In this paper. it is discussed how to constrnct wavefunctions of L-S couplingfermion system, which are classified by group chain A recurrent formula of fractional parentage coefficients with fixedseniority is also g...In this paper. it is discussed how to constrnct wavefunctions of L-S couplingfermion system, which are classified by group chain A recurrent formula of fractional parentage coefficients with fixedseniority is also given.展开更多
An irreducible tensor method based on M. O. theory for solving many-body Schrodinger equation of valence-electron system of metal complexes has been proposed. Electronic structures of several typical octahedral transi...An irreducible tensor method based on M. O. theory for solving many-body Schrodinger equation of valence-electron system of metal complexes has been proposed. Electronic structures of several typical octahedral transition metal complexes have been studied by means of this method. Calculated excitation energies agree with observed ones within several kcm-1.展开更多
The wavefunctions of L-S coupling fermion system, which are classified by group chain U(4ι1 + 4ι2 + 4) Us(2)×(U L(2ι+ 2ι2 + 2) O(2ι1 + 2ι2 + 2) O(2ι+1) ×O(2ι2 + 1) O1 (3)×O2 (3) O(3)), are const...The wavefunctions of L-S coupling fermion system, which are classified by group chain U(4ι1 + 4ι2 + 4) Us(2)×(U L(2ι+ 2ι2 + 2) O(2ι1 + 2ι2 + 2) O(2ι+1) ×O(2ι2 + 1) O1 (3)×O2 (3) O(3)), are constructed through introducing generalized pairs coupled by fermions with different ι. With the help of the fractional parentage coefficients of single-ιfermion system, the author obtains the corresponding fractional parentage coefficients of double-ιfermion system.展开更多
文摘In this paper. it is discussed how to constrnct wavefunctions of L-S couplingfermion system, which are classified by group chain A recurrent formula of fractional parentage coefficients with fixedseniority is also given.
基金Project supported by the National Natural Science Foundation of China.
文摘An irreducible tensor method based on M. O. theory for solving many-body Schrodinger equation of valence-electron system of metal complexes has been proposed. Electronic structures of several typical octahedral transition metal complexes have been studied by means of this method. Calculated excitation energies agree with observed ones within several kcm-1.
文摘The wavefunctions of L-S coupling fermion system, which are classified by group chain U(4ι1 + 4ι2 + 4) Us(2)×(U L(2ι+ 2ι2 + 2) O(2ι1 + 2ι2 + 2) O(2ι+1) ×O(2ι2 + 1) O1 (3)×O2 (3) O(3)), are constructed through introducing generalized pairs coupled by fermions with different ι. With the help of the fractional parentage coefficients of single-ιfermion system, the author obtains the corresponding fractional parentage coefficients of double-ιfermion system.
