To optimize industrial Fischer-Tropsch （IT） synthesis with the slurry bubble column reactor （SBCR） and iron- based catalyst, a comprehensive process model for IT synthesis that includes a detailed SBCR model, gas ...To optimize industrial Fischer-Tropsch （IT） synthesis with the slurry bubble column reactor （SBCR） and iron- based catalyst, a comprehensive process model for IT synthesis that includes a detailed SBCR model, gas liquid separation model, simplified CO2 removal model and tail gas cycle model was developed. An effective iteration algorithm was proposed to solve this process model, and the model was validated by industrial demonstration experiments data （SBCR with 5.8 m diameter and 30 m height）, with a maximum relative error 〈 10% for predicting the SBCR performances. Subsequently, the proposed model was adopted to optimize the industrial SBCR performances simultaneously considering process and reactor parameters variations. The results show that C5＋yield increases as catalyst loading increases within 10-70 ton and syngas H2/CO value decreases within 1.3-1.6, but it doesn＇t increase obviously when the catalyst loading exceeds 45 ton （about 15 wt% concentration）. Higher catalyst loading will result in higher difficulty for wax/catalyst separation and higher catalyst cost. There- fore, the catalyst loading （45 ton） is recommended for the industrial demonstration SBCR operation at syngas H2/ CO = 1.3, and the C5 ＋ yield is about 402 ton＂ per day, which has an about 16% increase than the industrial dem- onstration run result.展开更多
A novel process for catalytic oxidation of methane to synthesis gas (syngas), which consists of two consecutive fixed-bed reactors with air introduced into the reactors, integrated Fischer-Tropsch synthesis, was inves...A novel process for catalytic oxidation of methane to synthesis gas (syngas), which consists of two consecutive fixed-bed reactors with air introduced into the reactors, integrated Fischer-Tropsch synthesis, was investigated. At the same time, a catalytic combustion technology has been investigated for utilizing the F-T offgas to generate heat or power energy. The results show that the two-stage fixed reactor process keep away from explosion of CH4/O2. The integrated process is fitted to produce diesel oil and lubricating oil in remote gas field.展开更多
基金Supported by the National Key R&D Program of China(2017YFB0602500)
文摘To optimize industrial Fischer-Tropsch （IT） synthesis with the slurry bubble column reactor （SBCR） and iron- based catalyst, a comprehensive process model for IT synthesis that includes a detailed SBCR model, gas liquid separation model, simplified CO2 removal model and tail gas cycle model was developed. An effective iteration algorithm was proposed to solve this process model, and the model was validated by industrial demonstration experiments data （SBCR with 5.8 m diameter and 30 m height）, with a maximum relative error 〈 10% for predicting the SBCR performances. Subsequently, the proposed model was adopted to optimize the industrial SBCR performances simultaneously considering process and reactor parameters variations. The results show that C5＋yield increases as catalyst loading increases within 10-70 ton and syngas H2/CO value decreases within 1.3-1.6, but it doesn＇t increase obviously when the catalyst loading exceeds 45 ton （about 15 wt% concentration）. Higher catalyst loading will result in higher difficulty for wax/catalyst separation and higher catalyst cost. There- fore, the catalyst loading （45 ton） is recommended for the industrial demonstration SBCR operation at syngas H2/ CO = 1.3, and the C5 ＋ yield is about 402 ton＂ per day, which has an about 16% increase than the industrial dem- onstration run result.
基金Supported by the Major State Basic Research Projects of the Ministry of Science and Technology of China (G1999022402).
文摘A novel process for catalytic oxidation of methane to synthesis gas (syngas), which consists of two consecutive fixed-bed reactors with air introduced into the reactors, integrated Fischer-Tropsch synthesis, was investigated. At the same time, a catalytic combustion technology has been investigated for utilizing the F-T offgas to generate heat or power energy. The results show that the two-stage fixed reactor process keep away from explosion of CH4/O2. The integrated process is fitted to produce diesel oil and lubricating oil in remote gas field.
