目的通过观察黏固剂与根管牙本质的粘接界面,比较各种黏固剂的粘接性能。方法将15颗牙分成3组,分别用Rely X luting、Panavia F、Paracore 5mL粘接纤维桩,实验牙纵剖后,置于扫描电镜下观察纤维桩冠1/3、中1/3及根尖1/3处牙本质黏固剂界...目的通过观察黏固剂与根管牙本质的粘接界面,比较各种黏固剂的粘接性能。方法将15颗牙分成3组,分别用Rely X luting、Panavia F、Paracore 5mL粘接纤维桩,实验牙纵剖后,置于扫描电镜下观察纤维桩冠1/3、中1/3及根尖1/3处牙本质黏固剂界面,并分别测量混合层厚度。结果1组牙本质黏固剂界面未发现明显混合层,2组与3组可发现明显混合层,且3组可发现树脂突及粘接性侧枝。从根尖方向冠方,1组粘接界面裂隙逐渐缩小,而2组与3组混合层逐渐增厚。结论全酸蚀树脂黏固剂与牙本质结合紧密,粘接性能较树脂改良型玻璃离子黏固剂、自酸蚀树脂黏固剂优越。展开更多
Poly(vinylidenefluoride-co-hexafluoropropylene)(P(VDF-HFP))/Li_(1.3)Al_(0.3)Ti_(1.7)(PO_(4))_(3)(LATP)/P(VDFHFP) sandwiched hybrid solid electrolytes were precisely tailored and successfully fabricated to assemble int...Poly(vinylidenefluoride-co-hexafluoropropylene)(P(VDF-HFP))/Li_(1.3)Al_(0.3)Ti_(1.7)(PO_(4))_(3)(LATP)/P(VDFHFP) sandwiched hybrid solid electrolytes were precisely tailored and successfully fabricated to assemble into allsolid-state lithium-ion batteries,which were systematically evaluated on microstructure,morphology,thermal stability and electrochemical performance.The sandwiched hybrid solid electrolytes can achieve intimate contact with cathode and anode electrodes to present an excellent interfacial stability.Furthermore,the sandwiched hybrid solid electrolytes possess flexible surface,wide electrochemical working window of 4.7 V,high ionic conductivity of 0.763 mS·cm^(-1) and high thermal stability of 460℃,which may contribute to realizing the practical application in all-solid-state lithium-ion batteries.The assembled cells with the hybrid solid electrolytes can quickly stabilize at a specific discharge capacity of 145.4 mAh·g^(-1) at 0.1 C after only 5 cycles and present admirable rate performance.In addition,morphology characterizations of the sandwiched hybrid solid electrolytes after long-term cycles show a relatively integrated structure coating with a compact LATP layer.The investigations afford a promising strategy that the sandwiched hybrid solid electrolytes can overcome the mechanical limitations of the interface between electrodes and inorganic solid electrolytes to provide favorable properties for all-solid-state lithium-ion batteries.展开更多
Accurate predictions of Shock Waves and Boundary Layer Interaction(SWBLI)and strong Shock Waves and Wake Vortices Interaction(SWWVI)in a highly-loaded turbine propose challenges to the currently widely used Reynolds-A...Accurate predictions of Shock Waves and Boundary Layer Interaction(SWBLI)and strong Shock Waves and Wake Vortices Interaction(SWWVI)in a highly-loaded turbine propose challenges to the currently widely used Reynolds-Averaged Navier-Stokes(RANS)model.In this work,the SWBLI and the SWWVI in a highly-loaded Nozzle Guide Vane(NGV)are studied using a hybrid RANS/LES strategy.The Turbulence Kinetic Energy(TKE)budget and the Proper Orthogonal Decomposition(POD)method are used to analyze flow mechanisms.Results show that this hybrid RANS/LES method can obtain detailed flow structures for flow mechanisms analysis.Strong shock waves induce boundary layer separation,while the presence of a separation bubble can in turn lead to a Mach reflection phenomenon.The shock waves cause trailing-edge vortices to break clearly,and the wakes,in turn,can change the shocks intensity and direction.Furthermore,the Entropy Generation Rate(EGR)is used to analyze the irreversible loss.It turns out that the SWWVI can reduce the flow field loss.There are several weak shock waves in the NGV flow field,which can increase the irreversible loss.This work offers flow mechanisms analysis and presents the EGR distribution in SWBLI and SWWVI areas in a transonic turbine blade.展开更多
