The Hg 0 vapor adsorption experimental results on a novel sorbent obtained by impregnating a commercially available activated carbon （Darco G60 from BDH） with silver nitrate were reported.The study was performed by ...The Hg 0 vapor adsorption experimental results on a novel sorbent obtained by impregnating a commercially available activated carbon （Darco G60 from BDH） with silver nitrate were reported.The study was performed by using a fundamental approach,in an apparatus at laboratory scale in which a synthetic flue gas,formed by Hg 0 vapors in a nitrogen gas stream,at a given temperature and mercury concentration,was flowed through a fixed bed of adsorbent material.Breakthrough curves and adsorption isotherms were obtained for bed temperatures of 90,120 and 150°C and for Hg 0 concentrations in the gas varying in the range of 0.8–5.0 mg/m 3 .The experimental gas-solid equilibrium data were used to evaluate the Langmuir parameters and the heat of adsorption.The experimental results showed that silver impregnated carbon was very effective to capture elemental mercury and the amount of mercury adsorbed by the carbon decreased as the bed temperature increased.In addition,to evaluate the possibility of adsorbent recovery,desorption was also studied.Desorption runs showed that both the adsorbing material and the mercury could be easily recovered,since at the end of desorption the residue on solid was almost negligible.The material balance on mercury and the constitutive equations of the adsorption phenomenon were integrated,leading to the evaluation of only one kinetic parameter which fits well both the experimentally determined breakthrough and desorption curves.展开更多
This paper provides analytical diagnosis of mechanical conditions of medical waste incinerators used for healthcare waste (HCW) treatment in Tanzania. The main features assessed were types of incinerators, features of...This paper provides analytical diagnosis of mechanical conditions of medical waste incinerators used for healthcare waste (HCW) treatment in Tanzania. The main features assessed were types of incinerators, features of incinerators and incinerator house. The assessment was conducted in three levels of health care facilities (HCFs), that is, Regional, district hospitals and health centers, existed in 26 regions of Tanzania. Questionnaires, interview and checklists were used as tools for data collection. It was observed that High-Tech incinerators are mainly used in regional hospitals, while district hospital and health center use both High-Tech and De-Montfort incinerators. About 60% of the incinerators have defective doors. More than 55% of incinerators are corroded in regional and district hospitals. The chimney, top plates and grate which are good condition are 55.6% and 60% in regional hospitals and health centers, respectively. The situation is below 50% in district hospitals. The leakage of the roof and loose structures were observed in district hospitals and health center to be more than 50% of the incinerator houses. On other hand, the performance of burners and incinerator housing cleanliness are generally good. It was concluded that the incinerators in the HCFs are in bad conditions, necessitating maintenance.展开更多
The aim of this study was to assess Readiness of Healthcare facilities to Implement onsite Healthcare Waste Management Protocols and Incineration Guidelines in Tanzania. To address this, a national assessment was cond...The aim of this study was to assess Readiness of Healthcare facilities to Implement onsite Healthcare Waste Management Protocols and Incineration Guidelines in Tanzania. To address this, a national assessment was conducted country wide to assess readiness of Healthcare Facilities (HCFs) to undertake various Healthcare Waste Management (HCWM) initiatives with particular focus to adherence to HCWM protocols and incineration guidelines. The assessment of healthcare waste management was conducted in facilities in the 26 regions of Tanzania mainland for one month. A standardized checklist and tools were used to assess and monitor various aspects related to healthcare waste management using open source software for data collection (ODK). Data were analyzed using SPSS computer software. It was observed that 46.2%, 33.3% and 25% of the health centres, district hospitals and regional hospitals did not have appointed supervisors, which makes it difficult for the HCFs to perform better in managing healthcare waste in their respective facilities. It was further revealed that healthcare facilities have made remarkable improvement in the overall healthcare waste management with evidence of ongoing common activity on purchasing injection safety boxes (69.2%) and purchasing of waste bins (53.8%) at all levels. On average, about 70% of the HCFs have plans and budget though inadequate to support HCWM activities. In a conclusion Healthcare Facilities must designate a better system to compressively address healthcare waste management issues. Again the findings provide evidence for those engaged in improving HCF conditions to develop evidence-based policies and efficient programs, enhance service delivery systems, and make better use of available resources.展开更多
