An isotopic study was systemically carried out on the granitic complex,diorite-porphyrite, ores and ore minerals of the 103 Ma Xiaoxinancha gold-rich copper deposit in Jilin province to determine the geodynamic model ...An isotopic study was systemically carried out on the granitic complex,diorite-porphyrite, ores and ore minerals of the 103 Ma Xiaoxinancha gold-rich copper deposit in Jilin province to determine the geodynamic model of diagenesis and metallogenesis.Results show that the initial Nd and Sr isotopic compositions of the granitic complex are in the range of 0.70425-0.70505 for（87Sr/86Sr）i, 0.51243-0.51264 for INd,and -1.31 to ＋2.64 forεNd（t）;those of the diorite-porphyrite are in the range from 0.70438-0.70448 for（87Sr/86Sr）,,0.51259-0.51261 for INd,and ＋1.56 to ＋2.09 forεNd（t）.For ores and sulfides,the（87Sr/86Sr）i,7Nd,andεNd（t） values are in the range from 0.70440-0.70805,0.51259- 0.51279 and ＋1.72 to ＋5.56,respectively.The Pb isotopic ratios of the granitic complex range from 18.2992-18.6636 for 206Pb/204Pb,from 15.5343-15.5660 for 207Pb/204Pb,and from 38.1640-38.5657 for 208Pb/204Pb For diorite-porphyrite,the isotopic ratios of 206Pb/204Pb,207Pb/204Pb and 208Pb/204Pb are 18.3919,15.5794 and 38.3566,respectively,whereas those of the ores and ore sulfides vary from 18.2275-18.3770 for 206Pb/204Pb,from 15.5555-15.5934 for 207Pb/204Pb and from 38.1318-38.3131 for 208Pb/204Pb.The results indicate that the mineralization was correlated to the formation and evolution of the granitic complex and the diorite-porphyrite.Combining with the reported data in petrologic characteristics,elemental geochemistry and chronology,conclusions can be drawn that the geodynamic settings of diagenesis and metallogenesis of this deposit were consistent with the subduction of the Izanagi oceanic plate during the Early Cretaceous.The diorite-porphyrite was formed by the emplacement of the adakitic magma triggered by partial melting of the enriched mantle,which originated from the derivative continental lithospheric mantle metasomatized by dehydration fluids from the subducting oceanic crust.The granitic complex was produced by fractional crystallization of the mixture between the adakitic magma and the hig展开更多
The research on Paleozoic tectonics and endogenic metallogeny in the Tianshan-Altay region of Central Asia is an important and significant project. The Altay region, as a collision zone of the Early Paleozoic （500-39...The research on Paleozoic tectonics and endogenic metallogeny in the Tianshan-Altay region of Central Asia is an important and significant project. The Altay region, as a collision zone of the Early Paleozoic （500-397 Ma）, and the Tianshan region, as a collision zone of the early period in the Late Paleozoic （Late Devonian-Early Carboniferous, 385-323 Ma）, are all the result of nearly N-S trending shortening and collision （according to recent magnetic orientation）. In the Late Devonian-Early Carboniferous period （385-323 Ma）, regional NW trending faults displayed features of dextral strike-slip motion in the Altay and Junggar regions. In the Tianshan region, nearly EW-trending regional faults are motions of the thrusts. However, in the Late Carboniferous-Early Permian period （323-260 Ma）, influenced by the long-distance effect induced from the Ural collision zone, those areas suffered weaker eastward compression, the existing NW trending faults converted into sinistral strike-slip in the Altay and Junggar regions, and the existing nearly E-W trending faults transferred into dextral strike-slip faults in the Tianshan region. The Rocks of those regions in the Late Carboniferous-Early Permian period （323-260 Ma） were moderately ruptured to a certain tension-shear, and thus formed a number of world famous giant endogenic metal ore deposits in the Tianshan-Altay region. As to the Central Asian continent, the most powerful collision period may not coincide with the most favorable endogenic metallogenic period. It should be treated to ＂the orogenic metallogeny hypothesis＂ with caution in that region.展开更多
