Molecular electrocatalysts have demonstrated potential for the hydrogen evolution reaction(HER)due to their well-defined structures and high intrinsic activities.Achieving rapid production of hydrogen requires molecul...Molecular electrocatalysts have demonstrated potential for the hydrogen evolution reaction(HER)due to their well-defined structures and high intrinsic activities.Achieving rapid production of hydrogen requires molecular electrocatalysts to operate at high current densities,which still presents a challenge.In this work,we demonstrate that molecularly dispersed electrocatalysts of cobalt phthalocyanine anchored on carbon nanotubes(CoPc MDEs)are superior candidates due to the efficient charge transport between the substrate and the active site.The intrinsic activity can be enhanced by introducing functional groups on phthalocyanine.To facilitate mass transport,di(ethylene glycol)substituted CoPc molecules are further anchored on a threedimensional self-supported electrode(CoPc-DEG MDE@CC),enabling continuous operation for 25 h at−1000 mA/cm^(2)in 1.0 M KOH.Our study demonstrates the potential of molecular electrocatalysts for HER and emphasizes the importance of adjusting intrinsic activity,and charge and mass transport capacity for practical molecular electrocatalysts.展开更多
The quantum field theory (QFT) is one of branches of the Standard Model. According to QFT, quantum fields are the primary entities and particles are the excitations of these fields, coming in discrete lumps with no in...The quantum field theory (QFT) is one of branches of the Standard Model. According to QFT, quantum fields are the primary entities and particles are the excitations of these fields, coming in discrete lumps with no inner structures and with properties assigned by declaration. Such view is in conflict with the observed vacuum energy density, 140 orders of magnitudes less than required by the QFT. In addition, such view is challenged by Aphysical Quantum Mechanics (AQM), a deeper quantum theory. According to AQM, the fundamental understanding of quantum reality is expanded by the addition of two fundamental categories, aphysical and elementary consciousness of elementary particles. Based on AQM and as an example, the total ontology of the intrinsic (fundamental) electron is presented with its inner structure of perfect geometry consisting of the physical charged c-ring and aphysical cylinder, and with its properties such as self-mass, spin, magneto-electrostatic field configuration and magnetic moment. The position parameter in the inner structure demonstrates that there are no two identical intrinsic electrons in the Universe thus placing a question mark over the QFT principle of indistinguishability.展开更多
A new interpretation of the relativistic equation relating total-, momentum-, and mass-energies is presented. With the aid of the familiar energy-relationship triangle, old and new interpretations are compared. And th...A new interpretation of the relativistic equation relating total-, momentum-, and mass-energies is presented. With the aid of the familiar energy-relationship triangle, old and new interpretations are compared. And the key difference is emphasized—apparent relativity versus intrinsic relativity. Mass-to-energy conversion is then brought about by adopting a three-part strategy: 1) Make the motion relative to the universal space medium. This allows the introduction of the concept of intrinsic energy (total, kinetic, and mass energies) as counterpart to the apparent version. 2) Recognize that a particle’s mass property diminishes with increase in speed. This means introducing the concept of intrinsic mass (which varies with intrinsic speed). 3) Impose a change in the particle’s gravitational environment. Instead of applying an electromagnetic accelerating force or energy in order to alter the particle’s total energy, there will simply be an environmental change. Thus, it is shown how to use relativity equations and relativistic motion—in a way that exploits the distinction between apparent and innate levels of reality—to explain the mass-to-energy-conversion mechanism. Moreover, the mechanism explains the 100-percent conversion of mass to energy;which, in turn, leads to an explanation of the mechanism driving astrophysical jets.展开更多
In this paper we complete the relativistic cosmological theory because we extend the variational principle including variations of metric induced by expansion of the space. We will show that the mass not only curves S...In this paper we complete the relativistic cosmological theory because we extend the variational principle including variations of metric induced by expansion of the space. We will show that the mass not only curves Space and Time but also generates them: we’ll speak of the principle of mass-space equivalence. Then the increasing mass generates variations of metric as also the space increasing or expansion. So, the dark component of the mass generates additional gravity around galaxies as well as additional space, which generates a pressure (dark energy) accelerating the galaxies in their move away. All this could explain the cosmic coincidence (Ωdm/Ωde ≈ 1). To talk about the increasing mass is equivalent to speak of mass creation in universe, causing the variation of the tensor (T) mass-energy tensor of all component fields. We conjecture that its variation is caused by mass-energy flow comes out from a physical system (Θ) composed by set of uncoupled quantum oscillators (structure of no-field) in vacuum state. All this allows formulating a variational principle which generates the cosmological equation with the (Λ) parameter and a tensor T* with variable mass density, where T*(T, Θ).展开更多
