Zirconia graphite refractory is used as a core-nozzle in the thin-strip casting of steel. Post-mortem analysis of used refractory was performed in an effort to establish the failure mechanism. Corrosion behavior was s...Zirconia graphite refractory is used as a core-nozzle in the thin-strip casting of steel. Post-mortem analysis of used refractory was performed in an effort to establish the failure mechanism. Corrosion behavior was studied against molten steel with Mn O- SiO 2based liquid inclusions. Corrosion of these materials involves dissolution and oxidation of graphite in the matrix followed by penetration of liquid slag leading to degradation of ZrO 2particles. Thermodynamic equilibrium calculations were performed to study this corrosion mechanism.展开更多
基金the National Natural Science Foun⁃dation of China(No.22005206,22075318)Science and Technolo⁃gy Department of Sichuan Province(No.2022NSFSC1209,2022NS⁃FSC0219)Undergraduate Training Programs for Innovation and Entrepreneurship(No.cx2022046)。
文摘Zirconia graphite refractory is used as a core-nozzle in the thin-strip casting of steel. Post-mortem analysis of used refractory was performed in an effort to establish the failure mechanism. Corrosion behavior was studied against molten steel with Mn O- SiO 2based liquid inclusions. Corrosion of these materials involves dissolution and oxidation of graphite in the matrix followed by penetration of liquid slag leading to degradation of ZrO 2particles. Thermodynamic equilibrium calculations were performed to study this corrosion mechanism.