Red clay type gold deposits,located in the south of China,are situated not only in orogenic belts,but also in inner cratons,where climate is tropical-subtropical with clear arid and humid.The lateritic weathering crus...Red clay type gold deposits,located in the south of China,are situated not only in orogenic belts,but also in inner cratons,where climate is tropical-subtropical with clear arid and humid.The lateritic weathering crust often can be divided into five zones,including topsoil,siliceous duricrust zone,multi-color zone(or red clay zone in some deposits),pallid zone and saprolite zone from surface to the base rock,several of which are absent in some deposits.The base rocks are composed mainly of carbonate rocks with minor clastic rocks,intermediate-basic volcanic rocks and intermediate-acid and alkalic intrusions.The orebodies are mainly located in the multi-color zone with part of them in the pallid and saprolite zones.The ore sources include orebodies of Carlin-type gold deposits and porphyry gold deposits,as well as gold-rich base rocks.The red clay type gold deposits experienced early-stage endogenic gold mineralization and laterization during the Tertiary and Quaternary.The areas with endogenic gold deposits,especially Carlin-type gold deposits and porphyry gold deposits in karst depressions on the plateau,structual erosional platforms in the middle-lower mountains,and intermountain basins in southern China are well worth studying to trace red clay type gold deposits.展开更多
The dynamic effect is a very important issue widely debated by scholars when studying the genetic and disaster-causing mechanisms of earthquake-triggered landslides.First,the dynamic effect mechanism and phenomena of ...The dynamic effect is a very important issue widely debated by scholars when studying the genetic and disaster-causing mechanisms of earthquake-triggered landslides.First,the dynamic effect mechanism and phenomena of earthquake-triggered landslides were summarized in this paper.Then,the primary types of dynamic effects were further used to interpret the Mogangling landslide in Moxi Town of Luding County,China.A field investigation,remote sensing,numerical calculation and theoretical analysis were carried out to illustrate the failure mechanism of slope rock masses affected by earthquakes.The interaction between seismic waves and slope rock masses and the induced dynamic effect of slope rock masses were primarily accounted for in the analysis.The slope topography,rock mass weathering and unloading characteristics,river erosion,regional seismogenic structure,and rock mass structure characteristics were also discussed.The results showed that the formation of the Mogangling landslide was mainly related to the high amplification effect of seismic acceleration and back slope effects,interface dynamic stress effects,and double-sided slope effects of seismic waves caused by the catastrophic Ms 7.75 Moxi Earthquake in 1786.The principles for the site and route selection of large-scale infrastructure in the planning stage and the scientific prevention of seismic geological disasters were proposed on the basis of the dynamic effect of earthquake-induced landslides.展开更多
Upper Triassic sedimentary systems of both the Arabian Plate and the Germanic Basin reveal climate- and plate tectonic-forced effects through certain time-intervals experienced by architectural elements, lithofacies t...Upper Triassic sedimentary systems of both the Arabian Plate and the Germanic Basin reveal climate- and plate tectonic-forced effects through certain time-intervals experienced by architectural elements, lithofacies types, unconformities, flash flood deposits, maximum flooding surfaces/sequence boundary (MFS/SB), mineralogy, and isotope anomalies. Further, Moon recession and changes of Earth’s rotation velocity (core/mantle boundary) are associated with multiple impacting and large igneous provinces/Mid Oceanic Ridge Basalt, LIP/MORB-rifting/degassing. While acidification (by degassing, sturz-rain) does influence tectosilicates and carbonates, montmorillonite represents a key mineral as transformation