The microstructures and mechanical properties of Al-3.35Cu-1.2Li-0.4Mg-0.4Zn-0.3Mn-0.1Zr （mass fraction, %） alloywith Sc addition or free Sc were investigated through tensile test, SEM, EPMA and TEM. The addition of...The microstructures and mechanical properties of Al-3.35Cu-1.2Li-0.4Mg-0.4Zn-0.3Mn-0.1Zr （mass fraction, %） alloywith Sc addition or free Sc were investigated through tensile test, SEM, EPMA and TEM. The addition of 0.082% （mass fraction） Scelement leads to the formation of Cu-rich and Sc-contained nano-sized Al3（ScZr） particles and W phase particles. The Al3（ScZr）particles can inhibit recrystallization to a certain extent and impede recrystallized grain growth during solution treatment. It is foundthat W phase cannot dissolve in supersaturated solid solution during the solution heat treatment, and the Cu content in thesolutionized matrix is decreased, which causes a decrease in the fraction of Cu-contained strengthening precipitates with T1 （Al2CuLi）and θ＇ （Al2Cu） under T8 aging condition. Due to the formation of the W phases, the small Sc addition causes a little reduction in thestrength.展开更多
The effect of Li(2.0 wt%)addition on mechanical properties and ageing precipitation behavior of Al-3.0 Mg 0.5 Si was investigated by tensile test,dynamic elasticity modulus test,scanning electron microscopy(SEM),trans...The effect of Li(2.0 wt%)addition on mechanical properties and ageing precipitation behavior of Al-3.0 Mg 0.5 Si was investigated by tensile test,dynamic elasticity modulus test,scanning electron microscopy(SEM),transmission electron microscopy(TEM)and high-resolution transmission electron microscopy(HRTEM)images.The results show that the tensile strength of the Li-containing alloy can be significantly improved;however,the ductility is sharply decreased and the fracture mechanism changes from ductile fracture to intergranular fracture.The elasticity modulus of the Li-containing alloy increases by 11.6%compared with the base alloy.The microstructure observation shows that the Li addition can absolutely change the precipitation behavior of the base alloy,andδ′-Al_(3)Li phase becomes the main precipitates.Besides,β′′-Mg_(2)Si andδ′-Al_(3)Li dual phases precipitation can be visibly observed at 170℃ ageing for 100 h,although the quantity ofδ′-Al_(3)Li phase is more thanβ′′-Mg_(2)Si phase.The width of the precipitate-free zone(PFZ)of the Li-containing alloy is much wider at the over-ageing state than the base alloy,which has a negative impact on the ductile and results in the decrease of elongation.展开更多
Effects of Li addition (2%, 5%, 8% and 11%) on microstructure and mechanical properties of the as-cast and as-extruded Mg?6Al?2Sn?0.4Mn-based alloys were investigated. Mg?xLi?6Al?2Sn?0.4Mn (x= 2, 5, 8 and 11, mass fra...Effects of Li addition (2%, 5%, 8% and 11%) on microstructure and mechanical properties of the as-cast and as-extruded Mg?6Al?2Sn?0.4Mn-based alloys were investigated. Mg?xLi?6Al?2Sn?0.4Mn (x= 2, 5, 8 and 11, mass fraction, %) alloys were cast under an SF6 and CO2 atmosphere at 700 °C. After homogenization heat treatment at 350 °C, cast billets were extruded with a reduction ratio of 40:1 at 200 °C. Li addition to Mg?6Al?2Sn?0.4Mn resulted in the formation of MgSnLi2 and MgAlLi2 and/or AlLi intermetallic compounds and random basal texture. With increasing Li addition,β-Li phase was increased and the average area fraction of precipitates increased. Compression yield strength was increased from 212 to 235, 242 and 239 MPa as Li content was increased from 2% to 5%, 8% and 11%, respectively. Elongation was remarkably increased above 60% in 11% Li alloy. It is probable that Li-containing phases play a significant role in the enhanced mechanical properties by Li addition.展开更多
