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Evaluation of Influence of Multiple Scattering Effect in Light-Scattering-Based Applications
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作者 徐升华 孙祉伟 《Chinese Physics Letters》 SCIE CAS CSCD 2007年第6期1763-1766,共4页
The extinction cross sections of a system containing two particles are calculated by the T-matrix method, and the results are compared with those of two single particles with single-scattering approximation. The neces... The extinction cross sections of a system containing two particles are calculated by the T-matrix method, and the results are compared with those of two single particles with single-scattering approximation. The necessity of the correction of the refractive indices of water and polystyrene for different incident wavelengths is particularly addressed in the calculation. By this means, the volume fractions allowed for certain accuracy requirements of single-scattering approximation in the light scattering experiment can be evaluated. The volume fractions calculated with corrected refractive indices are compared with those obtained with fixed refractive indices which have been rather commonly used, showing that fixed refractive indices may cause significant error in evaluating multiple scattering effect. The results also give a simple criterion for selecting the incident wavelength and particle size to avoid the 'blind zone' in the turbidity measurement, where the turbidity change is insensitive to aggregation of two particles. 展开更多
关键词 T-MATRIX METHOD COLLOIDAL STABILITY TURBIDITY MEASUREMENT microscopicapproach RATE CONSTANTS COAGULATION INDEX
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