由于镁合金凝固温度区间很长,所以容易产生热裂。作为新型的高强度变形镁合金,Mg-Zn-Y(ZW系)合金在半连续铸造过程中极易发生热裂。采用"CRC"(Constrained Rod Casting)铸造热裂试验及冷却曲线热分析方法研究了ZW系中ZW22、Z...由于镁合金凝固温度区间很长,所以容易产生热裂。作为新型的高强度变形镁合金,Mg-Zn-Y(ZW系)合金在半连续铸造过程中极易发生热裂。采用"CRC"(Constrained Rod Casting)铸造热裂试验及冷却曲线热分析方法研究了ZW系中ZW22、ZW42、ZW44、ZW26、ZW62合金的凝固路径,凝固最后阶段剩余液相分数以及锆细化等因素和其热裂倾向的关系。热裂纹位置因子、宽度因子等热裂敏感性因子的表征结果表明,合金的热裂倾向从大到小顺序为:无Zr的ZW62>ZW62>ZW22,ZW42和ZW44>ZW26合金。无Zr的ZW62合金比其他合金具有更大热裂倾向与几方面因素有关:具有最长的凝固温度区间;从枝晶干涉点到凝固终了温度间形成W相,阻碍枝晶间剩余液体的流动性,不利于枝晶间补缩;最后凝固阶段剩余液相最少,且该阶段固相分数随温度降低增长缓慢;粗大组织和发达的枝晶。展开更多
The hot tearing susceptibility of MgZn2.5YxZr0.5 （x=0.5, 1, 2, 4, 6） alloys was evaluated by thermodynamic calculations based on Clyne-Davies model. The microstructure and morphology of hot tearing regions of the al...The hot tearing susceptibility of MgZn2.5YxZr0.5 （x=0.5, 1, 2, 4, 6） alloys was evaluated by thermodynamic calculations based on Clyne-Davies model. The microstructure and morphology of hot tearing regions of the alloys were observed by X-ray diffraction and scanning electron microscopy. The solidification temperature and shrinkage stress during the solidification of MgZn2.5YxZr0.5 alloys in the“T”type hot tearing permanent-mold were acquired with the attached computer. The effect factors of hot tearing susceptibility of MgZn2.5YxZr0.5 alloys, such as the solidification temperature interval, the variation of solid fraction in vulnerable region, the residual liquid fraction in the final stage, the type of the second phase of the alloys were discussed based on the above calculation and observation. The results demonstrated that the hot tearing susceptibility in the investigated alloys was found as follows：MgZn2.5Y2Zr0.5＆gt;MgZn2.5Y0.5Zr0.5＆gt;MgZn2.5Y4Zr0.5＆gt;MgZn2.5Y6Zr0.5＆gt;MgZn2.5Y1Zr0.5. The highest hot tearing susceptibility of MgZn2.5Y2Zr0.5 alloy related to the following reasons： the largest freezing range, the biggest changing of the variation of solid fraction in vulnerable region, the least liquid film in the final stage of solidification, the formation of the second phase which worsens the liquid flow and interdendritic feeding after dendrite coherency.展开更多
Machined chips of Mg-Zn-Y-Zr alloy were consolidated by cold pressing and then hot extrusion under various processing temperatures and extrusion ratios. The results show that the microstructure of the chip-extruded al...Machined chips of Mg-Zn-Y-Zr alloy were consolidated by cold pressing and then hot extrusion under various processing temperatures and extrusion ratios. The results show that the microstructure of the chip-extruded alloy is marked by a large number of recrystallized grains and some unrecrystallized grains, which results in high strength but low ductility at temperatures below 320 ℃. With increasing processing temperature up to 360 ℃, entirely recrystallized and equiaxed grains are obtained. Mg-Zn-Y-Zr alloy with low strength but high ductility is obtained compared with the alloy processed at low temperature. At 420℃, coarse and equiaxed grains are formed, which results in the drastic decrease of mechanical properties. With increasing extrusion ratio from 8 to 16, the grain refinement is more obvious and the mechanical properties at room temperature are improved effectively. However, the yield strength and ultimate tensile strength are improved a little with further increasing extrusion ratio.展开更多
