In a recent investigation Mills and Riaz [1] showed that industrial oxide refractory corrosion by liquid oxides could be changed by the application of a small voltage across the liquid oxide-refractory interface. They...In a recent investigation Mills and Riaz [1] showed that industrial oxide refractory corrosion by liquid oxides could be changed by the application of a small voltage across the liquid oxide-refractory interface. They explained their result in terms of penetration of the refractory pores with liquid oxide. Their analysis of the corrosion effect was to some degree limited by the use of an industrial refractory material in the study. Further, it was not clear whether their findings were limited to solely industrial refractories or had wider ranging application to more dense ceramic type solid oxide systems. In this study, a simpler and more easily characterized solid oxide (dense MgO) has been used to examine the effects of an applied voltage on the solid oxide in a liquid oxide melt. The dissolution rate of an MgO ceramic in a CaO-SiO2-Al2O3 and CaO-SiO2- Fe2O3-FeO-MgO liquid oxide composition at various applied voltages has been measured at 1540°C. It was found that the MgO corrosion in the CaO-SiO2-Al2O3 system was insensitive to an applied voltage over the voltage range –0.5 to 0.3 V. In the CaO-SiO2-Fe2O3-FeO-MgO liquid oxide system the MgO corrosion rate showed a maximum at –0.45 V. This effect has been explained by considering the consequences of an applied voltage on the rate of Marangoni flow at the liquid oxide-refractory-gas interface and in turn, the flow effect on the rate of the mass transfer controlled MgO dissolution reaction.展开更多
An effective procedure has been developed to synthesize the functionalized graphene oxide grafted by maleic anhydride grafted liquid polybutadiene（MLPB-GO）. Fourier transform spectroscopy and X-ray photoelectron spe...An effective procedure has been developed to synthesize the functionalized graphene oxide grafted by maleic anhydride grafted liquid polybutadiene（MLPB-GO）. Fourier transform spectroscopy and X-ray photoelectron spectroscopy indicate the successful functionalization of GO. The NR/MLPB-GO composites were then prepared by the co-coagulation process. The results show that the mechanical properties of NR/MLPB-GO composites are obviously superior to those of NR/GO composites and neat NR. Compared with neat NR, the tensile strength, modulus at 300% strain and tear strength of NR composite containing 2.12 phr MLPB-GO are significantly increased by 40.5%, 109.1% and 85.0%, respectively. Dynamic mechanical analysis results show that 84% increase in storage modulus and 2.9 K enhancement in the glass transition temperature of the composite have been achieved with the incorporation of 2.12 phr MLPB-GO into NR. The good dispersion of GO and the strong interface interaction in the composites are responsible for the unprecedented reinforcing efficiency of MLPB-GO towards NR.展开更多
文摘In a recent investigation Mills and Riaz [1] showed that industrial oxide refractory corrosion by liquid oxides could be changed by the application of a small voltage across the liquid oxide-refractory interface. They explained their result in terms of penetration of the refractory pores with liquid oxide. Their analysis of the corrosion effect was to some degree limited by the use of an industrial refractory material in the study. Further, it was not clear whether their findings were limited to solely industrial refractories or had wider ranging application to more dense ceramic type solid oxide systems. In this study, a simpler and more easily characterized solid oxide (dense MgO) has been used to examine the effects of an applied voltage on the solid oxide in a liquid oxide melt. The dissolution rate of an MgO ceramic in a CaO-SiO2-Al2O3 and CaO-SiO2- Fe2O3-FeO-MgO liquid oxide composition at various applied voltages has been measured at 1540°C. It was found that the MgO corrosion in the CaO-SiO2-Al2O3 system was insensitive to an applied voltage over the voltage range –0.5 to 0.3 V. In the CaO-SiO2-Fe2O3-FeO-MgO liquid oxide system the MgO corrosion rate showed a maximum at –0.45 V. This effect has been explained by considering the consequences of an applied voltage on the rate of Marangoni flow at the liquid oxide-refractory-gas interface and in turn, the flow effect on the rate of the mass transfer controlled MgO dissolution reaction.
基金financially supported by the National Natural Science Foundation of China(No.51363006)Science and Technology innovation key project of Hainan province(No.ZDXM20120090)National Science and Technology support project(No.2013BAF08B02)
文摘An effective procedure has been developed to synthesize the functionalized graphene oxide grafted by maleic anhydride grafted liquid polybutadiene（MLPB-GO）. Fourier transform spectroscopy and X-ray photoelectron spectroscopy indicate the successful functionalization of GO. The NR/MLPB-GO composites were then prepared by the co-coagulation process. The results show that the mechanical properties of NR/MLPB-GO composites are obviously superior to those of NR/GO composites and neat NR. Compared with neat NR, the tensile strength, modulus at 300% strain and tear strength of NR composite containing 2.12 phr MLPB-GO are significantly increased by 40.5%, 109.1% and 85.0%, respectively. Dynamic mechanical analysis results show that 84% increase in storage modulus and 2.9 K enhancement in the glass transition temperature of the composite have been achieved with the incorporation of 2.12 phr MLPB-GO into NR. The good dispersion of GO and the strong interface interaction in the composites are responsible for the unprecedented reinforcing efficiency of MLPB-GO towards NR.
