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Study on Tribological Properties of Irradiated Crosslinking UHMWPE Nano-Composite 被引量:15
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作者 Lei Xiong, Dang-sheng Xiong, Jia-bo JinDepartment of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094, P. R. China 《Journal of Bionic Engineering》 SCIE EI CSCD 2009年第1期7-13,共7页
Ultra High Molecular Weight Polyethylene(UHMWPE)has been widely used as a bearing material for artificial joint replacement over forty years.It is usually crosslinked by gamma rays irradiation before its implantation ... Ultra High Molecular Weight Polyethylene(UHMWPE)has been widely used as a bearing material for artificial joint replacement over forty years.It is usually crosslinked by gamma rays irradiation before its implantation into human body.In this study,UHMWPE and UHMWPE/nano-hydroxyapatite(n-HA)composite were prepared by vacuum hot-pressing method.The prepared materials were irradiated by gamma rays in vacuum and molten heat treated in vacuum just after irradiation.The effect of filling n-HA with gamma irradiation on tribological properties of UHMWPE was investigated by using friction and wear experimental machine(model MM-200)under deionized water lubrication.Micro-morphology of worn surface was observed by metallographic microscope.Contact angle and hardness of the materials were also measured.The results show that contact angle and hardness are changed by filling n-HA and gamma irradiation.Friction coefficient and wear rate under deionized water lubrication are reduced by filling n-HA.While friction coefficient is increased and wear rate is reduced significantly by gamma irradiation.The worn surface of unfilled material is mainly characterized as adhesive wear and abrasive wear,and that of n-HA filled material is mainly characterized as abrasive wear.After gamma irradiation,the degrees of adhesive and abrasive wear for unfilled material and abrasive wear of n-HA filled material are significantly reduced.Unfilled and filled materials after irradiation are mainly shown as slight fatigue wear.The results indicate that UHMWPE and UHMWPE/n-HA irradiated at the dose of 150 kGy can be used as bearing materials in artificial joints for its excellent wear resistance compared to original UHMWPE. 展开更多
关键词 tribological properties irradiated crosslinking UHMWPE n-HA artificial joints
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可辐照交联聚乙烯热收缩管专用料的研制 被引量:4
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作者 祝景云 李敬泽 +4 位作者 甄建 陈文淑 丁艳芬 郑梅梅 苏一凡 《合成树脂及塑料》 EI CAS 1998年第3期10-13,23,共5页
通过对辐照剂量及热塑性弹性体、交联敏化剂等用量的选择,研制出性能符合辐照交联热收缩管专用料技术指标的聚乙烯料。
关键词 辐照交联 聚乙烯 热收缩 管材
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辐照交联热收缩套管的制作及其应用 被引量:7
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作者 蔡鹤琴 符素兰 唐彬 《现代塑料加工应用》 CAS 1995年第1期40-42,共3页
叙述了制作辐照交联热收缩套管的基本原理、工艺和技术要点,介绍了这种新型塑料制品在各方面的应用。
关键词 低密度聚乙烯 辐照交联 热收缩管 塑料管 聚乙烯
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聚乙二醇20M的辐射交联及其固定化毛细色谱柱研究
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作者 周应才 康星武 +2 位作者 郭辉 李华 汪秀英 《辐射研究与辐射工艺学报》 CAS CSCD 北大核心 1990年第4期244-247,共4页
从聚乙二醇20M(PEG 20M)的辐射交联基础研究入手,利用所获得的结果移植到以其作固定相的毛细管柱的制备。从PEG 20M的分子量测定、红外光谱及其辐解产物的分析中推出PEG 20 M的基本交联反应和它的凝胶化剂量、交联G值,从而确定在不加任... 从聚乙二醇20M(PEG 20M)的辐射交联基础研究入手,利用所获得的结果移植到以其作固定相的毛细管柱的制备。从PEG 20M的分子量测定、红外光谱及其辐解产物的分析中推出PEG 20 M的基本交联反应和它的凝胶化剂量、交联G值,从而确定在不加任何添加剂的情况下,制备性能优良的PEG 20 M毛细柱的最适工艺条件。 展开更多
关键词 辐照交联 聚乙二醇 固定化 毛细柱
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紫外光辐照交联对超高相对分子质量聚乙烯纤维结构和性能的影响 被引量:15
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作者 陈自力 于俊荣 +1 位作者 刘兆峰 谈冠红 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2001年第3期62-65,共4页
在光敏剂和交联剂存在下 ,用紫外光进行辐照引发对超高相对分子质量聚乙烯 (UHMWPE)纤维进行交联改性。从纤维凝胶含量、力学性能、耐热性、蠕变性、粘结性能、红外光谱及扫描电镜 (SEM)等测试分析得知 ,UHMWPE纤维的性能和结构发生了... 在光敏剂和交联剂存在下 ,用紫外光进行辐照引发对超高相对分子质量聚乙烯 (UHMWPE)纤维进行交联改性。从纤维凝胶含量、力学性能、耐热性、蠕变性、粘结性能、红外光谱及扫描电镜 (SEM)等测试分析得知 ,UHMWPE纤维的性能和结构发生了重要变化 ,其耐热性和抗蠕变性能有了明显的提高。纤维的表面粘结性能得到了改善 ,同时 。 展开更多
关键词 超高相对分子质量 聚乙烯纤维 紫外光 辐照交联 耐热性 蠕变性 粘结性能
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辐射交联度对聚乙烯发泡材料性能的影响 被引量:7
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作者 王伟 王鹏飞 +2 位作者 杨小兵 武建平 卞志勇 《现代塑料加工应用》 CAS 北大核心 2013年第3期28-31,共4页
探索了辐射剂量对聚乙烯发泡材料的影响,并对辐射交联聚乙烯(IXPE)发泡材料的泡孔形态、力学性能等进行了分析。结果表明,在现有的工艺条件下辐射剂量为17 Hz时,能够制得发泡均匀、力学性能优异并可稳定连续生产的IXPE。
关键词 辐射交联 聚乙烯 交联度 发泡倍率 力学性能
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