The magnetic moment and the magnetostriction decrease slightly with the increase of total Si+B content.A maximum of the Curie temperature appears at about 25 at.-% of Si+B.The magnetic anisotropy is uninfluential by t...The magnetic moment and the magnetostriction decrease slightly with the increase of total Si+B content.A maximum of the Curie temperature appears at about 25 at.-% of Si+B.The magnetic anisotropy is uninfluential by the content of Si+B,but much influnce by the demagnetization effect of streak.A qualitative explanation of the experimental phenomenon seems to be noted by the aid of the electron transition and structure model of amorphous al- loys.展开更多
The dependence of composition varied,especially C,Si,Cr,Cu and Co in four amorphous alloy systems Fe_(80-x)Cr_xSi_5B_(15).Fe_(80-x)Cr_xC_5B_(15).Fe_(80-x)Cu_xSi_5B_(15)and (Fe_(1-x)Co_x)_(82)Cu_(0.4)Si_(4.4)B_(13.2)up...The dependence of composition varied,especially C,Si,Cr,Cu and Co in four amorphous alloy systems Fe_(80-x)Cr_xSi_5B_(15).Fe_(80-x)Cr_xC_5B_(15).Fe_(80-x)Cu_xSi_5B_(15)and (Fe_(1-x)Co_x)_(82)Cu_(0.4)Si_(4.4)B_(13.2)upon their saturation magnetostriction at room temperature has been studied.It was observed that the saturation magnetostriction of the alloys may be re- markably improved by small addition of Cu and Co.the peak value being up to 70×10^(-6)as x=0.02 in alloys(Fe_(1-x)Co_x)_(82)Cu_(0.4)Si_(4.4)B_(13.2).展开更多
The amorphous Fe78Si9B13 alloy was used as a heterogeneous Fenton catalyst in the process of phenol degradation.The influences of main operating parameters such as reaction temperature,catalyst amount,hydrogen peroxid...The amorphous Fe78Si9B13 alloy was used as a heterogeneous Fenton catalyst in the process of phenol degradation.The influences of main operating parameters such as reaction temperature,catalyst amount,hydrogen peroxide dosage and initial pH of solution on phenol degradation rate were investigated.The maximum mineralization of phenol was achieved at 60°C,6 g/L Fe78Si9B13, 0.31 mol/L hydrogen peroxide,with an initial pH of 2.5.More than 99%of phenol was completely removed under the optimum conditions within 10 min for a solution containing 1000 mg/L of phenol.Batch experiments for solutions containing phenol con- centrations ranging from 50 to 2000 mg/L were investigated under the above conditions and the same excellent degradation rate was obtained.The Fe78Si9B13 showed better catalytic activity than iron powder and Fe 2+ .Addition of n-butannol(hydroxyl radical scavenger)decreased the degradation rate of phenol,which demonstrates that hydroxyl radicals were mainly responsible for the removal of phenol.We demonstrated that phenol may be degraded by hydroxyl radicals decomposed by hydrogen peroxide on the surface of Fe78Si9B13 and illustrated the reaction mechanism for this process.This amorphous alloy exhibited high stability in recycling experiments and showed excellent reuse performance even after continuous operations of 8 cycles.展开更多
采用分段机械球磨-放电等离子烧结法,进行了节能变压器用新型非晶合金Fe77Si9B13Ce0.5Nb0.2Cr0.3,并进行了XRD、SEM分析和软磁性能、力学性能和耐腐蚀性能的测试。结果表明,与现有非晶合金Fe78Si9B13相比,该新型非晶合金的软磁性能、力...采用分段机械球磨-放电等离子烧结法,进行了节能变压器用新型非晶合金Fe77Si9B13Ce0.5Nb0.2Cr0.3,并进行了XRD、SEM分析和软磁性能、力学性能和耐腐蚀性能的测试。结果表明,与现有非晶合金Fe78Si9B13相比,该新型非晶合金的软磁性能、力学性能和耐腐蚀性能均得到明显改善,其中初始磁导率和饱和磁感应强度分别增加了70%、32%,20℃时试样的抗拉强度和伸长率分别增加36%、4.4%,腐蚀电位正移268 m V。展开更多
文摘The magnetic moment and the magnetostriction decrease slightly with the increase of total Si+B content.A maximum of the Curie temperature appears at about 25 at.-% of Si+B.The magnetic anisotropy is uninfluential by the content of Si+B,but much influnce by the demagnetization effect of streak.A qualitative explanation of the experimental phenomenon seems to be noted by the aid of the electron transition and structure model of amorphous al- loys.
文摘The dependence of composition varied,especially C,Si,Cr,Cu and Co in four amorphous alloy systems Fe_(80-x)Cr_xSi_5B_(15).Fe_(80-x)Cr_xC_5B_(15).Fe_(80-x)Cu_xSi_5B_(15)and (Fe_(1-x)Co_x)_(82)Cu_(0.4)Si_(4.4)B_(13.2)upon their saturation magnetostriction at room temperature has been studied.It was observed that the saturation magnetostriction of the alloys may be re- markably improved by small addition of Cu and Co.the peak value being up to 70×10^(-6)as x=0.02 in alloys(Fe_(1-x)Co_x)_(82)Cu_(0.4)Si_(4.4)B_(13.2).
基金supported by the National Basic Research Program of China(2007CB613901)the National Natural Science Foundation of China(50871062 and 50831003)the Natural Science Foundation of Shandong Province(Z2008F08)
文摘The amorphous Fe78Si9B13 alloy was used as a heterogeneous Fenton catalyst in the process of phenol degradation.The influences of main operating parameters such as reaction temperature,catalyst amount,hydrogen peroxide dosage and initial pH of solution on phenol degradation rate were investigated.The maximum mineralization of phenol was achieved at 60°C,6 g/L Fe78Si9B13, 0.31 mol/L hydrogen peroxide,with an initial pH of 2.5.More than 99%of phenol was completely removed under the optimum conditions within 10 min for a solution containing 1000 mg/L of phenol.Batch experiments for solutions containing phenol con- centrations ranging from 50 to 2000 mg/L were investigated under the above conditions and the same excellent degradation rate was obtained.The Fe78Si9B13 showed better catalytic activity than iron powder and Fe 2+ .Addition of n-butannol(hydroxyl radical scavenger)decreased the degradation rate of phenol,which demonstrates that hydroxyl radicals were mainly responsible for the removal of phenol.We demonstrated that phenol may be degraded by hydroxyl radicals decomposed by hydrogen peroxide on the surface of Fe78Si9B13 and illustrated the reaction mechanism for this process.This amorphous alloy exhibited high stability in recycling experiments and showed excellent reuse performance even after continuous operations of 8 cycles.
文摘采用分段机械球磨-放电等离子烧结法,进行了节能变压器用新型非晶合金Fe77Si9B13Ce0.5Nb0.2Cr0.3,并进行了XRD、SEM分析和软磁性能、力学性能和耐腐蚀性能的测试。结果表明,与现有非晶合金Fe78Si9B13相比,该新型非晶合金的软磁性能、力学性能和耐腐蚀性能均得到明显改善,其中初始磁导率和饱和磁感应强度分别增加了70%、32%,20℃时试样的抗拉强度和伸长率分别增加36%、4.4%,腐蚀电位正移268 m V。