In spectral-like resolution-WENO hybrid schemes,if the switch function takes more grid points as discontinuity points,the WENO scheme is often turned on,and the numerical solutions may be too dissipative.Conversely,if...In spectral-like resolution-WENO hybrid schemes,if the switch function takes more grid points as discontinuity points,the WENO scheme is often turned on,and the numerical solutions may be too dissipative.Conversely,if the switch function takes less grid points as discontinuity points,the hybrid schemes usually are found to produce oscillatory solutions or just to be unstable.Even if the switch function takes less grid points as discontinuity points,the final hybrid scheme is inclined to be more stable,provided the spectral-like resolution scheme in the hybrid scheme has moderate shock-capturing capability.Following this idea,we propose nonlinear spectral-like schemes named weighted group velocity control(WGVC)schemes.These schemes show not only high-resolution for short waves but also moderate shock capturing capability.Then a new class of hybrid schemes is designed in which the WGVC scheme is used in smooth regions and the WENO scheme is used to capture discontinuities.These hybrid schemes show good resolution for small-scales structures and fine shock-capturing capabilities while the switch function takes less grid points as discontinuity points.The seven-order WGVC-WENO scheme has also been applied successfully to the direct numerical simulation of oblique shock wave-turbulent boundary layer interaction.展开更多
Although aqueous zinc ion hybrid capacitors have advantageous integration of batteries and supercapacitors,they still suffer from the inherent problems of dendrite growth and interfacial side reactions on Zn anodes.He...Although aqueous zinc ion hybrid capacitors have advantageous integration of batteries and supercapacitors,they still suffer from the inherent problems of dendrite growth and interfacial side reactions on Zn anodes.Herein,a universal fast zinc-ion diffusion layer on a three-dimensional(3 D)mesh structure model is demonstrated to effectively improve Zn plating/stripping reversibility.The fast ion diffusion alloy layer accelerates the Zn^(2+)migration in an orderly manner to homogenize Zn^(2+)flux and overcomes the defects of the commercial mesh substrate,effectively avoiding dendrite growth and side reactions.Consequently,the proof-of-concept silver-zinc alloy modified stainless steel mesh delivers superb reversibility with the high coulombic efficiency over 99.4%at 4 mA cm^(-2)after 1600 cycles and excellent reliability of over 830 h at 1 mA cm^(-2),Its feasibility is also evidenced in commercial zinc ion hybrid capacitors with activated carbon as the cathode.This work enriches the fundamental comprehension of fast zinc-ion diffusion layer combined with a 3 D substrate on the Zn deposition and opens a universal approach to design advanced host for Zn electrodes in zinc ion hybrid capacitors.展开更多
Organic solar cells(OSCs)have gained conspicuous progress during the past few decades due to the development of materials and upgrading of the device structure.The power conversion efficiency(PCE)of the single-junctio...Organic solar cells(OSCs)have gained conspicuous progress during the past few decades due to the development of materials and upgrading of the device structure.The power conversion efficiency(PCE)of the single-junction device had surpassed 19%.The cathode interface layer(CIL),by optimizing the connection between the active layer and the cathode electrode,has become a momentous part to strengthen the performances of the OSCs.Simultaneously,CIL is also indispensable to illustrating the working mechanism of OSCs and enhancing the stability of the OSCs.In this essay,hybrid CILs in OSCs have been summarized.Firstly,the advancement and operating mechanism of OSCs,and the effects and relevant design rules of CIL are briefly concluded;secondly,the significant influence of CIL on enhancing the stability and PCE of OSCs is presented;thirdly,the characteristics of organic hybrid CIL and organic-inorganic hybrid CIL are introduced.Finally,the conclusion and outlook of CIL are summarized.展开更多