of volcanic/impact glass (Tephra) to be found as co-components in and in certain pelite units as “boundary clay-suspicions” (mixture of eolian paleoloess, pelite, paleosol, and tephra → tuffite). Obviously, unconformities and sequence boundaries of both study areas separate and dislocate interrupted ∂<sup>13</sup>C and <sup>87</sup>Sr/<sup>86</sup>Sr-data groups along the isotope curves. Both Proto-Arctic Ocean rifting/degassing comprising kimberlitic pyroclastic eruptions and Neotethys rifting/degassing as well as multiple impacting played the most important role during the Norian, followed by the incipient Central Atlantic Magmatic Provinces rifting since the Rhaetian. The following associations are encountered and dealt with in this study: Sequence boundaries-∂<sup>13</sup>C, maximum flooding surfaces-(FUCs)-∂<sup>13</sup>C, unconformities-plate motion, tephra-pelite-tuffite-montmorillonite. Norian: maximum flooding surfaces (MFSs)-“paleosol”/boundary clay?-rifting-volcanism, Moon/Earth data change. So the Norian (~221 - 206 Ma) hosts anomalous “amalgamated maximum flooding surfaces (MFSs)”, amalgamated paleosol (Jordanian Platform), multiple impacting (~219 - 214 Ma), the maximum opening of the Proto-Arctic Ocean (PAO) (~230 - 200 Ma), Neo-Tethys (NT)-subvolcanic (sills, dikes) in the NE D展开更多
A geologic time scale is a chronological system that separates the geological strata of a planetary body into different units in temporal sequence and shows its progressive evolution.The time scale of the Moon was est...A geologic time scale is a chronological system that separates the geological strata of a planetary body into different units in temporal sequence and shows its progressive evolution.The time scale of the Moon was established a half-century ago during the telescopic-early Apollo exploration era,using data with limited spatial coverage and resolution.The past decades have seen a wide array of studies,which have significantly extended our understanding of global lunar geologic evolution.Based on a comprehensive review of lunar evolution with respect to the dynamical changes,we propose two major updates to the current lunar time scale paradigm to include the evolution of both endogenic and exogenic dynamic forces now known to have influenced early lunar history.Firstly,based on the temporal interplay of exogenic and endogenic processes in altering the Moon,we defined three Eon/Eonothem-level units to represent three dynamical evolutionary phases.Secondly,the pre-Nectarian System is redefined and divided as the magma ocean-era Magma-oceanian System and the following Aitkenian System beginning with the South Pole-Aitken basin.The ejecta of this basin,Das Formation,was deposited on the primordial lunar crust as the oldest stratum produced from exogenic processes.The updated lunar time scale,facilitated by the post-Apollo exploration and research advances,provides an integrated framework to depict the evolution of the Moon and has important implications for the geologic study of other terrestrial planets.展开更多
In the light of analysis of the internal relations among the source strata for magmatism, thegranitic magmas and the endogenic metallizations, the basic regularity of petrogenesis and metallo-genesis of Nanling crust-...In the light of analysis of the internal relations among the source strata for magmatism, thegranitic magmas and the endogenic metallizations, the basic regularity of petrogenesis and metallo-genesis of Nanling crust-derived type granitoids can be generalized as follows: (1) Two suites ofsource strata for Magmatism-the Pre-Sinian and the Lower Sinianl here the unity of the old foldbasement, the source strata for magmatism and the source strata for metallization are particularlyhighlighted. (2) Multi-stage melting of source strata for magmatism resulting in the formation ofmajor ore-related granites of three different stages (the Late Jinningean stage, the Late Caledonianstage, and the Late Indosinian-Late Yanshanian stage) under the control of tw0 tectonic units(geosyncline and diwa). (3) Three endogenic meta1logenic epoches accompanying the three stagesof ore-related granitic magmatism. (4) One major metallogenic epoch characterized by concentrat-ed commercial metallizations in large scale related to the Yanshanian crust-derived type granites.Tectonically,this major metallogenic epoch is exactly consistent with the stage of violent diwa ac-tivity. This is by no means fortuitous, but is the unavoidable result of the development and evolu-tion of the objective geologic history.展开更多
