Eichhornia crassipes is a hyperaccumulator of metals and has been widely used to remove metal pollutants from water, but disposal of contaminated plants is problematic.Biochar prepared from plants is commonly used to ...Eichhornia crassipes is a hyperaccumulator of metals and has been widely used to remove metal pollutants from water, but disposal of contaminated plants is problematic.Biochar prepared from plants is commonly used to remediate soils and sequester carbon.Here, the catalytic activity of biochar prepared from plants enriched with iron was investigated as a potentially beneficial use of metal-contaminated plants.In a 30-day hydroponic experiment, E.crassipes was exposed to different concentrations of Fe(Ⅲ)(0, 4, 8, 16, 32 and 64 mg/L), and Fe-biochar(Fe-BC) was prepared by pyrolysis of the plant roots.The biochar was characterized using X-ray diffraction(XRD), scanning electron microscopy(SEM), energy dispersive X-ray spectrometry(EDS), Brunauer–Emmett–Teller(BET) analysis, X-ray photoelectron spectroscopy(XPS) and atomic absorption spectrometry(AAS).The original root morphology was visible and iron was present as γ-Fe2O3 and Fe3O4.The biochar enriched with Fe(Ⅲ) at 8 mg/L(8-Fe-BC) had the smallest specific surface area(SSA, 13.54 m^2/g) and the highest Fe content(27.9 mg/g).Fe-BC catalytic activity was tested in the electrocatalytic reduction of H2O2 using cyclic voltammetry(CV).The largest reduction current(1.82 mA/cm^2) was displayed by 8-Fe-BC, indicating the highest potential catalytic activity.We report here, for the first time, on the catalytic activity of biochar made from iron-enriched plants and demonstrate the potential for reusing metalcontaminated plants to produce a biochar catalyst.展开更多
基金supported by supported by the National Natural Science Foundation of China (Nos.21677086 and 21577078)Hubei Innovation Group Project (No.2015CFA021)+1 种基金the Hubei Foreign Science and Technology Cooperation Project (No.2018AHB020)Three Gorges University Master’s Thesis Training Fund (No.2018SSPY143).
文摘Eichhornia crassipes is a hyperaccumulator of metals and has been widely used to remove metal pollutants from water, but disposal of contaminated plants is problematic.Biochar prepared from plants is commonly used to remediate soils and sequester carbon.Here, the catalytic activity of biochar prepared from plants enriched with iron was investigated as a potentially beneficial use of metal-contaminated plants.In a 30-day hydroponic experiment, E.crassipes was exposed to different concentrations of Fe(Ⅲ)(0, 4, 8, 16, 32 and 64 mg/L), and Fe-biochar(Fe-BC) was prepared by pyrolysis of the plant roots.The biochar was characterized using X-ray diffraction(XRD), scanning electron microscopy(SEM), energy dispersive X-ray spectrometry(EDS), Brunauer–Emmett–Teller(BET) analysis, X-ray photoelectron spectroscopy(XPS) and atomic absorption spectrometry(AAS).The original root morphology was visible and iron was present as γ-Fe2O3 and Fe3O4.The biochar enriched with Fe(Ⅲ) at 8 mg/L(8-Fe-BC) had the smallest specific surface area(SSA, 13.54 m^2/g) and the highest Fe content(27.9 mg/g).Fe-BC catalytic activity was tested in the electrocatalytic reduction of H2O2 using cyclic voltammetry(CV).The largest reduction current(1.82 mA/cm^2) was displayed by 8-Fe-BC, indicating the highest potential catalytic activity.We report here, for the first time, on the catalytic activity of biochar made from iron-enriched plants and demonstrate the potential for reusing metalcontaminated plants to produce a biochar catalyst.