Incineration is an effective way of health care waste management, but it is also a source of air pollution. Thermal decomposition of organic and inorganic waste during incineration releases a large concentration of ai...Incineration is an effective way of health care waste management, but it is also a source of air pollution. Thermal decomposition of organic and inorganic waste during incineration releases a large concentration of air pollutants such as CO, SO<sub>2</sub>, NOx, CO<sub>2</sub> and particulate matter (PM). A cross sectional-descriptive study was conducted to determine the short-term variations in PM concentrations across various areas in the vicinity of a local incinerator in Windhoek, Namibia. XRF Qualitative analysis method was used to determine the elemental composition of fallout dust concentration from six study areas/stations in the vicinity of a local incinerator. Single bucket fallout monitors were deployed following the American Society for Testing and Materials standard method for collection and analysis of dust fallout to determine the elemental composition of fallout dust. Real-time PM concentration trends were also recorded using a portable Micro dust Pro Real-time Dust Monitor for PM10 at a height of 2.2 m above the ground. High PM concentration peaks were observed in the morning and afternoon hours at varying points. The fallout dust rate ranged between highest 1839.3 mg/m2/day at sampling Point 4 and lowest 711 mg/m2/day at sampling Point 2. The XRF analysis revealed the presence of toxic elements and crustal elements in order of decreasing abundance: Mn > Zn > Cr > V > Zr > Sr > Pb > Ni and SI > K > Fe > Ti > Ca > Al > P respectively. Highest elemental composition concentrations were found at sampling location in the vicinity of the incinerator and in industrial area.展开更多
According to the dual needs of heat transfer and thermal insulation in incinerators,different parts of the incinerators are designed with refractories of different SiC contents.Water vapor is mainly concentrated in th...According to the dual needs of heat transfer and thermal insulation in incinerators,different parts of the incinerators are designed with refractories of different SiC contents.Water vapor is mainly concentrated in the zones of feeding,drying and combustion,and the main damage factors of SiC refractories include high temperature and hydration.The results of hydration resistance of typical SiC-containing refractories show that the higher the SiC content,the worse the hydration resistance.Si_(3)N_(4)-SiC refractories after oxidation treatment have good hydration corrosion resistance,which are appropriate for water-cooled wall of waste incinerators.展开更多
Medical waste incinerators emit a wide range of pollutants like heavy metals, dioxins and furans. These include Pb （lead）, Hg （mercury）, Cd （cadmium）, fine dust particles and PICs （products of incomplete combus...Medical waste incinerators emit a wide range of pollutants like heavy metals, dioxins and furans. These include Pb （lead）, Hg （mercury）, Cd （cadmium）, fine dust particles and PICs （products of incomplete combustion）. The objective was to determine the elemental composition of medical waste residue after incineration in selected hospitals in Kiambu County, Kenya. Bottom/fly ash samples were collected from the burners/incinerators in the selected health care facilities visited. The concentrations of the metals in the fly ash and bottom ash were determined using an XRF （X-ray fluorescence） spectrometer after acid digestion. The concentrations of heavy metals in the fly and bottom ash were as follows： Ti （titanium） 62-839 mg·kg^-1 and a mean of 202 mg·kg^-1 and 344 mg·kg^-1 in fly ash and bottom ash, respectively. Ca （calcium） was 37,753-204,475 mg.kg1 with means of 27,132 mg.kg-1 in fly ash and 131,185 mgg·kg^-1 in bottom ash. Zn （zinc） was 297-6,605 mg·kg^-1 with means （2,307 mg·kg^-1 in fly ash, 4,359 mg·kg^-1 in bottom ash）, Pb （13-1,819 mg·kg^-1） had means of 280 mg·kg^-1 in fly ash and 291 mg-kg-1 in bottom ash. Cu （copper） （9.5-250 mg·kg^-1） had means of 83.47 mg·kg^-1 in fly ash and 98.8 mg·kg^-1 in bottom ash. The wide variations in results can be attributed to the different burners/incinerators used and different segregation methods of the medical waste. The results show that the reported levels of heavy metals could pose a health risk due to possible leaching after disposal.展开更多