In the present work,the microstructural characteristics and mechanical properties of Al-1.5 Mg-0.6Si and Al-3.0 Mg-0.6Si alloy containing 3 wt%Li were investigated by optical microscopy(OM),X-ray diffraction analysis(...In the present work,the microstructural characteristics and mechanical properties of Al-1.5 Mg-0.6Si and Al-3.0 Mg-0.6Si alloy containing 3 wt%Li were investigated by optical microscopy(OM),X-ray diffraction analysis(XRD),scanning electron microscopy(SEM),time of flight-secondary ion mass spectrometry(SIMS),transmission electron microscopy(TEM),and mechanical performance testing.The addition of Li reduces the density of the base alloy by up to 8.4%.The residual second phases contain Mg and Si in the hot-rolled condition,but the Mg/Si atomic ratio decreases after quenching,which means that Li substitute some of the Mg and convert Mg_(2)Si into a(Mg,Li)_(2)Si phase during solution treatment.The results of SIMS observations confirm this.The high Mg-containing alloy has a more rapid hardening response compared to the low Mg-containing alloy.TEM observation reveals that theδ′-Al3Li+β′′-Mg_(2)Si dual phases can be observed in the high Mg-containing alloy after aging for 100 h at 170°C.The higher Mg content enhances the precipitation of theδ′phase,which results in the high Mg-containing alloy having a larger average diameter size ofδ′particles and widerδ′-precipitate-free zones(δ′-PFZs).The mechanical properties are significantly improved with the elastic modulus increasing by more than 16.5%.However,the existence of large second phases and wideδ′-PFZs in Li-containing alloys is detrimental to their ductility;as a result,their elongation is much lower than that of the base alloy.展开更多
In order to develop high-performance diamond wheels,the vitrified bond with different contents of Li2O addition and corresponding diamond composites were prepared.The experimental results show that the addition of a s...In order to develop high-performance diamond wheels,the vitrified bond with different contents of Li2O addition and corresponding diamond composites were prepared.The experimental results show that the addition of a small content of Li2O leads the formation of the mullite phase in vitrified bond.When the Li2O content is 3wt%,the mullite content in the vitrified bond reaches the maximum.Whereas,the vitrified bond turns into a pure glass phase when the Li2O content further increases to 5wt%.The softening temperature of vitrified bond,wetting angle between the vitrified bond and the diamond film decrease with the increasing of the Li2O content.The softening point of the vitrified bond with 5wt% Li2O is 537 ℃ and the contact angle is 32°,which are 44 ℃ and 44° lower than those of the sample without Li2O.The CTE (coefficient of thermal expansion),the flexural strength and hardness of the diamond composite sample first increase and then decrease with the increasing of the Li2O content.When the Li2O addition is 3wt%,the flexural strength and hardness of the composites reaches the maximum values of 93 MPa and 98 HRB,respectively,which are 43.1% and 12.6% higher than those of the sample without Li2O.展开更多
The interaction between atoms, molecules and solid surface is an important research topic in the field of heterogeneous catalysis, gas erosion, separation and crystal growth. Theoretical study on a molecular level can...The interaction between atoms, molecules and solid surface is an important research topic in the field of heterogeneous catalysis, gas erosion, separation and crystal growth. Theoretical study on a molecular level can not only help people understand the interaction mech-展开更多
利用Gleeble-3800热模拟试验机进行热变形实验,开展含钪2099铝-锂合金的热变形行为研究。研究表明:在热变形初期,随着应变量的增加,流变应力呈急剧上升的趋势。在应变量为0.06左右时,合金在各变形条件下的流变应力均达到峰值;当应变量...利用Gleeble-3800热模拟试验机进行热变形实验,开展含钪2099铝-锂合金的热变形行为研究。研究表明:在热变形初期,随着应变量的增加,流变应力呈急剧上升的趋势。在应变量为0.06左右时,合金在各变形条件下的流变应力均达到峰值;当应变量继续增加时,合金的流变应力开始出现不同程度的下降。ln[sinh(ασ)]与lnε·以及ln[sinh(ασ)]与1/T之间满足线性关系,其平均热变形激活能为182.451 k J/mol,合金热压缩变形时的流变应力方程为ε·=2.05×10^(16)[sinh(0.01752σ)]^(6.542)exp(-182451/RT)。在变形温度为400℃,应变速率为1 s^(-1)条件下,合金组织中存在大量的位错墙;随着应变速率的降低,当应变速率为0.01 s^(-1)时,合金内部可以观察到少量动态再结晶组织。展开更多
