This review article compiles the recent achievements made in layered rare-earth (RE) hydroxide (LRH), including controlled crystallization, structural and morphological features, anion exchange, nanosheet exfoliation,...This review article compiles the recent achievements made in layered rare-earth (RE) hydroxide (LRH), including controlled crystallization, structural and morphological features, anion exchange, nanosheet exfoliation, and application in the field of luminescence for both the Ln2(OH)5(Ax-)1/x·nH2O (251-LRH) and Ln2(OH)4(Ax-)2/x·nH2O (241-LRH) phases. The luminescent properties of the LRHs themselves, the oxide, oxysulfate, and oxysulfide phosphors derived from the LRHs via controlled calcination, and the highly oriented transparent phosphor films of enhanced luminescence and/or novel emission features are summarized.展开更多
基金This work was supported in part by the National Natural Science Foundation of China,the Fundamental Research Funds for the Central Universities
文摘This review article compiles the recent achievements made in layered rare-earth (RE) hydroxide (LRH), including controlled crystallization, structural and morphological features, anion exchange, nanosheet exfoliation, and application in the field of luminescence for both the Ln2(OH)5(Ax-)1/x·nH2O (251-LRH) and Ln2(OH)4(Ax-)2/x·nH2O (241-LRH) phases. The luminescent properties of the LRHs themselves, the oxide, oxysulfate, and oxysulfide phosphors derived from the LRHs via controlled calcination, and the highly oriented transparent phosphor films of enhanced luminescence and/or novel emission features are summarized.