The dirhodium(II)-catalyzed organic reactions,including asymmetric transformation,are significantly benefitted from the discovery of simple and efficient protocols to introduce various bridging ligands,e.g.carboxylic ...The dirhodium(II)-catalyzed organic reactions,including asymmetric transformation,are significantly benefitted from the discovery of simple and efficient protocols to introduce various bridging ligands,e.g.carboxylic acids,amide and phosphoric acids.Ligands lying at axial position of dirhodium(II)complexes could strongly affect the activity and selectivity of these metal complexes involved reactions.This review summarizes the newly explored reactivity of dirhodium(II)complexes with N-heterocyclic carbenes or phosphines as the axial ligands.The asymmetric tries are also highlighted,where their stereo-induction were solely from the axial ligand of dirhodium(II)complexes.In the last part,the reactions catalyzed by inherent chiral ortho-metalated dirhodium(II)/phosphine complexes are also discussed.展开更多
基金This work was financially supported by the USTC Research Funds of the Double First-Class Initiative(No.YD2060002014)B.H.thanks Minjiang University(Nos.32903602,MJY20019 and MYK21007)Fujian Education Department(No.JT180396)for financial support.
文摘The dirhodium(II)-catalyzed organic reactions,including asymmetric transformation,are significantly benefitted from the discovery of simple and efficient protocols to introduce various bridging ligands,e.g.carboxylic acids,amide and phosphoric acids.Ligands lying at axial position of dirhodium(II)complexes could strongly affect the activity and selectivity of these metal complexes involved reactions.This review summarizes the newly explored reactivity of dirhodium(II)complexes with N-heterocyclic carbenes or phosphines as the axial ligands.The asymmetric tries are also highlighted,where their stereo-induction were solely from the axial ligand of dirhodium(II)complexes.In the last part,the reactions catalyzed by inherent chiral ortho-metalated dirhodium(II)/phosphine complexes are also discussed.