Combining with cosmological constraints we find a most probable value of 17.6 meV for beta decay anti-neutrinos. In passing we note that our expectation for the quadric Higgs self-coupling deviates from standard model...Combining with cosmological constraints we find a most probable value of 17.6 meV for beta decay anti-neutrinos. In passing we note that our expectation for the quadric Higgs self-coupling deviates from standard model expectations by a factor equal to the ud quark mixing matrix element. This matrix element also turns up by its square root in the expected triple self-coupling. We present neutrino mass eigenstates related to the neutron beta decay. In our first scenario we get 15.2 meV for the lowest mass eigenstate, in the second we get 0.917 eV. The latter is to be covered by the KATRIN experiment, while the former comes close to the CRES sensitivity in the Project 8 reach.展开更多
As solitary nymphal parasitoids of Pamtrioza sinica,the ectoparasitoid Tamarixia lyciumi and the endoparasitoid Psyllaephagus arenarius act as effective biocontrol agents.Thus,it is necessary to facilitate mass produc...As solitary nymphal parasitoids of Pamtrioza sinica,the ectoparasitoid Tamarixia lyciumi and the endoparasitoid Psyllaephagus arenarius act as effective biocontrol agents.Thus,it is necessary to facilitate mass productions of both species.Despite showing an excellent parasitic ability,Ps.arenarius is often trapped fatally inside 5th-instar nymphs of Pa.sinica due to strong host immunity.To improve the emergence rate of Ps.arenarius,we evaluated whether Ps.arenarius could utilize T.lyciumi venom via multiparasitism,so the parasitism characteristics of both species were examined between separate-existence(monoparasitism only)and co-existence(mono-and multiparasitism)systems.Further,the parasitism characteristics of Ps.arenarius on venom-injected hosts with/without T.lyciumi eggs were tested to further identify the facilitator.The results showed the parasitism rate of T.lyciumi was increased while that of Ps.arenarius did not change from separate-existence to co-existence systems.The intrinsic performances of two species in monoparasitism did not differ between separate-and co-existence systems.From monoparasitism(separate-existence)to multiparasitism(co-existence),no differences were detected in the intrinsic performances of T.lyciumi,but those of Ps.arenarius were greatly improved.After T.lyciumi venom injection,the parasitism characteristics of Ps.arenarius did not differ between venom-injected hosts with T.lyciumi eggs and those without,further indicating Ps.arenarius benefited from the venom of T.lyciumi females rather than T.lyciumi egg/larval secretions.Instead of negative effects,multiparasitism with ectoparasitoids improves endoparasitoids due to ectoparasitic venom.The study increases host resource utilization and provides creative ways for mass production of endoparasitoids.展开更多
In quantum mechanics, there is a profound distinction between orbital angular momentum and spin angular momentum in which the former can be associated with the motion of a physical object in space but the latter canno...In quantum mechanics, there is a profound distinction between orbital angular momentum and spin angular momentum in which the former can be associated with the motion of a physical object in space but the latter cannot. The difference leads to a radical deviation in the formulation of their corresponding dynamics in which an orbital angular momentum can be described by using a coordinate system but a spin angular momentum cannot. In this work, we show that it is possible to treat spin angular momentum in the same manner as orbital angular momentum by formulating spin dynamics using Schrödinger equation in an intrinsic coordinate system. As an illustration, we apply the formulation to the dynamics of a hydrogen atom and show that the intrinsic spin angular momentum of the electron can take half-integral values and, in particular, the intrinsic mass of the electron can take negative values. We also consider a further extension by generalising the formulation so that it can be used to describe other intrinsic dynamics that may associate with a quantum particle, for example, when a hydrogen atom radiates a photon, the photon associated with the electron may also possess an intrinsic dynamics that can be described by an intrinsic wave equation that has a similar form to that for the electron.展开更多
A brief review and analysis of two historical models of the electron, the charged spinning sphere and Goudsmit and Uhlenbeck’s concept, is presented. It is shown that the enormous potential of classical electrodynami...A brief review and analysis of two historical models of the electron, the charged spinning sphere and Goudsmit and Uhlenbeck’s concept, is presented. It is shown that the enormous potential of classical electrodynamics has been underutilized in particle physics. Such observation leads to discovery of a principal component in the electron inner structure—the charged c-ring. The intrinsic (fundamental) electron model based on the charged c-ring successfully explains the ontology of the charge fractionation in quantum chromodynamics and the formation of Cooper pairs in superconductivity. The c-ring properties are explained on the basis of the General Compton Conditions as defined. Properties of the charged c-ring include the explanation of the boundary conditions, electro-magnetostatic field configuration, self-mass, spin, magnetic moment, and the gyromagnetic ratio. The self-mass of the intrinsic electron is 100% electro-magnetostatic and it is shown how to compute its value. The classical-quantum divide no longer exists. Relation between the intrinsic electron and the electron is fundamentally defined. The electron is the composite fermion consisting of the intrinsic electron and the neutrino. The ontology of the anomaly in the electron magnetic moment is demonstrated—it is due to the addition of the neutrino magnetic moment to the overall electron magnetic moment. The intrinsic electron replaces the W? boson in particle physics, resulting in a fundamental implication for the Standard Model.展开更多
基金supported by Guangdong-Hong Kong-Macao Joint Laboratory for Photonic-Thermal-Electrical Energy Materials and Devices(No.2019B121205001)Shenzhen fundamental research funding(Nos.JCYJ20220818100618039 and JCYJ20200109141405950)+1 种基金the National Natural Science Foundation of China(No.22075125)supported by the Center for Computational Science and Engineering(SUSTech).
