以给水处理厂废弃铁铝泥(ferric and alum water treatment residuals,FARs)为载体,考察了不同粒径FARs对砷(Ⅲ)的吸附效果.不同粒径FARs的有效铁铝含量、比表面积和孔体积分别为523.72～1 861.72 mmol.kg-1、28.15～265.59 m2.g-1和0.0...以给水处理厂废弃铁铝泥(ferric and alum water treatment residuals,FARs)为载体,考察了不同粒径FARs对砷(Ⅲ)的吸附效果.不同粒径FARs的有效铁铝含量、比表面积和孔体积分别为523.72～1 861.72 mmol.kg-1、28.15～265.59 m2.g-1和0.03～0.09 cm3.g-1,总有机质、富里酸、胡敏酸和胡敏素分别为46.97～91.58、0.02～32.27、22.27～34.09和10.76～34.22 mg.kg-1.SEM和XRD检测表明,不同粒径FARs均以无定形结构存在.批量实验结果表明,准一级和准二级动力学方程均能较好地反映FARs吸附砷(Ⅲ)的动力学过程.不同粒径FARs对砷(Ⅲ)的吸附量随着浓度的增加而增高,用Langmuir等温线方程拟合获得理论饱和吸附量在6.72～21.79 mg.g-1之间.pH值对FARs吸附砷(Ⅲ)的作用影响不大.砷(Ⅲ)吸附量大小与不同粒径FARs的理化性质的变化趋势基本一致,由相关性分析可得,有效铁铝含量和孔体积大小是影响FARs对砷(Ⅲ)吸附的主要因素.展开更多
采用Gleeble-1500热模拟试验机对不同晶粒尺寸的7A04铝合金进行了热压缩试验,研究了变形温度为320~480℃、应变速率为0.001~1 s-1时的晶粒尺寸对热变形行为的影响。利用金相显微镜分析了合金的微观组织。结果表明：在相同变形条件下,粗...采用Gleeble-1500热模拟试验机对不同晶粒尺寸的7A04铝合金进行了热压缩试验,研究了变形温度为320~480℃、应变速率为0.001~1 s-1时的晶粒尺寸对热变形行为的影响。利用金相显微镜分析了合金的微观组织。结果表明：在相同变形条件下,粗晶铝合金流变应力明显高于细晶铝合金的流变应力。不同晶粒尺寸的塑性变形机制在320、480℃分别为动态回复和动态再结晶。粗晶与细晶7A04铝合金的本构方程存在明显的差异,其热激活能分别为143.4、125.6 k J/mol。展开更多
To optimize the magnetic properties of nanocomposite Nd9Fe85B6 magnets, the as-quenched ribbons with different microstructures were prepared at six wheel velocities from 10 to 30 m s^-1through rapid quenching,followed...To optimize the magnetic properties of nanocomposite Nd9Fe85B6 magnets, the as-quenched ribbons with different microstructures were prepared at six wheel velocities from 10 to 30 m s^-1through rapid quenching,followed by a series of annealing treatments at 550-800 °C for 5-10 min. It is found that both the large initial grains at low cooling rate and high content of amorphous phase at high cooling rate cause a-Fe grains coarsening, which leads to a decline in the strength of exchange coupling interaction and the deterioration of magnetic properties. In order to optimize the magnetic properties, the as-quenched ribbons should be chosen with relatively small initial grains as well as a small amount of amorphous phase. For nanocomposite Nd9Fe85B6 materials, the optimized magnetic properties of Hcj= 446 kA m^-1, Br= 0.86 T,（BH）max=80 kJ m^-3are obtained for ribbons prepared at 18 m s-1after annealing at 620 °C for 5 min.展开更多
Generally, sediment in natural rivers is non-uniform, and sorption capacities of different grain sizes vary greatly. In order to quantitatively describe sorption of heavy metal pollutant by sediment in natural rivers,...Generally, sediment in natural rivers is non-uniform, and sorption capacities of different grain sizes vary greatly. In order to quantitatively describe sorption of heavy metal pollutant by sediment in natural rivers, the concurrent sorption by sediment of different grain sizes should be studied. By combining systematic laboratory experiments and theoretical analysis the concurrent equilibrium sorption model and the concurrent sorption dynamic model by sediment of different grain sizes have been set up. Both of them indicate that there is no competition or interference among different grain sizes, its sorption content of unit weight of sediment is the sum of the sorption contents of each grain sizes , and the content of each grain size in non-uniform sediment. Furthermore, formulas for determining characteristic parameters ( b and k) in the Langmuir sorption isotherm for non-uniform sediment are deduced as follows:These can be used as a tool for predicting the sorption content of non-uniform sediment in natural rivers.展开更多
文摘采用Gleeble-1500热模拟试验机对不同晶粒尺寸的7A04铝合金进行了热压缩试验,研究了变形温度为320~480℃、应变速率为0.001~1 s-1时的晶粒尺寸对热变形行为的影响。利用金相显微镜分析了合金的微观组织。结果表明：在相同变形条件下,粗晶铝合金流变应力明显高于细晶铝合金的流变应力。不同晶粒尺寸的塑性变形机制在320、480℃分别为动态回复和动态再结晶。粗晶与细晶7A04铝合金的本构方程存在明显的差异,其热激活能分别为143.4、125.6 k J/mol。
基金financially supported by the Project of Xicheng District Science and Technology Plans (No. XCKJJH2013-33)
文摘To optimize the magnetic properties of nanocomposite Nd9Fe85B6 magnets, the as-quenched ribbons with different microstructures were prepared at six wheel velocities from 10 to 30 m s^-1through rapid quenching,followed by a series of annealing treatments at 550-800 °C for 5-10 min. It is found that both the large initial grains at low cooling rate and high content of amorphous phase at high cooling rate cause a-Fe grains coarsening, which leads to a decline in the strength of exchange coupling interaction and the deterioration of magnetic properties. In order to optimize the magnetic properties, the as-quenched ribbons should be chosen with relatively small initial grains as well as a small amount of amorphous phase. For nanocomposite Nd9Fe85B6 materials, the optimized magnetic properties of Hcj= 446 kA m^-1, Br= 0.86 T,（BH）max=80 kJ m^-3are obtained for ribbons prepared at 18 m s-1after annealing at 620 °C for 5 min.
基金Natural Science Foundation of Chinathe Post-doctoral Science Foundation of China and the Youth Teacher’ Foudation Beijing Normal University.
文摘Generally, sediment in natural rivers is non-uniform, and sorption capacities of different grain sizes vary greatly. In order to quantitatively describe sorption of heavy metal pollutant by sediment in natural rivers, the concurrent sorption by sediment of different grain sizes should be studied. By combining systematic laboratory experiments and theoretical analysis the concurrent equilibrium sorption model and the concurrent sorption dynamic model by sediment of different grain sizes have been set up. Both of them indicate that there is no competition or interference among different grain sizes, its sorption content of unit weight of sediment is the sum of the sorption contents of each grain sizes , and the content of each grain size in non-uniform sediment. Furthermore, formulas for determining characteristic parameters ( b and k) in the Langmuir sorption isotherm for non-uniform sediment are deduced as follows:These can be used as a tool for predicting the sorption content of non-uniform sediment in natural rivers.