Carbonate clumped isotope(Δ47)is a new and reliable geothermometer.Endogenic carbonates in lake sediments are good archives to reconstruct lake water temperature using clumped isotope thermometry.However,applications...Carbonate clumped isotope(Δ47)is a new and reliable geothermometer.Endogenic carbonates in lake sediments are good archives to reconstruct lake water temperature using clumped isotope thermometry.However,applications of carbonate clumped isotope thermometry to lacustrine carbonates are still scarce because the existed organic and/or sulfur contaminants in such samples interfere with clumped isotope analysis and cause notable temperature biases.Therefore,exploring an effective way to remove contamination is a prerequisite to widely applying carbonate clumped isotope thermometry to lake sediments.By pretreating fine-grained endogenic carbonates from Dali lake sediments with hydrogen peroxide of different concentrations for different lengths of time,we conducted a series of conditional experiments to seek the optimal pretreatment condition for clumped isotope analysis.Δ47,Δ48 offset and 49 parameter were obtained from clumped isotope measurements to assess the effect of contamination removal.Results showed that untreated samples("0%-0")had a very high 49 parameter.After the treatment with hydrogen peroxide,the 49 parameter was significantly reduced while theΔ48 offset evidently increased.TheΔ47,Δ48 offset and 49 parameter of samples pretreated under different conditions showed significant variability,even though the measuredΔ47 temperatures changed within a relatively narrow range(i.e.,from 17.0±1.3 to 22.8±1.6°C).Among various treated samples,the sample"3%-8"yielded a smallerΔ48 offset and 49 parameter,and lowerΔ47 temperature of 17.0±1.3°C.Therefore,"reacting with 3%hydrogen peroxide for 8 h"was suggested to be the optimal condition for removing contaminants from lacustrine endogenic carbonates prior to clumped isotope analysis.At the time when the pretreatment condition was too intense(i.e.,H2O2 concentration>3%and/or reaction time>8 h),secondary contaminants might have been generated in the closed reaction system,whose ultimately transformed state may interfere with masses 47,48.Using the optimal p展开更多
基金supported by the National Natural Science Foundation of China(Nos.40472050 and 40772050)the Natural Science Foundation of Jilin Provincial Science and Technology(grant no.20080452)+1 种基金funds from the State Key Laboratory for Mineral Deposits Research,Nanjing University(2006-2005,2006- 2008)Key Laboratory of Mineral Resources, Chinese Academy of Sciences(2009-2012)
文摘An isotopic study was systemically carried out on the granitic complex,diorite-porphyrite, ores and ore minerals of the 103 Ma Xiaoxinancha gold-rich copper deposit in Jilin province to determine the geodynamic model of diagenesis and metallogenesis.Results show that the initial Nd and Sr isotopic compositions of the granitic complex are in the range of 0.70425-0.70505 for（87Sr/86Sr）i, 0.51243-0.51264 for INd,and -1.31 to ＋2.64 forεNd（t）;those of the diorite-porphyrite are in the range from 0.70438-0.70448 for（87Sr/86Sr）,,0.51259-0.51261 for INd,and ＋1.56 to ＋2.09 forεNd（t）.For ores and sulfides,the（87Sr/86Sr）i,7Nd,andεNd（t） values are in the range from 0.70440-0.70805,0.51259- 0.51279 and ＋1.72 to ＋5.56,respectively.The Pb isotopic ratios of the granitic complex range from 18.2992-18.6636 for 206Pb/204Pb,from 15.5343-15.5660 for 207Pb/204Pb,and from 38.1640-38.5657 for 208Pb/204Pb For diorite-porphyrite,the isotopic ratios of 206Pb/204Pb,207Pb/204Pb and 208Pb/204Pb are 18.3919,15.5794 and 