文摘Molecular electrocatalysts have demonstrated potential for the hydrogen evolution reaction(HER)due to their well-defined structures and high intrinsic activities.Achieving rapid production of hydrogen requires molecular electrocatalysts to operate at high current densities,which still presents a challenge.In this work,we demonstrate that molecularly dispersed electrocatalysts of cobalt phthalocyanine anchored on carbon nanotubes(CoPc MDEs)are superior candidates due to the efficient charge transport between the substrate and the active site.The intrinsic activity can be enhanced by introducing functional groups on phthalocyanine.To facilitate mass transport,di(ethylene glycol)substituted CoPc molecules are further anchored on a threedimensional self-supported electrode(CoPc-DEG MDE@CC),enabling continuous operation for 25 h at−1000 mA/cm^(2)in 1.0 M KOH.Our study demonstrates the potential of molecular electrocatalysts for HER and emphasizes the importance of adjusting intrinsic activity,and charge and mass transport capacity for practical molecular electrocatalysts.
文摘The quantum field theory (QFT) is one of branches of the Standard Model. According to QFT, quantum fields are the primary entities and particles are the excitations of these fields, coming in discrete lumps with no inner structures and with properties assigned by declaration. Such view is in conflict with the observed vacuum energy density, 140 orders of magnitudes less than required by the QFT. In addition, such view is challenged by Aphysical Quantum Mechanics (AQM), a deeper quantum theory. According to AQM, the fundamental understanding of quantum reality is expanded by the addition of two fundamental categories, aphysical and elementary consciousness of elementary particles. Based on AQM and as an example, the total ontology of the intrinsic (fundamental) electron is presented with its inner structure of perfect geometry consisting of the physical charged c-ring and aphysical cylinder, and with its properties such as self-mass, spin, magneto-electrostatic field configuration and magnetic moment. The position parameter in the inner structure demonstrates that there are no two identical intrinsic electrons in the Universe thus placing a question mark over the QFT principle of indistinguishability.
文摘A new interpretation of the relativistic equation relating total-, momentum-, and mass-energies is presented. With the aid of the familiar energy-relationship triangle, old and new interpretations are compared. And the key difference is emphasized—apparent relativity versus intrinsic relativity. Mass-to-energy conversion is then brought about by adopting a three-part strategy: 1) Make the motion relative to the universal space medium. This allows the introduction of the concept of intrinsic energy (total, kinetic, and mass energies) as counterpart to the apparent version. 2) Recognize that a particle’s mass property diminishes with increase in speed. This means introducing the concept of intrinsic mass (which varies with intrinsic speed). 3) Impose a change in the particle’s gravitational environment. Instead of applying an electromagnetic accelerating force or energy in order to alter the particle’s total energy, there will simply be an environmental change. Thus, it is shown how to use relativity equations and relativistic motion—in a way that exploits the distinction between apparent and innate levels of reality—to explain the mass-to-energy-conversion mechanism. Moreover, the mechanism explains the 100-percent conversion of mass to energy;which, in turn, leads to an explanation of the mechanism driving astrophysical jets.
文摘In this paper we complete the relativistic cosmological theory because we extend the variational principle including variations of metric induced by expansion of the space. We will show that the mass not only curves Space and Time but also generates them: we’ll speak of the principle of mass-space equivalence. Then the increasing mass generates variations of metric as also the space increasing or expansion. So, the dark component of the mass generates additional gravity around galaxies as well as additional space, which generates a pressure (dark energy) accelerating the galaxies in their move away. All this could explain the cosmic coincidence (Ωdm/Ωde ≈ 1). To talk about the increasing mass is equivalent to speak of mass creation in universe, causing the variation of the tensor (T) mass-energy tensor of all component fields. We conjecture that its variation is caused by mass-energy flow comes out from a physical system (Θ) composed by set of uncoupled quantum oscillators (structure of no-field) in vacuum state. All this allows formulating a variational principle which generates the cosmological equation with the (Λ) parameter and a tensor T* with variable mass density, where T*(T, Θ).