文摘The Hg 0 vapor adsorption experimental results on a novel sorbent obtained by impregnating a commercially available activated carbon （Darco G60 from BDH） with silver nitrate were reported.The study was performed by using a fundamental approach,in an apparatus at laboratory scale in which a synthetic flue gas,formed by Hg 0 vapors in a nitrogen gas stream,at a given temperature and mercury concentration,was flowed through a fixed bed of adsorbent material.Breakthrough curves and adsorption isotherms were obtained for bed temperatures of 90,120 and 150°C and for Hg 0 concentrations in the gas varying in the range of 0.8–5.0 mg/m 3 .The experimental gas-solid equilibrium data were used to evaluate the Langmuir parameters and the heat of adsorption.The experimental results showed that silver impregnated carbon was very effective to capture elemental mercury and the amount of mercury adsorbed by the carbon decreased as the bed temperature increased.In addition,to evaluate the possibility of adsorbent recovery,desorption was also studied.Desorption runs showed that both the adsorbing material and the mercury could be easily recovered,since at the end of desorption the residue on solid was almost negligible.The material balance on mercury and the constitutive equations of the adsorption phenomenon were integrated,leading to the evaluation of only one kinetic parameter which fits well both the experimentally determined breakthrough and desorption curves.
文摘This paper provides analytical diagnosis of mechanical conditions of medical waste incinerators used for healthcare waste (HCW) treatment in Tanzania. The main features assessed were types of incinerators, features of incinerators and incinerator house. The assessment was conducted in three levels of health care facilities (HCFs), that is, Regional, district hospitals and health centers, existed in 26 regions of Tanzania. Questionnaires, interview and checklists were used as tools for data collection. It was observed that High-Tech incinerators are mainly used in regional hospitals, while district hospital and health center use both High-Tech and De-Montfort incinerators. About 60% of the incinerators have defective doors. More than 55% of incinerators are corroded in regional and district hospitals. The chimney, top plates and grate which are good condition are 55.6% and 60% in regional hospitals and health centers, respectively. The situation is below 50% in district hospitals. The leakage of the roof and loose structures were observed in district hospitals and health center to be more than 50% of the incinerator houses. On other hand, the performance of burners and incinerator housing cleanliness are generally good. It was concluded that the incinerators in the HCFs are in bad conditions, necessitating maintenance.
文摘The aim of this study was to assess Readiness of Healthcare facilities to Implement onsite Healthcare Waste Management Protocols and Incineration Guidelines in Tanzania. To address this, a national assessment was conducted country wide to assess readiness of Healthcare Facilities (HCFs) to undertake various Healthcare Waste Management (HCWM) initiatives with particular focus to adherence to HCWM protocols and incineration guidelines. The assessment of healthcare waste management was conducted in facilities in the 26 regions of Tanzania mainland for one month. A standardized checklist and tools were used to assess and monitor various aspects related to healthcare waste management using open source software for data collection (ODK). Data were analyzed using SPSS computer software. It was observed that 46.2%, 33.3% and 25% of the health centres, district hospitals and regional hospitals did not have appointed supervisors, which makes it difficult for the HCFs to perform better in managing healthcare waste in their respective facilities. It was further revealed that healthcare facilities have made remarkable improvement in the overall healthcare waste management with evidence of ongoing common activity on purchasing injection safety boxes (69.2%) and purchasing of waste bins (53.8%) at all levels. On average, about 70% of the HCFs have plans and budget though inadequate to support HCWM activities. In a conclusion Healthcare Facilities must designate a better system to compressively address healthcare waste management issues. Again the findings provide evidence for those engaged in improving HCF conditions to develop evidence-based policies and efficient programs, enhance service delivery systems, and make better use of available resources.