The behavior of growth and coarsening of T-1(Al2CuLi) precipitates was comparatively studied by means of TEM technique in two Al-Li alloys 2090 and 2090+Ce (with cerium content less than 0.1% in mass fraction). Statis...The behavior of growth and coarsening of T-1(Al2CuLi) precipitates was comparatively studied by means of TEM technique in two Al-Li alloys 2090 and 2090+Ce (with cerium content less than 0.1% in mass fraction). Statistical analysis results show that T-1 precipitates in alloy 2090+Ce have smaller aspect ratio, which is connected with the more intersections between different T-1 variants in this alloy. It is also found that the variation of maximum length of T-1 precipitates with aging time can be obviously divided into two stages of growth and coarsening. The diffusion coefficients of solute atoms of Cu and Li are calculated via growth kinetics curves of T-1 precipitates. The results show that the diffusion of atom Cu plays a more important role in the formation of T-1 precipitates.展开更多
文摘The microstructures and mechanical properties of Al-3.35Cu-1.2Li-0.4Mg-0.4Zn-0.3Mn-0.1Zr （mass fraction, %） alloywith Sc addition or free Sc were investigated through tensile test, SEM, EPMA and TEM. The addition of 0.082% （mass fraction） Scelement leads to the formation of Cu-rich and Sc-contained nano-sized Al3（ScZr） particles and W phase particles. The Al3（ScZr）particles can inhibit recrystallization to a certain extent and impede recrystallized grain growth during solution treatment. It is foundthat W phase cannot dissolve in supersaturated solid solution during the solution heat treatment, and the Cu content in thesolutionized matrix is decreased, which causes a decrease in the fraction of Cu-contained strengthening precipitates with T1 （Al2CuLi）and θ＇ （Al2Cu） under T8 aging condition. Due to the formation of the W phases, the small Sc addition causes a little reduction in thestrength.
基金Project(2016YFB0300802)supported by the National Key Research and Development Program of China。
文摘The effect of Li(2.0 wt%)addition on mechanical properties and ageing precipitation behavior of Al-3.0 Mg 0.5 Si was investigated by tensile test,dynamic elasticity modulus test,scanning electron microscopy(SEM),transmission electron microscopy(TEM)and high-resolution transmission electron microscopy(HRTEM)images.The results show that the tensile strength of the Li-containing alloy can be significantly improved;however,the ductility is sharply decreased and the fracture mechanism changes from ductile fracture to intergranular fracture.The elasticity modulus of the Li-containing alloy increases by 11.6%compared with the base alloy.The microstructure observation shows that the Li addition can absolutely change the precipitation behavior of the base alloy,andδ′-Al_(3)Li phase becomes the main precipitates.Besides,β′′-Mg_(2)Si andδ′-Al_(3)Li dual phases precipitation can be visibly observed at 170℃ ageing for 100 h,although the quantity ofδ′-Al_(3)Li phase is more thanβ′′-Mg_(2)Si phase.The width of the precipitate-free zone(PFZ)of the Li-containing alloy is much wider at the over-ageing state than the base alloy,which has a negative impact on the ductile and results in the decrease of elongation.
文摘Effects of Li addition (2%, 5%, 8% and 11%) on microstructure and mechanical properties of the as-cast and as-extruded Mg?6Al?2Sn?0.4Mn-based alloys were investigated. Mg?xLi?6Al?2Sn?0.4Mn (x= 2, 5, 8 and 11, mass fraction, %) alloys were cast under an SF6 and CO2 atmosphere at 700 °C. After homogenization heat treatment at 350 °C, cast billets were extruded with a reduction ratio of 40:1 at 200 °C. Li addition to Mg?6Al?2Sn?0.4Mn resulted in the formation of MgSnLi2 and MgAlLi2 and/or AlLi intermetallic compounds and random basal texture. With increasing Li addition,β-Li phase was increased and the average area fraction of precipitates increased. Compression yield strength was increased from 212 to 235, 242 and 239 MPa as Li content was increased from 2% to 5%, 8% and 11%, respectively. Elongation was remarkably increased above 60% in 11% Li alloy. It is probable that Li-containing phases play a significant role in the enhanced mechanical properties by Li addition.
基金This work was financially supported by the National Key Research and Development Program of China(No.2016YFB0300802).