文摘由于镁合金凝固温度区间很长,所以容易产生热裂。作为新型的高强度变形镁合金,Mg-Zn-Y(ZW系)合金在半连续铸造过程中极易发生热裂。采用"CRC"(Constrained Rod Casting)铸造热裂试验及冷却曲线热分析方法研究了ZW系中ZW22、ZW42、ZW44、ZW26、ZW62合金的凝固路径,凝固最后阶段剩余液相分数以及锆细化等因素和其热裂倾向的关系。热裂纹位置因子、宽度因子等热裂敏感性因子的表征结果表明,合金的热裂倾向从大到小顺序为:无Zr的ZW62>ZW62>ZW22,ZW42和ZW44>ZW26合金。无Zr的ZW62合金比其他合金具有更大热裂倾向与几方面因素有关:具有最长的凝固温度区间;从枝晶干涉点到凝固终了温度间形成W相,阻碍枝晶间剩余液体的流动性,不利于枝晶间补缩;最后凝固阶段剩余液相最少,且该阶段固相分数随温度降低增长缓慢;粗大组织和发达的枝晶。
基金Project (2011BAE22B01) supported by the National Key Technologies R&D Program,ChinaProject (2013CB632203) supported by the National Basic Research Program of China
文摘The hot tearing susceptibility of MgZn2.5YxZr0.5 （x=0.5, 1, 2, 4, 6） alloys was evaluated by thermodynamic calculations based on Clyne-Davies model. The microstructure and morphology of hot tearing regions of the alloys were observed by X-ray diffraction and scanning electron microscopy. The solidification temperature and shrinkage stress during the solidification of MgZn2.5YxZr0.5 alloys in the“T”type hot tearing permanent-mold were acquired with the attached computer. The effect factors of hot tearing susceptibility of MgZn2.5YxZr0.5 alloys, such as the solidification temperature interval, the variation of solid fraction in vulnerable region, the residual liquid fraction in the final stage, the type of the second phase of the alloys were discussed based on the above calculation and observation. The results demonstrated that the hot tearing susceptibility in the investigated alloys was found as follows：MgZn2.5Y2Zr0.5＆gt;MgZn2.5Y0.5Zr0.5＆gt;MgZn2.5Y4Zr0.5＆gt;MgZn2.5Y6Zr0.5＆gt;MgZn2.5Y1Zr0.5. The highest hot tearing susceptibility of MgZn2.5Y2Zr0.5 alloy related to the following reasons： the largest freezing range, the biggest changing of the variation of solid fraction in vulnerable region, the least liquid film in the final stage of solidification, the formation of the second phase which worsens the liquid flow and interdendritic feeding after dendrite coherency.
基金Project (51005217) supported by the National Natural Science Foundation of ChinaProject (20100480677) supported by China Postdoctoral Science Foundation
文摘Machined chips of Mg-Zn-Y-Zr alloy were consolidated by cold pressing and then hot extrusion under various processing temperatures and extrusion ratios. The results show that the microstructure of the chip-extruded alloy is marked by a large number of recrystallized grains and some unrecrystallized grains, which results in high strength but low ductility at temperatures below 320 ℃. With increasing processing temperature up to 360 ℃, entirely recrystallized and equiaxed grains are obtained. Mg-Zn-Y-Zr alloy with low strength but high ductility is obtained compared with the alloy processed at low temperature. At 420℃, coarse and equiaxed grains are formed, which results in the drastic decrease of mechanical properties. With increasing extrusion ratio from 8 to 16, the grain refinement is more obvious and the mechanical properties at room temperature are improved effectively. However, the yield strength and ultimate tensile strength are improved a little with further increasing extrusion ratio.
