天然气水合物饱和度是评估天然气水合物资源量的重要参数,而用来估算饱和度的速度模型则是有限的几个,它们有的为经验公式,有的是以实验数据或野外资料为基础建立起来的,需要进行实验验证和参数分析以确定其使用的适用性.本文首次利用...天然气水合物饱和度是评估天然气水合物资源量的重要参数,而用来估算饱和度的速度模型则是有限的几个,它们有的为经验公式,有的是以实验数据或野外资料为基础建立起来的,需要进行实验验证和参数分析以确定其使用的适用性.本文首次利用超声和时域反射联合探测技术,研究了沉积物中水合物饱和度与声学特性的关系.并对时间平均方程、伍德及其修正方程、李权重方程和BGTL(Biot-Gassmann Theory by Lee)理论等常用的水合物饱和度估算模型进行了验证.实验结果表明,超声和时域反射联合探测技术能有效地实时获得水合物饱和度和纵、横波速的实验数据,李权重方程和BGTL理论的速度预测值与实验值比较吻合,有广泛的适用性.展开更多
An ultrasonic system(20 kHz,0—150 W) of natural gas hydrate formation was built up to investigate the induction time of gas hydrate formation in the presence of sodium dodecyl sulfate (SDS).The experimental results i...An ultrasonic system(20 kHz,0—150 W) of natural gas hydrate formation was built up to investigate the induction time of gas hydrate formation in the presence of sodium dodecyl sulfate (SDS).The experimental results indicated that the concentration of SDS solution did not affect the induction time distinctly and no critical micelle concentration(CMC) phenomenon was observed.The induction time decreased with the increase of ultrasonic power or reaction pressure.展开更多
In this study, visualizations and experiments are carried out on the influence of static and rotating magnetic fields on the characteristics of HCFC-141b gas hydrate formation, such as crystallization form, formation ...In this study, visualizations and experiments are carried out on the influence of static and rotating magnetic fields on the characteristics of HCFC-141b gas hydrate formation, such as crystallization form, formation temperature and induction time. It has been found that a proper rotating magnetic field can considerably improve the low-pressure gas hydrate formation process, especially in increasing the formation temperature and shortening the induction time. The mor- phology of the gas hydrate formation appears rather complex and compact. However, a proper static magnetic field can make the gas hydrate crystal more organized, which will be benefit to heat transfer.展开更多
The focus of this study is to investigate the influence of memory effect and the relation of its existence with the dissociation temperature,using gas hydrate formation and dissociation experiments.This is beneficial ...The focus of this study is to investigate the influence of memory effect and the relation of its existence with the dissociation temperature,using gas hydrate formation and dissociation experiments.This is beneficial because memory effect is considered as an effective approach to promote the thermodynamic and dynamic conditions of gas hydrate nucleation.Seven experimental systems （twenty tests in total） were performed in a 1 L pressure cell.Three types of hydrate morphology,namely massive,whiskery and jelly crystals were present in the experiments.The pressures and temperatures at the time when visual hydrate crystals appeared were measured.Furthermore,the influence of memory effect was quantified in terms of pressure-temperature-time （p-T-t） relations.The results revealed that memory effect could promote the thermodynamic conditions and shorten the induction time when the dissociation temperature was not higher than 25℃.In this study,the nucleation superpressure and induction time decrease gradually with time of tests,when the earlier and the later tests are compared.It is assumed that the residual structure of hydrate dissociation,as the source of the memory effect,provides a site for mass transfer between host and guest molecules.Therefore,a driving force is created between the residual structures and its surrounding bulk phase to promote the hydrate nucleation.However,when the dissociation temperature was higher than 25 ℃,the memory effect vanished.These findings provide references for the application of memory effect in hydrate-based technology.展开更多
文摘天然气水合物饱和度是评估天然气水合物资源量的重要参数,而用来估算饱和度的速度模型则是有限的几个,它们有的为经验公式,有的是以实验数据或野外资料为基础建立起来的,需要进行实验验证和参数分析以确定其使用的适用性.本文首次利用超声和时域反射联合探测技术,研究了沉积物中水合物饱和度与声学特性的关系.并对时间平均方程、伍德及其修正方程、李权重方程和BGTL(Biot-Gassmann Theory by Lee)理论等常用的水合物饱和度估算模型进行了验证.实验结果表明,超声和时域反射联合探测技术能有效地实时获得水合物饱和度和纵、横波速的实验数据,李权重方程和BGTL理论的速度预测值与实验值比较吻合,有广泛的适用性.
文摘An ultrasonic system(20 kHz,0—150 W) of natural gas hydrate formation was built up to investigate the induction time of gas hydrate formation in the presence of sodium dodecyl sulfate (SDS).The experimental results indicated that the concentration of SDS solution did not affect the induction time distinctly and no critical micelle concentration(CMC) phenomenon was observed.The induction time decreased with the increase of ultrasonic power or reaction pressure.
基金This work was supported by the National Natural Science Foundation of China(Grant Nos.20076046 and 59836230).
文摘In this study, visualizations and experiments are carried out on the influence of static and rotating magnetic fields on the characteristics of HCFC-141b gas hydrate formation, such as crystallization form, formation temperature and induction time. It has been found that a proper rotating magnetic field can considerably improve the low-pressure gas hydrate formation process, especially in increasing the formation temperature and shortening the induction time. The mor- phology of the gas hydrate formation appears rather complex and compact. However, a proper static magnetic field can make the gas hydrate crystal more organized, which will be benefit to heat transfer.
基金supported by the National Natural Science Foundation(No.50874040,No.50904026)Heilongjiang Provincial Natural Science Foundation(No.B2007-10)Harbin Innovation Talent of Science and Technology Foundation(No.2007RFXXS050,No.2008RFQXG111)
文摘The focus of this study is to investigate the influence of memory effect and the relation of its existence with the dissociation temperature,using gas hydrate formation and dissociation experiments.This is beneficial because memory effect is considered as an effective approach to promote the thermodynamic and dynamic conditions of gas hydrate nucleation.Seven experimental systems （twenty tests in total） were performed in a 1 L pressure cell.Three types of hydrate morphology,namely massive,whiskery and jelly crystals were present in the experiments.The pressures and temperatures at the time when visual hydrate crystals appeared were measured.Furthermore,the influence of memory effect was quantified in terms of pressure-temperature-time （p-T-t） relations.The results revealed that memory effect could promote the thermodynamic conditions and shorten the induction time when the dissociation temperature was not higher than 25℃.In this study,the nucleation superpressure and induction time decrease gradually with time of tests,when the earlier and the later tests are compared.It is assumed that the residual structure of hydrate dissociation,as the source of the memory effect,provides a site for mass transfer between host and guest molecules.Therefore,a driving force is created between the residual structures and its surrounding bulk phase to promote the hydrate nucleation.However,when the dissociation temperature was higher than 25 ℃,the memory effect vanished.These findings provide references for the application of memory effect in hydrate-based technology.