文摘In the present work,the microstructural characteristics and mechanical properties of Al-1.5 Mg-0.6Si and Al-3.0 Mg-0.6Si alloy containing 3 wt%Li were investigated by optical microscopy(OM),X-ray diffraction analysis(XRD),scanning electron microscopy(SEM),time of flight-secondary ion mass spectrometry(SIMS),transmission electron microscopy(TEM),and mechanical performance testing.The addition of Li reduces the density of the base alloy by up to 8.4%.The residual second phases contain Mg and Si in the hot-rolled condition,but the Mg/Si atomic ratio decreases after quenching,which means that Li substitute some of the Mg and convert Mg_(2)Si into a(Mg,Li)_(2)Si phase during solution treatment.The results of SIMS observations confirm this.The high Mg-containing alloy has a more rapid hardening response compared to the low Mg-containing alloy.TEM observation reveals that theδ′-Al3Li+β′′-Mg_(2)Si dual phases can be observed in the high Mg-containing alloy after aging for 100 h at 170°C.The higher Mg content enhances the precipitation of theδ′phase,which results in the high Mg-containing alloy having a larger average diameter size ofδ′particles and widerδ′-precipitate-free zones(δ′-PFZs).The mechanical properties are significantly improved with the elastic modulus increasing by more than 16.5%.However,the existence of large second phases and wideδ′-PFZs in Li-containing alloys is detrimental to their ductility;as a result,their elongation is much lower than that of the base alloy.
基金Funded by the Zhejiang Provincial Key Research and Development Project(No.2018C01076)。
文摘In order to develop high-performance diamond wheels,the vitrified bond with different contents of Li2O addition and corresponding diamond composites were prepared.The experimental results show that the addition of a small content of Li2O leads the formation of the mullite phase in vitrified bond.When the Li2O content is 3wt%,the mullite content in the vitrified bond reaches the maximum.Whereas,the vitrified bond turns into a pure glass phase when the Li2O content further increases to 5wt%.The softening temperature of vitrified bond,wetting angle between the vitrified bond and the diamond film decrease with the increasing of the Li2O content.The softening point of the vitrified bond with 5wt% Li2O is 537 ℃ and the contact angle is 32°,which are 44 ℃ and 44° lower than those of the sample without Li2O.The CTE (coefficient of thermal expansion),the flexural strength and hardness of the diamond composite sample first increase and then decrease with the increasing of the Li2O content.When the Li2O addition is 3wt%,the flexural strength and hardness of the composites reaches the maximum values of 93 MPa and 98 HRB,respectively,which are 43.1% and 12.6% higher than those of the sample without Li2O.
文摘The interaction between atoms, molecules and solid surface is an important research topic in the field of heterogeneous catalysis, gas erosion, separation and crystal growth. Theoretical study on a molecular level can not only help people understand the interaction mech-
文摘利用Gleeble-3800热模拟试验机进行热变形实验,开展含钪2099铝-锂合金的热变形行为研究。研究表明:在热变形初期,随着应变量的增加,流变应力呈急剧上升的趋势。在应变量为0.06左右时,合金在各变形条件下的流变应力均达到峰值;当应变量继续增加时,合金的流变应力开始出现不同程度的下降。ln[sinh(ασ)]与lnε·以及ln[sinh(ασ)]与1/T之间满足线性关系,其平均热变形激活能为182.451 k J/mol,合金热压缩变形时的流变应力方程为ε·=2.05×10^(16)[sinh(0.01752σ)]^(6.542)exp(-182451/RT)。在变形温度为400℃,应变速率为1 s^(-1)条件下,合金组织中存在大量的位错墙;随着应变速率的降低,当应变速率为0.01 s^(-1)时,合金内部可以观察到少量动态再结晶组织。
文摘The behavior of growth and coarsening of T-1(Al2CuLi) precipitates was comparatively studied by means of TEM technique in two Al-Li alloys 2090 and 2090+Ce (with cerium content less than 0.1% in mass fraction). Statistical analysis results show that T-1 precipitates in alloy 2090+Ce have smaller aspect ratio, which is connected with the more intersections between different T-1 variants in this alloy. It is also found that the variation of maximum length of T-1 precipitates with aging time can be obviously divided into two stages of growth and coarsening. The diffusion coefficients of solute atoms of Cu and Li are calculated via growth kinetics curves of T-1 precipitates. The results show that the diffusion of atom Cu plays a more important role in the formation of T-1 precipitates.