38.3566,respectively,whereas those of the ores and ore sulfides vary from 18.2275-18.3770 for 206Pb/204Pb,from 15.5555-15.5934 for 207Pb/204Pb and from 38.1318-38.3131 for 208Pb/204Pb.The results indicate that the mineralization was correlated to the formation and evolution of the granitic complex and the diorite-porphyrite.Combining with the reported data in petrologic characteristics,elemental geochemistry and chronology,conclusions can be drawn that the geodynamic settings of diagenesis and metallogenesis of this deposit were consistent with the subduction of the Izanagi oceanic plate during the Early Cretaceous.The diorite-porphyrite was formed by the emplacement of the adakitic magma triggered by partial melting of the enriched mantle,which originated from the derivative continental lithospheric mantle metasomatized by dehydration fluids from the subducting oceanic crust.The granitic complex was produced by fractional crystallization of the mixture between the adakitic magma and the hig
文摘The research on Paleozoic tectonics and endogenic metallogeny in the Tianshan-Altay region of Central Asia is an important and significant project. The Altay region, as a collision zone of the Early Paleozoic （500-397 Ma）, and the Tianshan region, as a collision zone of the early period in the Late Paleozoic （Late Devonian-Early Carboniferous, 385-323 Ma）, are all the result of nearly N-S trending shortening and collision （according to recent magnetic orientation）. In the Late Devonian-Early Carboniferous period （385-323 Ma）, regional NW trending faults displayed features of dextral strike-slip motion in the Altay and Junggar regions. In the Tianshan region, nearly EW-trending regional faults are motions of the thrusts. However, in the Late Carboniferous-Early Permian period （323-260 Ma）, influenced by the long-distance effect induced from the Ural collision zone, those areas suffered weaker eastward compression, the existing NW trending faults converted into sinistral strike-slip in the Altay and Junggar regions, and the existing nearly E-W trending faults transferred into dextral strike-slip faults in the Tianshan region. The Rocks of those regions in the Late Carboniferous-Early Permian period （323-260 Ma） were moderately ruptured to a certain tension-shear, and thus formed a number of world famous giant endogenic metal ore deposits in the Tianshan-Altay region. As to the Central Asian continent, the most powerful collision period may not coincide with the most favorable endogenic metallogenic period. It should be treated to ＂the orogenic metallogeny hypothesis＂ with caution in that region.
基金supported by the National Basic Research Program of China(973 Program)(No. 2009CB421008)111 Project(No.B07011)Program for Changjiang Scholars and Innovative Research Team in University(PCSIRT)
文摘Red clay type gold deposits,located in the south of China,are situated not only in orogenic belts,but also in inner cratons,where climate is tropical-subtropical with clear arid and humid.The lateritic weathering crust often can be divided into five zones,including topsoil,siliceous duricrust zone,multi-color zone(or red clay zone in some deposits),pallid zone and saprolite zone from surface to the base rock,several of which are absent in some deposits.The base rocks are composed mainly of carbonate rocks with minor clastic rocks,intermediate-basic volcanic rocks and intermediate-acid and alkalic intrusions.The orebodies are mainly located in the multi-color zone with part of them in the pallid and saprolite zones.The ore sources include orebodies of Carlin-type gold deposits and porphyry gold deposits,as well as gold-rich base rocks.The red clay type gold deposits experienced early-stage endogenic gold mineralization and laterization during the Tertiary and Quaternary.The areas with endogenic gold deposits,especially Carlin-type gold deposits and porphyry gold deposits in karst depressions on the plateau,structual erosional platforms in the middle-lower mountains,and intermountain basins in southern China are well worth studying to trace red clay type gold deposits.
