The electron-hole exchange interaction significantly influences the optical properties of excitons and radiative decay. However, exciton dynamics in luminescent carbon dots (Cdots) is still not clear. In this study,...The electron-hole exchange interaction significantly influences the optical properties of excitons and radiative decay. However, exciton dynamics in luminescent carbon dots (Cdots) is still not clear. In this study, we have developed a simple and efficient one-step strategy to synthesize luminescent Cdots using the pyrolysis of oleylamine. The sp^2 clusters of a few aromatic rings are responsible for the observed blue photoluminescence. The size of these clusters can be tuned by controlling the reaction time, and the energy gap between the π-π* states of the sp^2 domains decreases as the sp^2 cluster size increases. More importantly, the strong electron-hole exchange interaction results in the splitting of the exciton states of the sp^2 clusters into the singlet-bright and triplet-dark states with an energy difference ΔE, which decreases with increasing sp^2 cluster size owing to the reduction of the confinement energy and the suppression of the electron-hole exchange interaction.展开更多
The asymmetric parabolic double quantum wells (DQWs) with resonant levels (the ground state energy in one well co-incides with the first excited state energy in another well) is analyzed. The splitting of these levels...The asymmetric parabolic double quantum wells (DQWs) with resonant levels (the ground state energy in one well co-incides with the first excited state energy in another well) is analyzed. The splitting of these levels and the tunneling times are calculated. If the typical life time of the excited state is much smaller than the tunneling time between wells, the charged particle can radiate as a result of the quantum transition from the excited state to the ground state. In the opposite case, the asymmetric DQWs can be treated as a metastable excited nanosystem regardless of that the dipole transition from the excited state to ground state is permitted. The lifetime of this metastable state can be considerably reduced by putting it into a resonant cavity. The possibility of coherent radiation of an ensemble of asymmetric DQWS is discussed.展开更多
基金supported by the National Natural Science Foundation of China(11504041)the Fundamental Research Funds for the Central Universities of China(DUT16LAB01,DUT17LAB19)the Supercomputing Center of Dalian University of Technology,China~~
文摘The electron-hole exchange interaction significantly influences the optical properties of excitons and radiative decay. However, exciton dynamics in luminescent carbon dots (Cdots) is still not clear. In this study, we have developed a simple and efficient one-step strategy to synthesize luminescent Cdots using the pyrolysis of oleylamine. The sp^2 clusters of a few aromatic rings are responsible for the observed blue photoluminescence. The size of these clusters can be tuned by controlling the reaction time, and the energy gap between the π-π* states of the sp^2 domains decreases as the sp^2 cluster size increases. More importantly, the strong electron-hole exchange interaction results in the splitting of the exciton states of the sp^2 clusters into the singlet-bright and triplet-dark states with an energy difference ΔE, which decreases with increasing sp^2 cluster size owing to the reduction of the confinement energy and the suppression of the electron-hole exchange interaction.
文摘The asymmetric parabolic double quantum wells (DQWs) with resonant levels (the ground state energy in one well co-incides with the first excited state energy in another well) is analyzed. The splitting of these levels and the tunneling times are calculated. If the typical life time of the excited state is much smaller than the tunneling time between wells, the charged particle can radiate as a result of the quantum transition from the excited state to the ground state. In the opposite case, the asymmetric DQWs can be treated as a metastable excited nanosystem regardless of that the dipole transition from the excited state to ground state is permitted. The lifetime of this metastable state can be considerably reduced by putting it into a resonant cavity. The possibility of coherent radiation of an ensemble of asymmetric DQWS is discussed.