文摘Combining with cosmological constraints we find a most probable value of 17.6 meV for beta decay anti-neutrinos. In passing we note that our expectation for the quadric Higgs self-coupling deviates from standard model expectations by a factor equal to the ud quark mixing matrix element. This matrix element also turns up by its square root in the expected triple self-coupling. We present neutrino mass eigenstates related to the neutron beta decay. In our first scenario we get 15.2 meV for the lowest mass eigenstate, in the second we get 0.917 eV. The latter is to be covered by the KATRIN experiment, while the former comes close to the CRES sensitivity in the Project 8 reach.
基金This research was funded by the Ningxia Agriculture Integrated Development and Sci-tech Extension Program(Grant no.znnfkj2015).
文摘As solitary nymphal parasitoids of Pamtrioza sinica,the ectoparasitoid Tamarixia lyciumi and the endoparasitoid Psyllaephagus arenarius act as effective biocontrol agents.Thus,it is necessary to facilitate mass productions of both species.Despite showing an excellent parasitic ability,Ps.arenarius is often trapped fatally inside 5th-instar nymphs of Pa.sinica due to strong host immunity.To improve the emergence rate of Ps.arenarius,we evaluated whether Ps.arenarius could utilize T.lyciumi venom via multiparasitism,so the parasitism characteristics of both species were examined between separate-existence(monoparasitism only)and co-existence(mono-and multiparasitism)systems.Further,the parasitism characteristics of Ps.arenarius on venom-injected hosts with/without T.lyciumi eggs were tested to further identify the facilitator.The results showed the parasitism rate of T.lyciumi was increased while that of Ps.arenarius did not change from separate-existence to co-existence systems.The intrinsic performances of two species in monoparasitism did not differ between separate-and co-existence systems.From monoparasitism(separate-existence)to multiparasitism(co-existence),no differences were detected in the intrinsic performances of T.lyciumi,but those of Ps.arenarius were greatly improved.After T.lyciumi venom injection,the parasitism characteristics of Ps.arenarius did not differ between venom-injected hosts with T.lyciumi eggs and those without,further indicating Ps.arenarius benefited from the venom of T.lyciumi females rather than T.lyciumi egg/larval secretions.Instead of negative effects,multiparasitism with ectoparasitoids improves endoparasitoids due to ectoparasitic venom.The study increases host resource utilization and provides creative ways for mass production of endoparasitoids.
文摘In quantum mechanics, there is a profound distinction between orbital angular momentum and spin angular momentum in which the former can be associated with the motion of a physical object in space but the latter cannot. The difference leads to a radical deviation in the formulation of their corresponding dynamics in which an orbital angular momentum can be described by using a coordinate system but a spin angular momentum cannot. In this work, we show that it is possible to treat spin angular momentum in the same manner as orbital angular momentum by formulating spin dynamics using Schrödinger equation in an intrinsic coordinate system. As an illustration, we apply the formulation to the dynamics of a hydrogen atom and show that the intrinsic spin angular momentum of the electron can take half-integral values and, in particular, the intrinsic mass of the electron can take negative values. We also consider a further extension by generalising the formulation so that it can be used to describe other intrinsic dynamics that may associate with a quantum particle, for example, when a hydrogen atom radiates a photon, the photon associated with the electron may also possess an intrinsic dynamics that can be described by an intrinsic wave equation that has a similar form to that for the electron.
文摘A brief review and analysis of two historical models of the electron, the charged spinning sphere and Goudsmit and Uhlenbeck’s concept, is presented. It is shown that the enormous potential of classical electrodynamics has been underutilized in particle physics. Such observation leads to discovery of a principal component in the electron inner structure—the charged c-ring. The intrinsic (fundamental) electron model based on the charged c-ring successfully explains the ontology of the charge fractionation in quantum chromodynamics and the formation of Cooper pairs in superconductivity. The c-ring properties are explained on the basis of the General Compton Conditions as defined. Properties of the charged c-ring include the explanation of the boundary conditions, electro-magnetostatic field configuration, self-mass, spin, magnetic moment, and the gyromagnetic ratio. The self-mass of the intrinsic electron is 100% electro-magnetostatic and it is shown how to compute its value. The classical-quantum divide no longer exists. Relation between the intrinsic electron and the electron is fundamentally defined. The electron is the composite fermion consisting of the intrinsic electron and the neutrino. The ontology of the anomaly in the electron magnetic moment is demonstrated—it is due to the addition of the neutrino magnetic moment to the overall electron magnetic moment. The intrinsic electron replaces the W? boson in particle physics, resulting in a fundamental implication for the Standard Model.
