.Furthermore,the normalized peak intensity of C4H7+ions on the hematite sample at pH 8.2 increased remarkably comparing with corresponding result of hematite sample at pH 6.8.The new findings of the present study well revealed the dissolution of microfine hematite and the pH effects on the hematite flotation,as well as the adsorption characteristics of oleate species.