This work made use of the Aalto University Otanano-Nanomicroscopy Center and RAMI infrastructures.Financial support from Business Finland NextGenBat[grant number 211849]is greatly acknowledged.The tomography experimen...This work made use of the Aalto University Otanano-Nanomicroscopy Center and RAMI infrastructures.Financial support from Business Finland NextGenBat[grant number 211849]is greatly acknowledged.The tomography experiment was performed at the beamline ID16B of the European Synchrotron Radiation Facility(ESRF),Grenoble,France,in the frame of proposal CH-6644.The patent titled“Stabilized Positive Electrode Material to Enable High Energy and Power Density Lithium-Ion Batteries”(IPD3173)is pertinent to this manuscript.It was filed by Zahra Ahaliabadeh and Tanja Kallio,and the patent rights are held by Aalto University.展开更多
文摘目的通过观察黏固剂与根管牙本质的粘接界面,比较各种黏固剂的粘接性能。方法将15颗牙分成3组,分别用Rely X luting、Panavia F、Paracore 5mL粘接纤维桩,实验牙纵剖后,置于扫描电镜下观察纤维桩冠1/3、中1/3及根尖1/3处牙本质黏固剂界面,并分别测量混合层厚度。结果1组牙本质黏固剂界面未发现明显混合层,2组与3组可发现明显混合层,且3组可发现树脂突及粘接性侧枝。从根尖方向冠方,1组粘接界面裂隙逐渐缩小,而2组与3组混合层逐渐增厚。结论全酸蚀树脂黏固剂与牙本质结合紧密,粘接性能较树脂改良型玻璃离子黏固剂、自酸蚀树脂黏固剂优越。
基金financially supported by the National Natural Science Foundation of China (Nos.51874046 and 51404038)the Outstanding Youth Foundation of Hubei Province (No.2020CFA090)。
文摘Poly(vinylidenefluoride-co-hexafluoropropylene)(P(VDF-HFP))/Li_(1.3)Al_(0.3)Ti_(1.7)(PO_(4))_(3)(LATP)/P(VDFHFP) sandwiched hybrid solid electrolytes were precisely tailored and successfully fabricated to assemble into allsolid-state lithium-ion batteries,which were systematically evaluated on microstructure,morphology,thermal stability and electrochemical performance.The sandwiched hybrid solid electrolytes can achieve intimate contact with cathode and anode electrodes to present an excellent interfacial stability.Furthermore,the sandwiched hybrid solid electrolytes possess flexible surface,wide electrochemical working window of 4.7 V,high ionic conductivity of 0.763 mS·cm^(-1) and high thermal stability of 460℃,which may contribute to realizing the practical application in all-solid-state lithium-ion batteries.The assembled cells with the hybrid solid electrolytes can quickly stabilize at a specific discharge capacity of 145.4 mAh·g^(-1) at 0.1 C after only 5 cycles and present admirable rate performance.In addition,morphology characterizations of the sandwiched hybrid solid electrolytes after long-term cycles show a relatively integrated structure coating with a compact LATP layer.The investigations afford a promising strategy that the sandwiched hybrid solid electrolytes can overcome the mechanical limitations of the interface between electrodes and inorganic solid electrolytes to provide favorable properties for all-solid-state lithium-ion batteries.
基金supported by the National Natural Science Foundation of China(No.51876098).
文摘Accurate predictions of Shock Waves and Boundary Layer Interaction(SWBLI)and strong Shock Waves and Wake Vortices Interaction(SWWVI)in a highly-loaded turbine propose challenges to the currently widely used Reynolds-Averaged Navier-Stokes(RANS)model.In this work,the SWBLI and the SWWVI in a highly-loaded Nozzle Guide Vane(NGV)are studied using a hybrid RANS/LES strategy.The Turbulence Kinetic Energy(TKE)budget and the Proper Orthogonal Decomposition(POD)method are used to analyze flow mechanisms.Results show that this hybrid RANS/LES method can obtain detailed flow structures for flow mechanisms analysis.Strong shock waves induce boundary layer separation,while the presence of a separation bubble can in turn lead to a Mach reflection phenomenon.The shock waves cause trailing-edge vortices to break clearly,and the wakes,in turn,can change the shocks intensity and direction.Furthermore,the Entropy Generation Rate(EGR)is used to analyze the irreversible loss.It turns out that the SWWVI can reduce the flow field loss.There are several weak shock waves in the NGV flow field,which can increase the irreversible loss.This work offers flow mechanisms analysis and presents the EGR distribution in SWBLI and SWWVI areas in a transonic turbine blade.
