Commercial lithium-ion(Li-ion)batteries based on graphite anodes are meeting their bottlenecks that are limited energy densities.In order to satisfy the large market demands of smaller and lighter rechargeable batteri...Commercial lithium-ion(Li-ion)batteries based on graphite anodes are meeting their bottlenecks that are limited energy densities.In order to satisfy the large market demands of smaller and lighter rechargeable batteries,high-capacity metallic Li replacing low-specific-capacity graphite enables the higher energy density in next-generation rechargeable Li metal batteries(LMBs).However,Li metal anode has been suffering from dendritic problems,interfacial side reactions,volume change and low Coulombic efficiency.Therefore,performance enhancements of Li metal anodes are rather important to realize the high energy density characteristic of metallic Li.In this review,the annoying Li dendrite growth,unstable reaction interface and practical application issues of Li metal anodes are summarized and detailedly discussed to understand the current challenges concerning Li metal anodes.For overcoming such remaining challenges,the corresponding strategies and recent advances are covered and categorized.Finally,we discuss future opportunities and perspectives for developing high-performance Li metal anodes.展开更多
锂硫电池具有理论比容量高(1675 m Ah·g^(-1))、能量密度高(2600 Wh·kg^(-1))、环境友好、价格低廉等性质,是一种高性能的新型储能电池。这些性能使其在电动汽车和便携式设备领域具有重要意义。然而,快速的容量衰减以及较差...锂硫电池具有理论比容量高(1675 m Ah·g^(-1))、能量密度高(2600 Wh·kg^(-1))、环境友好、价格低廉等性质,是一种高性能的新型储能电池。这些性能使其在电动汽车和便携式设备领域具有重要意义。然而,快速的容量衰减以及较差的循环性能,使锂硫电池还达不到商业应用的要求。本文全面总结了锂硫电池的最新研究进展,详细阐述了锂硫电池的正极、电解质、隔膜以及负极保护,分析了现有锂硫电池存在的缺陷和问题。最后,对锂硫电池未来的发展方向进行了展望。展开更多
Lithium battery with high energy density and enhanced safety is undoubtedly the ideal choice for consumer electronics and electric vehicles.Metal anode such as lithium has been considered as the most effective way to ...Lithium battery with high energy density and enhanced safety is undoubtedly the ideal choice for consumer electronics and electric vehicles.Metal anode such as lithium has been considered as the most effective way to enhance the energy density as it provides ultra-high theoretical capacity and the lowest redox potential.However,due to the low coulombic efficiency as well as safety concerns originated from dendrite issue of lithium,its further commercial utilization is hindered.Dendrite growth is a common phenomenon in metal electrodeposition while the plating process of Li is more complicated than other metals for its high reactivity nature.As a matter of fact,the Li plating process is accompanied with the generation of solid electrolyte interphase(SEI)in which the electrolyte plays a vital role.In this paper,recent advances of electrolytes for Li protect application are reviewed,from liquid to gel polymer and solid state,on which we find that although tremendous progress has been accomplished,there are still great challenges before Li metal anode could be commercially used.展开更多
The application of cyclohexyl benzene(CHB)as the overcharge protection additive in lithium ion batteries was analyzed.Through 1C overcharge testing,battery performance testing, electrochemical impedance testing,electr...The application of cyclohexyl benzene(CHB)as the overcharge protection additive in lithium ion batteries was analyzed.Through 1C overcharge testing,battery performance testing, electrochemical impedance testing,electrolyte conductivity and self-discharge testing,the use of cyclohexyl benzene as the overcharge protection additive and the effect of cyclohexyl benzene on battery performance were investigated.The possible mechanism of cyclohexyl benzene as the overcharge protection addtive was discussed.When the content of cyclohexyl benzene was more than 5%(mass),the battery could be protected from explosion.When the content of the cyclohexyl benzene exceeded 7%(mass),a detrimental effect on battery performance was found.Cyclohexyl benzene could also decrease electrolyte conductivity,leading to increased self-discharge.The proper content of cyclohexyl benzene was between 5%(mass) and 7%(mass).展开更多
