The Henry’s law constant of volatiles in polymer systems is a crucial parameter reflecting the gas-liquid equilibrium,which is very important for devolatilization.In this research,polyolefin elastomer(POE)-cyclohexan...The Henry’s law constant of volatiles in polymer systems is a crucial parameter reflecting the gas-liquid equilibrium,which is very important for devolatilization.In this research,polyolefin elastomer(POE)-cyclohexane and polydimethylsiloxane(PDMS)-hexane systems were studied,and the Henry’s law constant was obtained by measuring the gas phase equilibrium partial pressure when polymer solutions containing different mass fractions of volatiles reached a saturated state.The effects of temperature,type of volatiles,and polymer viscosity on the gas phase equilibrium partial pressure and Henry’s law constant of the volatiles were investigated.The results indicate that,with the increase of temperature and polymer viscosity,the gas phase equilibrium partial pressure and Henry’s law constant of volatiles increase.As temperature increases,the solubility of gas in liquid decreases.The relationship between the Henry’s law constant and temperature is consistent with the Arrhenius law.In the PDMS-hexane system,the gas phase equilibrium partial pressure and Henry’s law constant of n-hexane are higher than those of cyclohexane.The obtained Henry’s law constants can be used as a reference for perfecting the devolatilization process and improving the devolatilization effect.展开更多
Capillary filling in small length scale is an important process in nanotechnology and microfabrication. When one end of the tube or channel is sealed, it is important to consider the escape of the trapped gas. We deve...Capillary filling in small length scale is an important process in nanotechnology and microfabrication. When one end of the tube or channel is sealed, it is important to consider the escape of the trapped gas. We develop a dynamic model on capillary filling in closed-end tubes, based on the diffusion-convection equation and Henry＇s law of gas dissolution. We systematically investigate the filling dynamics for various sets of parameters, and compare the results with a previous model which assumes a linear density profile of dissolved gas and neglect the convective term.展开更多
基金Polyolefin Elastomer Technology Development project(2020B-2619).
文摘The Henry’s law constant of volatiles in polymer systems is a crucial parameter reflecting the gas-liquid equilibrium,which is very important for devolatilization.In this research,polyolefin elastomer(POE)-cyclohexane and polydimethylsiloxane(PDMS)-hexane systems were studied,and the Henry’s law constant was obtained by measuring the gas phase equilibrium partial pressure when polymer solutions containing different mass fractions of volatiles reached a saturated state.The effects of temperature,type of volatiles,and polymer viscosity on the gas phase equilibrium partial pressure and Henry’s law constant of the volatiles were investigated.The results indicate that,with the increase of temperature and polymer viscosity,the gas phase equilibrium partial pressure and Henry’s law constant of volatiles increase.As temperature increases,the solubility of gas in liquid decreases.The relationship between the Henry’s law constant and temperature is consistent with the Arrhenius law.In the PDMS-hexane system,the gas phase equilibrium partial pressure and Henry’s law constant of n-hexane are higher than those of cyclohexane.The obtained Henry’s law constants can be used as a reference for perfecting the devolatilization process and improving the devolatilization effect.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.21434001,21504004,and 21774004)
文摘Capillary filling in small length scale is an important process in nanotechnology and microfabrication. When one end of the tube or channel is sealed, it is important to consider the escape of the trapped gas. We develop a dynamic model on capillary filling in closed-end tubes, based on the diffusion-convection equation and Henry＇s law of gas dissolution. We systematically investigate the filling dynamics for various sets of parameters, and compare the results with a previous model which assumes a linear density profile of dissolved gas and neglect the convective term.