基金supported by the China Geological Survey Projects(Nos.20160272,20211379)the Second Tibetan Plateau Scientific Expedition and Research Program(No.2019QZKK0904)。
文摘The dynamic effect is a very important issue widely debated by scholars when studying the genetic and disaster-causing mechanisms of earthquake-triggered landslides.First,the dynamic effect mechanism and phenomena of earthquake-triggered landslides were summarized in this paper.Then,the primary types of dynamic effects were further used to interpret the Mogangling landslide in Moxi Town of Luding County,China.A field investigation,remote sensing,numerical calculation and theoretical analysis were carried out to illustrate the failure mechanism of slope rock masses affected by earthquakes.The interaction between seismic waves and slope rock masses and the induced dynamic effect of slope rock masses were primarily accounted for in the analysis.The slope topography,rock mass weathering and unloading characteristics,river erosion,regional seismogenic structure,and rock mass structure characteristics were also discussed.The results showed that the formation of the Mogangling landslide was mainly related to the high amplification effect of seismic acceleration and back slope effects,interface dynamic stress effects,and double-sided slope effects of seismic waves caused by the catastrophic Ms 7.75 Moxi Earthquake in 1786.The principles for the site and route selection of large-scale infrastructure in the planning stage and the scientific prevention of seismic geological disasters were proposed on the basis of the dynamic effect of earthquake-induced landslides.
文摘Upper Triassic sedimentary systems of both the Arabian Plate and the Germanic Basin reveal climate- and plate tectonic-forced effects through certain time-intervals experienced by architectural elements, lithofacies types, unconformities, flash flood deposits, maximum flooding surfaces/sequence boundary (MFS/SB), mineralogy, and isotope anomalies. Further, Moon recession and changes of Earth’s rotation velocity (core/mantle boundary) are associated with multiple impacting and large igneous provinces/Mid Oceanic Ridge Basalt, LIP/MORB-rifting/degassing. While acidification (by degassing, sturz-rain) does influence tectosilicates and carbonates, montmorillonite represents a key mineral as transformation of volcanic/impact glass (Tephra) to be found as co-components in and in certain pelite units as “boundary clay-suspicions” (mixture of eolian paleoloess, pelite, paleosol, and tephra → tuffite). Obviously, unconformities and sequence boundaries of both study areas separate and dislocate interrupted ∂<sup>13</sup>C and <sup>87</sup>Sr/<sup>86</sup>Sr-data groups along the isotope curves. Both Proto-Arctic Ocean rifting/degassing comprising kimberlitic pyroclastic eruptions and Neotethys rifting/degassing as well as multiple impacting played the most important role during the Norian, followed by the incipient Central Atlantic Magmatic Provinces rifting since the Rhaetian. The following associations are encountered and dealt with in this study: Sequence boundaries-∂<sup>13</sup>C, maximum flooding surfaces-(FUCs)-∂<sup>13</sup>C, unconformities-plate motion, tephra-pelite-tuffite-montmorillonite. Norian: maximum flooding surfaces (MFSs)-“paleosol”/boundary clay?-rifting-volcanism, Moon/Earth data change. So the Norian (~221 - 206 Ma) hosts anomalous “amalgamated maximum flooding surfaces (MFSs)”, amalgamated paleosol (Jordanian Platform), multiple impacting (~219 - 214 Ma), the maximum opening of the Proto-Arctic Ocean (PAO) (~230 - 200 Ma), Neo-Tethys (NT)-subvolcanic (sills, dikes) in the NE D
基金This work was supported partly by the National Key Research and Development Program of China(Grant No.2022YFF0503100)the B-type Strategic Priority Program of the Chinese Academy of Sciences(Grant No.XDB41000000)+1 种基金the National Natural Science Foundation of China(Grant Nos.41902317,41941002,41773065)the National Science and Technology Infrastructure Work Projects(Grant No.2015FY210500).
文摘A geologic time scale is a chronological system that separates the geological strata of a planetary body into different units in temporal sequence and shows its progressive evolution.The time scale of the Moon was established a half-century ago during the telescopic-early Apollo exploration era,using data with limited spatial coverage and resolution.The past decades have seen a wide array of studies,which have significantly extended our understanding of global lunar geologic evolution.Based on a comprehensive review of lunar evolution with respect to the dynamical changes,we propose two major updates to the current lunar time scale paradigm to include the evolution of both endogenic and exogenic dynamic forces now known to have influenced early lunar history.Firstly,based on the temporal interplay of exogenic and endogenic processes in altering the Moon,we defined three Eon/Eonothem-level units to represent three dynamical evolutionary phases.Secondly,the pre-Nectarian System is redefined and divided as the magma ocean-era Magma-oceanian System and the following Aitkenian System beginning with the South Pole-Aitken basin.The ejecta of this basin,Das Formation,was deposited on the primordial lunar crust as the oldest stratum produced from exogenic processes.The updated lunar time scale,facilitated by the post-Apollo exploration and research advances,provides an integrated framework to depict the evolution of the Moon and has important implications for the geologic study of other terrestrial planets.
