The author studied the grain size, shape, colour, altered coat, mineral species, chemical composition,end- member components and infrared spectra of clinopyroxenes occurring as megacryst, macrocryst andgroundmass mine...The author studied the grain size, shape, colour, altered coat, mineral species, chemical composition,end- member components and infrared spectra of clinopyroxenes occurring as megacryst, macrocryst andgroundmass minerals, intergrowths with pyrope and ilmenite and minerals in deep-seated xenoliths and inclu-sions in diamonds in kimberlites of China. The clinopyroxenes under study were compared with megacrystclinopyroxenes in basalts and minerals in their deep-seated xenoliths and clinopyroxenes in lamproites andminettes. The coexisting clinopyroxene-pyrope pair was studied. Besides the author also studied the origin ofclinopyroxenes in kimberlites, P-T conditions for their formation and their reflected tectonic environments ofthe kimberlite formation. He suggests that this mineral is an indicator for diamond exploration.展开更多
Mantle xenoliths(>150) and concentrates from late autolithic breccia and porphyritic kimberlite from the Sytykanskaya pipe of the Alakit field(Yakutia) were analyzed by EPMA and LAM ICP methods.In P-TX-f(O2) ...Mantle xenoliths(>150) and concentrates from late autolithic breccia and porphyritic kimberlite from the Sytykanskaya pipe of the Alakit field(Yakutia) were analyzed by EPMA and LAM ICP methods.In P-TX-f(O2) diagrams minerals from xenoliths show widest variations,the trends P-Fe#-CaO,f(O2)for minerals from porphyric kimberlites are more stepped than for xenocrysts from breccia.Ilmenite PTX points mark moving for protokimberlites from the lithosphere base(7.5 GPa) to pyroxenite lens(5-3.5 GPa) accompanied by Cr increase by AFC and creation of two trends P-Fe#OI10-12%and13-15%.The Opx-Gar-based mantle geotherm in Alakit field is close to 35 mW/m2 at 65 GPa and 600 C near Moho was determined.The oxidation state for the megacrystalline ilmenites is lower for the metasomatic associations due to reduction of protokimberlites on peridotites than for uncontaminated varieties at the lithosphere base.Highly inclined linear REE patterns with deep HFSE troughs for the parental melts of clinopyroxene and garnet xenocrysts from breccia were influenced by differentiated protokimberlite.Melts for metasomatic xenoliths reveal less inclined slopes without deep troughs in spider diagrams.Garnets reveal S-shaped REE patterns.The clinopyroxenes from graphite bearing Cr-websterites show inclined and inflected in Gd spectrums with LREE variations due to AFC differentiation.Melts for garnets display less inclined patterns and Ba-Sr troughs but enrichment in Nb-Ta-U.The40Ar/39Ar ages for micas from the Alakit mantle xenoliths for disseminated phlogopites reveal Proterozoic(1154 Ma) age of metasomatism in early Rodinia mantle.Veined glimmerites with richterite- like amphiboles mark1015 Ma plume event in Rodinia mantle.The600-550 Ma stage manifests final Rodinia break-up.The last 385 Ma metasomatism is protokimberlite-related.展开更多
Post-Neoproterozoic dolerites from the Kéniéba region (Western Mali) are often associated with kimberlites. The rarity of kimberlite outcrops led to the study of doleritic rocks, spatially associated with th...Post-Neoproterozoic dolerites from the Kéniéba region (Western Mali) are often associated with kimberlites. The rarity of kimberlite outcrops led to the study of doleritic rocks, spatially associated with them. The petrographic and lithogeochemical study showed that the dolerites of the Kéniéba kimberlitic fields are of tholeiitic nature and of the E-MORB (Enriched-Mid Ocean Ridge Basalt) type. This reflects an enrichment over time, compared to the Birimian dolerites of the volcano-sedimentary greenstone belt of Toumodi, in central C?te d’Ivoire. Furthermore, these dolerites are enriched in SiO2, TiO2, Zr and poor in Fe2O3, MgO. These dolerites would have formed in a late to post-orogenic intracontinental context during the breakup of Gondwana. Structurally, Kéniéba dolerites are often associated with kimberlite pipes, fractures and large deep structures identified using aeromagnetic images. Taking into account the fact that kimberlites do not outcrop in the Kéniéba region, the geochemical study coupled with the interpretation of aeromagnetic data proved to be very useful for the search for pipes.展开更多
Utility of geochemistry in mineral exploration is known since more than half-a-century.In reconnaissance diamond exploration,regolith geochemistry is a well known tool worldwide and helps in distinguishing bedrock
文摘The author studied the grain size, shape, colour, altered coat, mineral species, chemical composition,end- member components and infrared spectra of clinopyroxenes occurring as megacryst, macrocryst andgroundmass minerals, intergrowths with pyrope and ilmenite and minerals in deep-seated xenoliths and inclu-sions in diamonds in kimberlites of China. The clinopyroxenes under study were compared with megacrystclinopyroxenes in basalts and minerals in their deep-seated xenoliths and clinopyroxenes in lamproites andminettes. The coexisting clinopyroxene-pyrope pair was studied. Besides the author also studied the origin ofclinopyroxenes in kimberlites, P-T conditions for their formation and their reflected tectonic environments ofthe kimberlite formation. He suggests that this mineral is an indicator for diamond exploration.
