The Nd_(60)Fe_(20)Al_8Co_(10)B_2 alloy was prepared by suction casting of the molten alloy into a copper mold under argon atmosphere. The micro-structural and magnetic property changes in the Nd_(60)Fe_(20)Al_8Co_(10)...The Nd_(60)Fe_(20)Al_8Co_(10)B_2 alloy was prepared by suction casting of the molten alloy into a copper mold under argon atmosphere. The micro-structural and magnetic property changes in the Nd_(60)Fe_(20)Al_8Co_(10)B_2 alloy during crystallization were investigated by X-ray diffraction (XRD), differential scanning calorimetry (DSC), scanning electron microscope (SEM) and the vibrating sample magnetometer (VSM). The precipitation and Nd-rich and Fe-rich phases have no significant effect on the intrinsic coercitity for Nd_(60)Fe_(20)Al_8Co_(10)B_2 alloy annealed below 723 K. However, the growth of Fe-rich phase decreases the saturate magnetization and remanence of the alloy. The hard magnetic behavior is disappeared when the alloy is fully crystallized.展开更多
Crystalline behavior and magnetic properties of Nd 60 Fe 30- x Al 10 Co x (x =0,5,10) bulk amorphous alloys were investigated by differential scanning calorimeter (DSC), X ray diffraction (XRD) and...Crystalline behavior and magnetic properties of Nd 60 Fe 30- x Al 10 Co x (x =0,5,10) bulk amorphous alloys were investigated by differential scanning calorimeter (DSC), X ray diffraction (XRD) and the vibrating sample magnetometer (VSM). Neither glass transition nor supercooled liquid region before crystallization was observed for the as cast Nd 60 Fe 30- x Al 10 Co x (x =0,5,10) bulk amorphous alloys. The glass forming ability can be improved significantly by the addition of Co. The as cast Nd 60 Fe 30- x Al 10 Co x (x =0,5,10) alloys show hard magnetic behavior. With the addition of Co content, intrinsic coercivity ( i H c) increases while the saturation magnetization( σ s) and remanence ( σ r) decrease. The Curie temperature for the as cast Nd 60 Fe 30- x Al 10 Co x alloys increases from 451 K for x =0 to 468 K for x =10. Some precipitation of crystalline phases does not affect the hard magnetic properties of Nd 60 Fe 30- x Al 10 Co x (x =0,5,10) alloys, while the hard magnetic behavior disappears quickly after the alloys being completely crystallized.展开更多
文摘The Nd_(60)Fe_(20)Al_8Co_(10)B_2 alloy was prepared by suction casting of the molten alloy into a copper mold under argon atmosphere. The micro-structural and magnetic property changes in the Nd_(60)Fe_(20)Al_8Co_(10)B_2 alloy during crystallization were investigated by X-ray diffraction (XRD), differential scanning calorimetry (DSC), scanning electron microscope (SEM) and the vibrating sample magnetometer (VSM). The precipitation and Nd-rich and Fe-rich phases have no significant effect on the intrinsic coercitity for Nd_(60)Fe_(20)Al_8Co_(10)B_2 alloy annealed below 723 K. However, the growth of Fe-rich phase decreases the saturate magnetization and remanence of the alloy. The hard magnetic behavior is disappeared when the alloy is fully crystallized.
文摘Crystalline behavior and magnetic properties of Nd 60 Fe 30- x Al 10 Co x (x =0,5,10) bulk amorphous alloys were investigated by differential scanning calorimeter (DSC), X ray diffraction (XRD) and the vibrating sample magnetometer (VSM). Neither glass transition nor supercooled liquid region before crystallization was observed for the as cast Nd 60 Fe 30- x Al 10 Co x (x =0,5,10) bulk amorphous alloys. The glass forming ability can be improved significantly by the addition of Co. The as cast Nd 60 Fe 30- x Al 10 Co x (x =0,5,10) alloys show hard magnetic behavior. With the addition of Co content, intrinsic coercivity ( i H c) increases while the saturation magnetization( σ s) and remanence ( σ r) decrease. The Curie temperature for the as cast Nd 60 Fe 30- x Al 10 Co x alloys increases from 451 K for x =0 to 468 K for x =10. Some precipitation of crystalline phases does not affect the hard magnetic properties of Nd 60 Fe 30- x Al 10 Co x (x =0,5,10) alloys, while the hard magnetic behavior disappears quickly after the alloys being completely crystallized.