文摘Incineration is an effective way of health care waste management, but it is also a source of air pollution. Thermal decomposition of organic and inorganic waste during incineration releases a large concentration of air pollutants such as CO, SO<sub>2</sub>, NOx, CO<sub>2</sub> and particulate matter (PM). A cross sectional-descriptive study was conducted to determine the short-term variations in PM concentrations across various areas in the vicinity of a local incinerator in Windhoek, Namibia. XRF Qualitative analysis method was used to determine the elemental composition of fallout dust concentration from six study areas/stations in the vicinity of a local incinerator. Single bucket fallout monitors were deployed following the American Society for Testing and Materials standard method for collection and analysis of dust fallout to determine the elemental composition of fallout dust. Real-time PM concentration trends were also recorded using a portable Micro dust Pro Real-time Dust Monitor for PM10 at a height of 2.2 m above the ground. High PM concentration peaks were observed in the morning and afternoon hours at varying points. The fallout dust rate ranged between highest 1839.3 mg/m2/day at sampling Point 4 and lowest 711 mg/m2/day at sampling Point 2. The XRF analysis revealed the presence of toxic elements and crustal elements in order of decreasing abundance: Mn > Zn > Cr > V > Zr > Sr > Pb > Ni and SI > K > Fe > Ti > Ca > Al > P respectively. Highest elemental composition concentrations were found at sampling location in the vicinity of the incinerator and in industrial area.
文摘According to the dual needs of heat transfer and thermal insulation in incinerators,different parts of the incinerators are designed with refractories of different SiC contents.Water vapor is mainly concentrated in the zones of feeding,drying and combustion,and the main damage factors of SiC refractories include high temperature and hydration.The results of hydration resistance of typical SiC-containing refractories show that the higher the SiC content,the worse the hydration resistance.Si_(3)N_(4)-SiC refractories after oxidation treatment have good hydration corrosion resistance,which are appropriate for water-cooled wall of waste incinerators.
文摘Medical waste incinerators emit a wide range of pollutants like heavy metals, dioxins and furans. These include Pb （lead）, Hg （mercury）, Cd （cadmium）, fine dust particles and PICs （products of incomplete combustion）. The objective was to determine the elemental composition of medical waste residue after incineration in selected hospitals in Kiambu County, Kenya. Bottom/fly ash samples were collected from the burners/incinerators in the selected health care facilities visited. The concentrations of the metals in the fly ash and bottom ash were determined using an XRF （X-ray fluorescence） spectrometer after acid digestion. The concentrations of heavy metals in the fly and bottom ash were as follows： Ti （titanium） 62-839 mg·kg^-1 and a mean of 202 mg·kg^-1 and 344 mg·kg^-1 in fly ash and bottom ash, respectively. Ca （calcium） was 37,753-204,475 mg.kg1 with means of 27,132 mg.kg-1 in fly ash and 131,185 mgg·kg^-1 in bottom ash. Zn （zinc） was 297-6,605 mg·kg^-1 with means （2,307 mg·kg^-1 in fly ash, 4,359 mg·kg^-1 in bottom ash）, Pb （13-1,819 mg·kg^-1） had means of 280 mg·kg^-1 in fly ash and 291 mg-kg-1 in bottom ash. Cu （copper） （9.5-250 mg·kg^-1） had means of 83.47 mg·kg^-1 in fly ash and 98.8 mg·kg^-1 in bottom ash. The wide variations in results can be attributed to the different burners/incinerators used and different segregation methods of the medical waste. The results show that the reported levels of heavy metals could pose a health risk due to possible leaching after disposal.