基金supported by RBRF grants 05-05-64718,03-05-64146,08-05-00524,11-05-00060,11-05-91060-PICSjointresearch projects of IGM SB RAS and ALROSA Stock Company 77-2,65-03,02-05,grant of the President of Russia MK-3240.2014.5
文摘Mantle xenoliths(>150) and concentrates from late autolithic breccia and porphyritic kimberlite from the Sytykanskaya pipe of the Alakit field(Yakutia) were analyzed by EPMA and LAM ICP methods.In P-TX-f(O2) diagrams minerals from xenoliths show widest variations,the trends P-Fe#-CaO,f(O2)for minerals from porphyric kimberlites are more stepped than for xenocrysts from breccia.Ilmenite PTX points mark moving for protokimberlites from the lithosphere base(7.5 GPa) to pyroxenite lens(5-3.5 GPa) accompanied by Cr increase by AFC and creation of two trends P-Fe#OI10-12%and13-15%.The Opx-Gar-based mantle geotherm in Alakit field is close to 35 mW/m2 at 65 GPa and 600 C near Moho was determined.The oxidation state for the megacrystalline ilmenites is lower for the metasomatic associations due to reduction of protokimberlites on peridotites than for uncontaminated varieties at the lithosphere base.Highly inclined linear REE patterns with deep HFSE troughs for the parental melts of clinopyroxene and garnet xenocrysts from breccia were influenced by differentiated protokimberlite.Melts for metasomatic xenoliths reveal less inclined slopes without deep troughs in spider diagrams.Garnets reveal S-shaped REE patterns.The clinopyroxenes from graphite bearing Cr-websterites show inclined and inflected in Gd spectrums with LREE variations due to AFC differentiation.Melts for garnets display less inclined patterns and Ba-Sr troughs but enrichment in Nb-Ta-U.The40Ar/39Ar ages for micas from the Alakit mantle xenoliths for disseminated phlogopites reveal Proterozoic(1154 Ma) age of metasomatism in early Rodinia mantle.Veined glimmerites with richterite- like amphiboles mark1015 Ma plume event in Rodinia mantle.The600-550 Ma stage manifests final Rodinia break-up.The last 385 Ma metasomatism is protokimberlite-related.
文摘Post-Neoproterozoic dolerites from the Kéniéba region (Western Mali) are often associated with kimberlites. The rarity of kimberlite outcrops led to the study of doleritic rocks, spatially associated with them. The petrographic and lithogeochemical study showed that the dolerites of the Kéniéba kimberlitic fields are of tholeiitic nature and of the E-MORB (Enriched-Mid Ocean Ridge Basalt) type. This reflects an enrichment over time, compared to the Birimian dolerites of the volcano-sedimentary greenstone belt of Toumodi, in central C?te d’Ivoire. Furthermore, these dolerites are enriched in SiO2, TiO2, Zr and poor in Fe2O3, MgO. These dolerites would have formed in a late to post-orogenic intracontinental context during the breakup of Gondwana. Structurally, Kéniéba dolerites are often associated with kimberlite pipes, fractures and large deep structures identified using aeromagnetic images. Taking into account the fact that kimberlites do not outcrop in the Kéniéba region, the geochemical study coupled with the interpretation of aeromagnetic data proved to be very useful for the search for pipes.
文摘Utility of geochemistry in mineral exploration is known since more than half-a-century.In reconnaissance diamond exploration,regolith geochemistry is a well known tool worldwide and helps in distinguishing bedrock