Novel graphene nanosheet （GNS） supported Cu-Ni bimetal catalysts were firstly synthesized and used for the direct synthesis of dimethyl carbonate （DMC）. The experimental results demonstrated that GNS was an effect...Novel graphene nanosheet （GNS） supported Cu-Ni bimetal catalysts were firstly synthesized and used for the direct synthesis of dimethyl carbonate （DMC）. The experimental results demonstrated that GNS was an effective and convenient support for the fabrication of Cu-Ni/GNS bimetal catalyst.展开更多
采用氧化-还原法制备了石墨烯纳米片(GNS);然后将GNS加入到苯并噁嗪(BOZ)/环氧树脂(EP)体系中,制成了GNS/BOZ/EP复合材料。采用红外光谱(FT-IR)、透射电镜(TEM)和X射线衍射(XRD)法等对所得GNS的结构进行了表征和分析,同时研究了复合材...采用氧化-还原法制备了石墨烯纳米片(GNS);然后将GNS加入到苯并噁嗪(BOZ)/环氧树脂(EP)体系中,制成了GNS/BOZ/EP复合材料。采用红外光谱(FT-IR)、透射电镜(TEM)和X射线衍射(XRD)法等对所得GNS的结构进行了表征和分析,同时研究了复合材料的力学性能和耐热性。研究结果表明:GNS能提高BOZ/EP体系的力学性能和耐热性;当w(GNS)=0.2%(相对于复合材料总质量而言)时,GNS/BOZ/EP体系的综合性能相对最优,其冲击强度(14.2 k J/m2)比BOZ/EP体系提高了14.5%左右,弯曲强度达到了139 MPa,最初热分解温度和最大热分解温度(分别为299.7、353.4℃)均有所提高。展开更多
基金The authors would like to thank the Key Research Fund Program of Xihua University(No.Z0910109)for financial support of this researchZ.Guan.thanks National University of Singapore for financial support
文摘Novel graphene nanosheet （GNS） supported Cu-Ni bimetal catalysts were firstly synthesized and used for the direct synthesis of dimethyl carbonate （DMC）. The experimental results demonstrated that GNS was an effective and convenient support for the fabrication of Cu-Ni/GNS bimetal catalyst.
文摘采用氧化-还原法制备了石墨烯纳米片(GNS);然后将GNS加入到苯并噁嗪(BOZ)/环氧树脂(EP)体系中,制成了GNS/BOZ/EP复合材料。采用红外光谱(FT-IR)、透射电镜(TEM)和X射线衍射(XRD)法等对所得GNS的结构进行了表征和分析,同时研究了复合材料的力学性能和耐热性。研究结果表明:GNS能提高BOZ/EP体系的力学性能和耐热性;当w(GNS)=0.2%(相对于复合材料总质量而言)时,GNS/BOZ/EP体系的综合性能相对最优,其冲击强度(14.2 k J/m2)比BOZ/EP体系提高了14.5%左右,弯曲强度达到了139 MPa,最初热分解温度和最大热分解温度(分别为299.7、353.4℃)均有所提高。
