Carbonatites in the Maoniuping REE deposit, Sichuan Province, which are spatially and temporally associated with rare earth mineralization, were emplaced at the time of Himalayan. The rocks are carbonatite-syenite com...Carbonatites in the Maoniuping REE deposit, Sichuan Province, which are spatially and temporally associated with rare earth mineralization, were emplaced at the time of Himalayan. The rocks are carbonatite-syenite complexes, with the mineral assemblages of calcite-aegirine-acmite-arfvedsonite-mica-orthoclase. The rocks are characterized by the enrichment in incompatible elements, such as Sr, Ba and REE, with C and O isotopic compositions of the “primary igneous carbonatites”, relatively high initial 87Sr/86Sr ratios and low ?nd values. All of these suggest that the rocks were derived from the metasomatic enriched mantle. It is demonstrated by geological and geochemical evidence that the mixing of the Himalayan subducting crustal materials with mantle source EM1 is probably the main factor responsible for the formation of carbonatites. The carbonatite-syenite complexes were generated from liquid immiscibility of CO2-rich alkalic silicate magma, which was derived from partial melting of the metasomatic mantle.展开更多
Bioko Island(3008 m a.s.l) is located in the presently more active volcanic zone of the Cameroon Line and composed essentially of alkaline basalts and hawaiites, and lesser mugearites. The rocks show microlitic porp...Bioko Island(3008 m a.s.l) is located in the presently more active volcanic zone of the Cameroon Line and composed essentially of alkaline basalts and hawaiites, and lesser mugearites. The rocks show microlitic porphyritic texture with phenocrysts of olivine(83% 〈 Fo 〈 87%) and clinopyroxene in a matrix of plagioclase, clinopyroxene and oxides. Hawaiites and mugearites also include phenocrysts of plagioclase(An62-67Ab35-32Or3-1). Major element variation diagrams show an increase in Si O2, Al2O3, Na2 O and K2 O with increasing Mg O for the studied rock groups. The rocks are characterized by low(^86Sr/^87Sr)i ratios(0.70320e0.70406), high 3Nd(t) values(2.56e4.33) and high(^206Pb/^204Pb)i ratios(20.032e20.035) values.Basalts are enriched in LILE and LREE, and have(Hf/Sm)N= 0.57e1.16. These geochemical signatures are similar to those of the Mount Cameroon rocks, and might be attributed to low degrees of partial melting from a garnet-amphibole-bearing mantle source. The trace elements and isotopic compositions suggest that the parental magma source might have involved HIMU- and EM1-components.展开更多
基金This work was supported by the State Climbing Program (Grant No. 95-Pre-39).
文摘Carbonatites in the Maoniuping REE deposit, Sichuan Province, which are spatially and temporally associated with rare earth mineralization, were emplaced at the time of Himalayan. The rocks are carbonatite-syenite complexes, with the mineral assemblages of calcite-aegirine-acmite-arfvedsonite-mica-orthoclase. The rocks are characterized by the enrichment in incompatible elements, such as Sr, Ba and REE, with C and O isotopic compositions of the “primary igneous carbonatites”, relatively high initial 87Sr/86Sr ratios and low ?nd values. All of these suggest that the rocks were derived from the metasomatic enriched mantle. It is demonstrated by geological and geochemical evidence that the mixing of the Himalayan subducting crustal materials with mantle source EM1 is probably the main factor responsible for the formation of carbonatites. The carbonatite-syenite complexes were generated from liquid immiscibility of CO2-rich alkalic silicate magma, which was derived from partial melting of the metasomatic mantle.
基金financially supported by the Ministère des Affaires Economiques (Project SGB/ NAT 91-98)
文摘Bioko Island(3008 m a.s.l) is located in the presently more active volcanic zone of the Cameroon Line and composed essentially of alkaline basalts and hawaiites, and lesser mugearites. The rocks show microlitic porphyritic texture with phenocrysts of olivine(83% 〈 Fo 〈 87%) and clinopyroxene in a matrix of plagioclase, clinopyroxene and oxides. Hawaiites and mugearites also include phenocrysts of plagioclase(An62-67Ab35-32Or3-1). Major element variation diagrams show an increase in Si O2, Al2O3, Na2 O and K2 O with increasing Mg O for the studied rock groups. The rocks are characterized by low(^86Sr/^87Sr)i ratios(0.70320e0.70406), high 3Nd(t) values(2.56e4.33) and high(^206Pb/^204Pb)i ratios(20.032e20.035) values.Basalts are enriched in LILE and LREE, and have(Hf/Sm)N= 0.57e1.16. These geochemical signatures are similar to those of the Mount Cameroon rocks, and might be attributed to low degrees of partial melting from a garnet-amphibole-bearing mantle source. The trace elements and isotopic compositions suggest that the parental magma source might have involved HIMU- and EM1-components.
基金supported by Natural Science Foundation of Anhui Province,No.1508085MH170 National Natural Science Foundation of China,No.81472656 Natural Science Foundation Project of Anhui Province Education Department,No.KJ2017A247