Under neat conditions,an efficient method for synthesis of imidoesters has been developed using cyanatobenzenes and dicarbonyl compounds.Nucleophilic addition spontaneously occurred between the two kinds of materials ...Under neat conditions,an efficient method for synthesis of imidoesters has been developed using cyanatobenzenes and dicarbonyl compounds.Nucleophilic addition spontaneously occurred between the two kinds of materials at room temperature with yields of up to 90%.A mechanism directed towards to the imidoester formation has been proposed.展开更多
基金the National Natural Science Foundation of China (Nos.21372265 and 61271059)the Scientific Research Foundation for the Returned Overseas Chinese Scholars,State Education Ministry,the Natural Science Foundation Project of CQ CSTC (Nos.CSTC2013jcyjA0217 and CSTC2010BB4086)the Fundamental Research Funds for the Central Universities(Nos.CQDXWL2013-Z012 and CDJZR-14225502)
文摘Under neat conditions,an efficient method for synthesis of imidoesters has been developed using cyanatobenzenes and dicarbonyl compounds.Nucleophilic addition spontaneously occurred between the two kinds of materials at room temperature with yields of up to 90%.A mechanism directed towards to the imidoester formation has been proposed.