基金financially supported by the Innovation-Driven Project of Central South University(No.2019CX033)the National Natural Science Foundation of China(No:51904344)+2 种基金the Natural Science Foundation of Guangdong Province(2019A1515012111)the Science&Technology Innovation Commission of Shenzhen(Grant No.20180123)the Shenzhen Science and Technology Program(KQTD20180412181422399)。
文摘Commercial lithium-ion(Li-ion)batteries based on graphite anodes are meeting their bottlenecks that are limited energy densities.In order to satisfy the large market demands of smaller and lighter rechargeable batteries,high-capacity metallic Li replacing low-specific-capacity graphite enables the higher energy density in next-generation rechargeable Li metal batteries(LMBs).However,Li metal anode has been suffering from dendritic problems,interfacial side reactions,volume change and low Coulombic efficiency.Therefore,performance enhancements of Li metal anodes are rather important to realize the high energy density characteristic of metallic Li.In this review,the annoying Li dendrite growth,unstable reaction interface and practical application issues of Li metal anodes are summarized and detailedly discussed to understand the current challenges concerning Li metal anodes.For overcoming such remaining challenges,the corresponding strategies and recent advances are covered and categorized.Finally,we discuss future opportunities and perspectives for developing high-performance Li metal anodes.
文摘锂硫电池具有理论比容量高(1675 m Ah·g^(-1))、能量密度高(2600 Wh·kg^(-1))、环境友好、价格低廉等性质,是一种高性能的新型储能电池。这些性能使其在电动汽车和便携式设备领域具有重要意义。然而,快速的容量衰减以及较差的循环性能,使锂硫电池还达不到商业应用的要求。本文全面总结了锂硫电池的最新研究进展,详细阐述了锂硫电池的正极、电解质、隔膜以及负极保护,分析了现有锂硫电池存在的缺陷和问题。最后,对锂硫电池未来的发展方向进行了展望。
基金financially supported by the National Key Research and Development Program of China (No.2016YFB0100104)National Natural Science Foundation of China (No. 21706261 and No. 21706262)+1 种基金Beijing Natural Science Foundation (No. L172045)Beijing-Tianjin-Hebei Cooperative Innovation Community Construction Project (18244409D)
文摘Lithium battery with high energy density and enhanced safety is undoubtedly the ideal choice for consumer electronics and electric vehicles.Metal anode such as lithium has been considered as the most effective way to enhance the energy density as it provides ultra-high theoretical capacity and the lowest redox potential.However,due to the low coulombic efficiency as well as safety concerns originated from dendrite issue of lithium,its further commercial utilization is hindered.Dendrite growth is a common phenomenon in metal electrodeposition while the plating process of Li is more complicated than other metals for its high reactivity nature.As a matter of fact,the Li plating process is accompanied with the generation of solid electrolyte interphase(SEI)in which the electrolyte plays a vital role.In this paper,recent advances of electrolytes for Li protect application are reviewed,from liquid to gel polymer and solid state,on which we find that although tremendous progress has been accomplished,there are still great challenges before Li metal anode could be commercially used.
文摘The application of cyclohexyl benzene(CHB)as the overcharge protection additive in lithium ion batteries was analyzed.Through 1C overcharge testing,battery performance testing, electrochemical impedance testing,electrolyte conductivity and self-discharge testing,the use of cyclohexyl benzene as the overcharge protection additive and the effect of cyclohexyl benzene on battery performance were investigated.The possible mechanism of cyclohexyl benzene as the overcharge protection addtive was discussed.When the content of cyclohexyl benzene was more than 5%(mass),the battery could be protected from explosion.When the content of the cyclohexyl benzene exceeded 7%(mass),a detrimental effect on battery performance was found.Cyclohexyl benzene could also decrease electrolyte conductivity,leading to increased self-discharge.The proper content of cyclohexyl benzene was between 5%(mass) and 7%(mass).