文摘In the light of analysis of the internal relations among the source strata for magmatism, thegranitic magmas and the endogenic metallizations, the basic regularity of petrogenesis and metallo-genesis of Nanling crust-derived type granitoids can be generalized as follows: (1) Two suites ofsource strata for Magmatism-the Pre-Sinian and the Lower Sinianl here the unity of the old foldbasement, the source strata for magmatism and the source strata for metallization are particularlyhighlighted. (2) Multi-stage melting of source strata for magmatism resulting in the formation ofmajor ore-related granites of three different stages (the Late Jinningean stage, the Late Caledonianstage, and the Late Indosinian-Late Yanshanian stage) under the control of tw0 tectonic units(geosyncline and diwa). (3) Three endogenic meta1logenic epoches accompanying the three stagesof ore-related granitic magmatism. (4) One major metallogenic epoch characterized by concentrat-ed commercial metallizations in large scale related to the Yanshanian crust-derived type granites.Tectonically,this major metallogenic epoch is exactly consistent with the stage of violent diwa ac-tivity. This is by no means fortuitous, but is the unavoidable result of the development and evolu-tion of the objective geologic history.
基金supported by the Strategic Priority Research Program of Chinese Academy of Sciences(Grants Nos.XDA19050104 and XDB26000000)the National Key R&D Program of China(Grant No.2017YFA0603400)+1 种基金the National Natural Science Foundation of China(Grants Nos.41931181&41672166)the Key Research Program of the Institute of Geology&Geophysics,CAS(Grant No.IGGCAS-201905)。
文摘Carbonate clumped isotope(Δ47)is a new and reliable geothermometer.Endogenic carbonates in lake sediments are good archives to reconstruct lake water temperature using clumped isotope thermometry.However,applications of carbonate clumped isotope thermometry to lacustrine carbonates are still scarce because the existed organic and/or sulfur contaminants in such samples interfere with clumped isotope analysis and cause notable temperature biases.Therefore,exploring an effective way to remove contamination is a prerequisite to widely applying carbonate clumped isotope thermometry to lake sediments.By pretreating fine-grained endogenic carbonates from Dali lake sediments with hydrogen peroxide of different concentrations for different lengths of time,we conducted a series of conditional experiments to seek the optimal pretreatment condition for clumped isotope analysis.Δ47,Δ48 offset and 49 parameter were obtained from clumped isotope measurements to assess the effect of contamination removal.Results showed that untreated samples("0%-0")had a very high 49 parameter.After the treatment with hydrogen peroxide,the 49 parameter was significantly reduced while theΔ48 offset evidently increased.TheΔ47,Δ48 offset and 49 parameter of samples pretreated under different conditions showed significant variability,even though the measuredΔ47 temperatures changed within a relatively narrow range(i.e.,from 17.0±1.3 to 22.8±1.6°C).Among various treated samples,the sample"3%-8"yielded a smallerΔ48 offset and 49 parameter,and lowerΔ47 temperature of 17.0±1.3°C.Therefore,"reacting with 3%hydrogen peroxide for 8 h"was suggested to be the optimal condition for removing contaminants from lacustrine endogenic carbonates prior to clumped isotope analysis.At the time when the pretreatment condition was too intense(i.e.,H2O2 concentration>3%and/or reaction time>8 h),secondary contaminants might have been generated in the closed reaction system,whose ultimately transformed state may interfere with masses 47,48.Using the optimal p
