[ Objective] The paper was to study the insecticidal activity and field efficacy of cyhalediamide, a novel insecticide developed by Zhejiang Research Institute of Chemical Industry, Ltd. [ Method] Toxicity of cyhalodi...[ Objective] The paper was to study the insecticidal activity and field efficacy of cyhalediamide, a novel insecticide developed by Zhejiang Research Institute of Chemical Industry, Ltd. [ Method] Toxicity of cyhalodiamide against Plutella xylostella, Spodoptera exigua, Prodenia litura and Chilo suppressalis were tasted in the laboratory by leaf-dipping method, and the field efficacy of cyhalodiamide against P. xylostella, S. exigua, P. litura, Pieris rapae, C. suppressalis and Cnaphalocrocis medinalis was evaluated. [ Result] The LCs0 values of cyhalodiamide against P. xylostella, S. exigua, P. litura and C. suppressalis were 0. 046, 0.072, 0.071 and 1.95 mg/L, respectively, almost equivalent to that of flubendiamide and ehlorantraniliprole. The control efficacy of 20% Z4042 SC （30 g/hm2） against P. xylostella, S. exigua, P. litura and P. rapae was 90.1% - 96.3 % after spraying for 7 d, and its control efficacy against C. suppressalis and C. medinalis was 82.9% -90.5% after spraying for 15 d. No crop injury was observed at the test dosage. [Conclusion] The study provided reference for field control against Lepidoptera pests.展开更多
Cyhalodiamide is a novel agrochemical which is effective against Lepidoptera pests,including Cnaphalocrocis medinalis,Chilo suppressalis,Pieris rapae,Plutella xylostella,Helicoverpa armigera,etc.In the study,a fast an...Cyhalodiamide is a novel agrochemical which is effective against Lepidoptera pests,including Cnaphalocrocis medinalis,Chilo suppressalis,Pieris rapae,Plutella xylostella,Helicoverpa armigera,etc.In the study,a fast and accurate analytical method was developed to detect cyhalodiamide in Chinese typical rice field environment by a modified Qu ECh ERS(Quick,Easy,Cheap,Effective,Rugged,Safe)method with UPLC-MS/MS(ultra-high performance chromatography-tandem mass spectrometry).The mean recoveries of cyhalodiamide varied from 73.5% to 107.5%,with the RSDs from 1.2% to 10.7%.The limits of determination(LODs)were 0.0005 mg·kg^(-1),and the limits of quantitation(LOQs)were from 0.002 to 0.01 mg·kg^(-1)in all five matrices.This method was used to determine cyhalodiamide residues for studies of the distribution and degradation kinetics in rice field environment.The field trials results showed that cyhalodiamide was easily degradable and the half-lives were4.2–13.6 d in rice straw,8.77 d in paddy soil and 5.37–8.45 d in paddy water,respectively.The final residues of cyhalodiamide in brown rice were below 0.35 mg·kg^(-1).The used dosage of 33.75 g·hm^(-2)with pre-harvest interval(PHI)of 21 d and the maximum residue limit(MRL)of cyhalodiamide in rice at 0.1 mg·kg^(-1)were recommended,which would be safe to human health and environment.The developed analytical method will be useful to monitor cyhalodiamide residues and safety evaluation in rice environment.展开更多
基金Supported by"Twelfth Five-Year"National Science and Technology Support Program(2011BAE06B01-20)
文摘[ Objective] The paper was to study the insecticidal activity and field efficacy of cyhalediamide, a novel insecticide developed by Zhejiang Research Institute of Chemical Industry, Ltd. [ Method] Toxicity of cyhalodiamide against Plutella xylostella, Spodoptera exigua, Prodenia litura and Chilo suppressalis were tasted in the laboratory by leaf-dipping method, and the field efficacy of cyhalodiamide against P. xylostella, S. exigua, P. litura, Pieris rapae, C. suppressalis and Cnaphalocrocis medinalis was evaluated. [ Result] The LCs0 values of cyhalodiamide against P. xylostella, S. exigua, P. litura and C. suppressalis were 0. 046, 0.072, 0.071 and 1.95 mg/L, respectively, almost equivalent to that of flubendiamide and ehlorantraniliprole. The control efficacy of 20% Z4042 SC （30 g/hm2） against P. xylostella, S. exigua, P. litura and P. rapae was 90.1% - 96.3 % after spraying for 7 d, and its control efficacy against C. suppressalis and C. medinalis was 82.9% -90.5% after spraying for 15 d. No crop injury was observed at the test dosage. [Conclusion] The study provided reference for field control against Lepidoptera pests.
基金Supported by the National Key Research and Development Plan(2016YFD020120)the Natural Science Foundation of Hunan Province(2017JJ3165)
文摘Cyhalodiamide is a novel agrochemical which is effective against Lepidoptera pests,including Cnaphalocrocis medinalis,Chilo suppressalis,Pieris rapae,Plutella xylostella,Helicoverpa armigera,etc.In the study,a fast and accurate analytical method was developed to detect cyhalodiamide in Chinese typical rice field environment by a modified Qu ECh ERS(Quick,Easy,Cheap,Effective,Rugged,Safe)method with UPLC-MS/MS(ultra-high performance chromatography-tandem mass spectrometry).The mean recoveries of cyhalodiamide varied from 73.5% to 107.5%,with the RSDs from 1.2% to 10.7%.The limits of determination(LODs)were 0.0005 mg·kg^(-1),and the limits of quantitation(LOQs)were from 0.002 to 0.01 mg·kg^(-1)in all five matrices.This method was used to determine cyhalodiamide residues for studies of the distribution and degradation kinetics in rice field environment.The field trials results showed that cyhalodiamide was easily degradable and the half-lives were4.2–13.6 d in rice straw,8.77 d in paddy soil and 5.37–8.45 d in paddy water,respectively.The final residues of cyhalodiamide in brown rice were below 0.35 mg·kg^(-1).The used dosage of 33.75 g·hm^(-2)with pre-harvest interval(PHI)of 21 d and the maximum residue limit(MRL)of cyhalodiamide in rice at 0.1 mg·kg^(-1)were recommended,which would be safe to human health and environment.The developed analytical method will be useful to monitor cyhalodiamide residues and safety evaluation in rice environment.