基金supported by the National Natural Science Foundation of China(Grant Nos.11372330 and 11072248)the National High Technology Research and Development Program of China(Grant No.2012AA01A304)the Chinese Academy of Sciences Program(Grant Nos.KJCX2-EW-J01 and XXH12503-02-02-04)
文摘In spectral-like resolution-WENO hybrid schemes,if the switch function takes more grid points as discontinuity points,the WENO scheme is often turned on,and the numerical solutions may be too dissipative.Conversely,if the switch function takes less grid points as discontinuity points,the hybrid schemes usually are found to produce oscillatory solutions or just to be unstable.Even if the switch function takes less grid points as discontinuity points,the final hybrid scheme is inclined to be more stable,provided the spectral-like resolution scheme in the hybrid scheme has moderate shock-capturing capability.Following this idea,we propose nonlinear spectral-like schemes named weighted group velocity control(WGVC)schemes.These schemes show not only high-resolution for short waves but also moderate shock capturing capability.Then a new class of hybrid schemes is designed in which the WGVC scheme is used in smooth regions and the WENO scheme is used to capture discontinuities.These hybrid schemes show good resolution for small-scales structures and fine shock-capturing capabilities while the switch function takes less grid points as discontinuity points.The seven-order WGVC-WENO scheme has also been applied successfully to the direct numerical simulation of oblique shock wave-turbulent boundary layer interaction.
基金financially supported by the National Natural Science Foundation of China(51901249,U1904216)。
文摘Although aqueous zinc ion hybrid capacitors have advantageous integration of batteries and supercapacitors,they still suffer from the inherent problems of dendrite growth and interfacial side reactions on Zn anodes.Herein,a universal fast zinc-ion diffusion layer on a three-dimensional(3 D)mesh structure model is demonstrated to effectively improve Zn plating/stripping reversibility.The fast ion diffusion alloy layer accelerates the Zn^(2+)migration in an orderly manner to homogenize Zn^(2+)flux and overcomes the defects of the commercial mesh substrate,effectively avoiding dendrite growth and side reactions.Consequently,the proof-of-concept silver-zinc alloy modified stainless steel mesh delivers superb reversibility with the high coulombic efficiency over 99.4%at 4 mA cm^(-2)after 1600 cycles and excellent reliability of over 830 h at 1 mA cm^(-2),Its feasibility is also evidenced in commercial zinc ion hybrid capacitors with activated carbon as the cathode.This work enriches the fundamental comprehension of fast zinc-ion diffusion layer combined with a 3 D substrate on the Zn deposition and opens a universal approach to design advanced host for Zn electrodes in zinc ion hybrid capacitors.
基金supported by the National Natural Science Foundation of China(52263017,21965023,52173170,51973087,and22065025)the Science Fund for Distinguished Young Scholars of Jiangxi Province(20212ACB214009)+2 种基金the Natural Science Foundation of Jiangxi Province(20212ACB203010,20224BAB214007 and20212BAB204052)the Training Project of High-level and Highskilled Leading Talents of Jiangxi Province(2023)the Thousand Talents Plan of Jiangxi Province(jxsq2019201004 and jxsq2020101068)。
文摘Organic solar cells(OSCs)have gained conspicuous progress during the past few decades due to the development of materials and upgrading of the device structure.The power conversion efficiency(PCE)of the single-junction device had surpassed 19%.The cathode interface layer(CIL),by optimizing the connection between the active layer and the cathode electrode,has become a momentous part to strengthen the performances of the OSCs.Simultaneously,CIL is also indispensable to illustrating the working mechanism of OSCs and enhancing the stability of the OSCs.In this essay,hybrid CILs in OSCs have been summarized.Firstly,the advancement and operating mechanism of OSCs,and the effects and relevant design rules of CIL are briefly concluded;secondly,the significant influence of CIL on enhancing the stability and PCE of OSCs is presented;thirdly,the characteristics of organic hybrid CIL and organic-inorganic hybrid CIL are introduced.Finally,the conclusion and outlook of CIL are summarized.
基金Financial support from Business Finland NextGenBat[grant number 211849]is greatly acknowledged.
文摘This work made use of the Aalto University Otanano-Nanomicroscopy Center and RAMI infrastructures.Financial support from Business Finland NextGenBat[grant number 211849]is greatly acknowledged.The tomography experiment was performed at the beamline ID16B of the European Synchrotron Radiation Facility(ESRF),Grenoble,France,in the frame of proposal CH-6644.The patent titled“Stabilized Positive Electrode Material to Enable High Energy and Power Density Lithium-Ion Batteries”(IPD3173)is pertinent to this manuscript.It was filed by Zahra Ahaliabadeh and Tanja Kallio,and the patent rights are held by Aalto University.
