The crowding agent induced phase transition of amphiphilic block copolymers in solution was explicitly considered. The influence of the size and the volume fraction of the crowding agent on the phase separation of amp...The crowding agent induced phase transition of amphiphilic block copolymers in solution was explicitly considered. The influence of the size and the volume fraction of the crowding agent on the phase separation of ampbiphilic diblock copolymers is investigated by using self-consistent field theory （SCFT） method. The concentration of the disorder to order transition of the block copolymer decreases when the size of the crowding agent is larger than that of the solvent. The higher volume fraction of the crowding agent will induce the transition of the block copolymer from disorder to order state at a lower concentration. The relation between the size and the volume fraction of the crowding agent is elucidated. When the size of the crowding agent is larger, its volume fraction of the disorder to order transition of the block copolymer will be lower. The conformation of the crowding agent considered as a polymer chain is also studied and compared.展开更多
模拟焦虑情绪下的人群疏散,对于解决逃生等运动学问题具有重要意义。国内外大多数研究在人群疏散问题中单纯引入焦虑因子这一介质,并未考虑在此类紧急环境下外界关键因素如何影响焦虑因子。提出了改进社会力模型(improving social force...模拟焦虑情绪下的人群疏散,对于解决逃生等运动学问题具有重要意义。国内外大多数研究在人群疏散问题中单纯引入焦虑因子这一介质,并未考虑在此类紧急环境下外界关键因素如何影响焦虑因子。提出了改进社会力模型(improving social force model,ISFM),结合基于Agent的踩踏风险评估,量化了环境关键变量对焦虑因子的影响,引入心理作用力参数,将焦虑因子对现实疏散过程中所造成的影响通过物理矢量的方式作用在模型中。ISFM通过增强个体心理行为异质性,实现了个体运动矢量的选择。对比真实疏散情景,实验结果表明:ISFM更能反映个体疏散行为,更具说服力。展开更多
基金financially supported by the National Natural Science Foundations of China(Nos.20874046,21074053 and 51133002)National Basic Research Program of China(Nos.2010CB923303,2012CB821503)Fundamental Research Funds for the Central Universities(No.1095020515)
文摘The crowding agent induced phase transition of amphiphilic block copolymers in solution was explicitly considered. The influence of the size and the volume fraction of the crowding agent on the phase separation of ampbiphilic diblock copolymers is investigated by using self-consistent field theory （SCFT） method. The concentration of the disorder to order transition of the block copolymer decreases when the size of the crowding agent is larger than that of the solvent. The higher volume fraction of the crowding agent will induce the transition of the block copolymer from disorder to order state at a lower concentration. The relation between the size and the volume fraction of the crowding agent is elucidated. When the size of the crowding agent is larger, its volume fraction of the disorder to order transition of the block copolymer will be lower. The conformation of the crowding agent considered as a polymer chain is also studied and compared.
文摘模拟焦虑情绪下的人群疏散,对于解决逃生等运动学问题具有重要意义。国内外大多数研究在人群疏散问题中单纯引入焦虑因子这一介质,并未考虑在此类紧急环境下外界关键因素如何影响焦虑因子。提出了改进社会力模型(improving social force model,ISFM),结合基于Agent的踩踏风险评估,量化了环境关键变量对焦虑因子的影响,引入心理作用力参数,将焦虑因子对现实疏散过程中所造成的影响通过物理矢量的方式作用在模型中。ISFM通过增强个体心理行为异质性,实现了个体运动矢量的选择。对比真实疏散情景,实验结果表明:ISFM更能反映个体疏散行为,更具说服力。
