The present work describes the viability of a mortar binder based on two industrial by-products: poly(vinyl chloride) (PVC) particles from scrap and anhydrite (CaSO4) from fluorgypsum. Mortar composites were made inco...The present work describes the viability of a mortar binder based on two industrial by-products: poly(vinyl chloride) (PVC) particles from scrap and anhydrite (CaSO4) from fluorgypsum. Mortar composites were made incorporating different amounts of PVC particles and cured at constant room temperature during various periods of time. From X-ray diffraction, it was possible to follow the hydration process and to estimate the effect of the PVC particles on anhydrite transformation to gypsum (CaSO4·2H2O). Compressive strength from uniaxial testing was measured from stress-strain curves carried out at room temperature. According to these results, the hydration rates of the composites depend on the concentration of PVC particles and there is an enhancement in their compressive strength as particle content increases, reaching values of 36 MPa after 28 days.展开更多
To contribute to the enhancement of unconventional local materials used for road construction,this study characterizes a crushed sand 0/5,a clayey soil and the litho-stabilized material without and with hydraulic bind...To contribute to the enhancement of unconventional local materials used for road construction,this study characterizes a crushed sand 0/5,a clayey soil and the litho-stabilized material without and with hydraulic binder and determines their use in accordance with some reference specifications(CEBTP 1984).It is shown that the different components are not usable alone in pavement base.Indeed,the plasticity index obtained for the clayey soil is 21%,a value higher than the imposed standards.In addition,the grading of the 0/5 crushed sand does not fit into the range proposed by CEBTP.A combination of these two(02)components is therefore considered to obtain a suitable material usable for the sub-base.This new material does not enter any class of the CEBTP lateritic soils.In order to be used in base layer,a treatment with hydraulic binder is carried out with the intention to improve its mechanical performances.The optimal dosage of hydraulic binder to achieve the desired mechanical performance is obtained by studying the evolution of the mechanical characteristics of the mixture.After this treatment,the Bearing Ratio index of the mix increases from 37 to 223 for the optimal dosage and the dry compaction density decreases from 2.11 to 2.06 g/cm3 while the optimal water content increases from 9%to 10.1%.展开更多
A new hydraulic cementitious binder was developed by mainly utilizing industrial byproducts phosphogypsum(PG)and ground granulated blast furnace slag(GGBFS)with small addition of ordinary portland cement(OPC).Th...A new hydraulic cementitious binder was developed by mainly utilizing industrial byproducts phosphogypsum(PG)and ground granulated blast furnace slag(GGBFS)with small addition of ordinary portland cement(OPC).The hydration process and microstructure were studied by X-ray diffraction(XRD) and scanning electronic microscopy(SEM).OPC hydrated first at early age to form primarily C-S-H gel,ettringite and calcium hydroxide(CH).GGBFS activated by CH and sulfate ions hydrated continuously at later age,producing more and more hydration products,C-S-H gel and ettringite.Thus the paste developed a denser microstructure and its strength increased.The 28 d compressive strength of the mixture of 50%PG,46% GGBFS and 4%OPC exceeded 45 MPa.The setting time was faster and 3 d and 7 d strength were higher when the proportion of OPC increased.But the 28 d strength decreased when OPC exceeded 4%due to large amount of ettringite formed at late hydration age which damaged the microstructure.展开更多
文摘The present work describes the viability of a mortar binder based on two industrial by-products: poly(vinyl chloride) (PVC) particles from scrap and anhydrite (CaSO4) from fluorgypsum. Mortar composites were made incorporating different amounts of PVC particles and cured at constant room temperature during various periods of time. From X-ray diffraction, it was possible to follow the hydration process and to estimate the effect of the PVC particles on anhydrite transformation to gypsum (CaSO4·2H2O). Compressive strength from uniaxial testing was measured from stress-strain curves carried out at room temperature. According to these results, the hydration rates of the composites depend on the concentration of PVC particles and there is an enhancement in their compressive strength as particle content increases, reaching values of 36 MPa after 28 days.
文摘To contribute to the enhancement of unconventional local materials used for road construction,this study characterizes a crushed sand 0/5,a clayey soil and the litho-stabilized material without and with hydraulic binder and determines their use in accordance with some reference specifications(CEBTP 1984).It is shown that the different components are not usable alone in pavement base.Indeed,the plasticity index obtained for the clayey soil is 21%,a value higher than the imposed standards.In addition,the grading of the 0/5 crushed sand does not fit into the range proposed by CEBTP.A combination of these two(02)components is therefore considered to obtain a suitable material usable for the sub-base.This new material does not enter any class of the CEBTP lateritic soils.In order to be used in base layer,a treatment with hydraulic binder is carried out with the intention to improve its mechanical performances.The optimal dosage of hydraulic binder to achieve the desired mechanical performance is obtained by studying the evolution of the mechanical characteristics of the mixture.After this treatment,the Bearing Ratio index of the mix increases from 37 to 223 for the optimal dosage and the dry compaction density decreases from 2.11 to 2.06 g/cm3 while the optimal water content increases from 9%to 10.1%.
文摘A new hydraulic cementitious binder was developed by mainly utilizing industrial byproducts phosphogypsum(PG)and ground granulated blast furnace slag(GGBFS)with small addition of ordinary portland cement(OPC).The hydration process and microstructure were studied by X-ray diffraction(XRD) and scanning electronic microscopy(SEM).OPC hydrated first at early age to form primarily C-S-H gel,ettringite and calcium hydroxide(CH).GGBFS activated by CH and sulfate ions hydrated continuously at later age,producing more and more hydration products,C-S-H gel and ettringite.Thus the paste developed a denser microstructure and its strength increased.The 28 d compressive strength of the mixture of 50%PG,46% GGBFS and 4%OPC exceeded 45 MPa.The setting time was faster and 3 d and 7 d strength were higher when the proportion of OPC increased.But the 28 d strength decreased when OPC exceeded 4%due to large amount of ettringite formed at late hydration age which damaged the microstructure.