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Cr^(Ⅵ) adsorption on four typical soil colloids: equilibrium and kinetics 被引量:15
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作者 ZHOU Dong-mei CHEN Huai-man 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2000年第3期325-329,共5页
It is observed that the adsorption of chromium are greater on kaolinite minerals, red soil (R) and laterite (L) colloids than that on montmorillonite, indicotic black (IB) and yellow brown (YB) soil colloids. The adso... It is observed that the adsorption of chromium are greater on kaolinite minerals, red soil (R) and laterite (L) colloids than that on montmorillonite, indicotic black (IB) and yellow brown (YB) soil colloids. The adsorption process of Cr Ⅵ on these media can be further described by Langmuir or Freundlich equation quite well. The adsorption reaction of Cr Ⅵ is fast, and the adsorption equilibrium can be reached within the first two hours in moderate temperature. The adsorption quantity of Cr Ⅵ to kaolinite mineral increased with the increasing pH in the range of 2.0 to 7.0, then decreased at higher pH. But it showed some consistence among the four soil colloids. The lower the pH, the stronger the adsorption. The possible mechanisms are further discussed here. Meanwhile the influence of temperature on Cr Ⅵ adsorption on different soil colloid and clay minerals are also investigated. 展开更多
关键词 cr soil colloids clay mineral ADSORPTION
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中空介孔SiO_(2)的合成及其对Cr^(Ⅵ)的吸附 被引量:2
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作者 张辰 韩伟豪 +2 位作者 宫玉梅 于洋 曹金城 《材料研究学报》 EI CAS CSCD 北大核心 2021年第1期45-52,共8页
以3-氨基苯酚/甲醛(AF)树脂为软模板、正硅酸乙酯(TEOS)为硅源、十六烷基三甲基溴化铵(CTAB)为制孔剂,采用一锅溶胶-凝胶法制备中空介孔二氧化硅(HMS)微球。通过改变反应温度对软模板AF树脂的结构以及TEOS的水解速率进行调控,制备多形貌... 以3-氨基苯酚/甲醛(AF)树脂为软模板、正硅酸乙酯(TEOS)为硅源、十六烷基三甲基溴化铵(CTAB)为制孔剂,采用一锅溶胶-凝胶法制备中空介孔二氧化硅(HMS)微球。通过改变反应温度对软模板AF树脂的结构以及TEOS的水解速率进行调控,制备多形貌SiO_(2)微球。使用扫描电子显微镜(SEM)、透射电子显微镜(TEM)、N_(2)吸附-脱附比表面积分析(BET)及傅里叶变换红外光谱(FTIR)等手段对制得的SiO_(2)微球进行表征。结果表明,随着反应温度从0℃提高到100℃,制备的SiO_(2)微球分别为实心微球、蛋黄壳空心球、单层壳空心球和破碎实心球等。其中具有蛋黄壳结构的HMS微球具有较大的比表面积和孔体积,比表面积可达513m^(2)/g,孔体积达0.432 cm^(3)/g,孔径均匀达3.66 nm。将在30℃下制得的具有蛋黄壳结构的HMS微球表面进行接枝聚丙烯腈并偕胺肟化的改性制备蛋黄壳HMS接枝聚偕胺肟(HMS-g-PAO)。将HMS-g-PAO用于对水中Cr^(Ⅵ)的吸附,在pH=2时HMS-g-PAO粒子对100 mg/mL的重铬酸钾溶液中Cr^(Ⅵ)有很好的吸附效果,其吸附量达140 mg/g。 展开更多
关键词 无机非金属材料 中空介孔SiO_(2) 软模板 偕胺肟化 ^cr^()吸附
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