Most of volatile organic compounds （VOCs） are harmful to the atmosphere and human health. Cata‐lytic combustion is an effective way to eliminate VOCs. The key issue is the availability of high per‐formance catalys...Most of volatile organic compounds （VOCs） are harmful to the atmosphere and human health. Cata‐lytic combustion is an effective way to eliminate VOCs. The key issue is the availability of high per‐formance catalysts. Many catalysts including transition metal oxides, mixed metal oxides, and sup‐ported noble metals have been developed. Among these catalysts, the porous ones attract much attention. In this review, we focus on recent advances in the synthesis of ordered mesoporous and macroporous transition metal oxides, perovskites, and supported noble metal catalysts and their catalytic oxidation of VOCs. The porous catalysts outperformed their bulk counterparts. This excel‐lent catalytic performance was due to their high surface areas, high concentration of adsorbed oxy‐gen species, low temperature reducibility, strong interaction between noble metal and support and highly dispersed noble metal nanoparticles and unique porous structures. Catalytic oxidation of carbon monoxide over typical catalysts was also discussed. We made conclusive remarks and pro‐posed future work for the removal of VOCs.展开更多
Various physical parameters, including gas concentrations (O2, CO, CH4, and H2) and temperatures at dif- ferent air velocities, were determined for full scale wood fires in the Chongqing Coal Research Institute fire t...Various physical parameters, including gas concentrations (O2, CO, CH4, and H2) and temperatures at dif- ferent air velocities, were determined for full scale wood fires in the Chongqing Coal Research Institute fire test tunnel. Both experimental measurements and numerical simulations are discussed. The numer- ical analysis was performed with the computational fluid dynamics software package ''FLUENT''. The results show that the experimental data agree with the simulation results. The results verify that Roberts' theory of burning is correct. They also prove that the air velocity is the key factor that determines the type of combustion. Also, it is shown that secondary disasters are unlikely for oxygen rich combustion with a limited fire load.展开更多
基金supported by the National High Technology Research and Development Program (863 Program,2015AA034603)the National Natural Science Foundation of China (21377008,201077007,20973017)+1 种基金Foundation on the Creative Research Team Construction Promotion Project of Beijing Municipal InstitutionsScientific Research Base Construction-Science and Technology Creation Platform National Materials Research Base Construction~~
文摘Most of volatile organic compounds （VOCs） are harmful to the atmosphere and human health. Cata‐lytic combustion is an effective way to eliminate VOCs. The key issue is the availability of high per‐formance catalysts. Many catalysts including transition metal oxides, mixed metal oxides, and sup‐ported noble metals have been developed. Among these catalysts, the porous ones attract much attention. In this review, we focus on recent advances in the synthesis of ordered mesoporous and macroporous transition metal oxides, perovskites, and supported noble metal catalysts and their catalytic oxidation of VOCs. The porous catalysts outperformed their bulk counterparts. This excel‐lent catalytic performance was due to their high surface areas, high concentration of adsorbed oxy‐gen species, low temperature reducibility, strong interaction between noble metal and support and highly dispersed noble metal nanoparticles and unique porous structures. Catalytic oxidation of carbon monoxide over typical catalysts was also discussed. We made conclusive remarks and pro‐posed future work for the removal of VOCs.
基金Financial support for this work provided by the National"Eleventh Five-Year" Key Scientific and Technological Support[Program (No. 2007BAK22B04)2008 independent task (No.SKLCRSM08B12)
文摘Various physical parameters, including gas concentrations (O2, CO, CH4, and H2) and temperatures at dif- ferent air velocities, were determined for full scale wood fires in the Chongqing Coal Research Institute fire test tunnel. Both experimental measurements and numerical simulations are discussed. The numer- ical analysis was performed with the computational fluid dynamics software package ''FLUENT''. The results show that the experimental data agree with the simulation results. The results verify that Roberts' theory of burning is correct. They also prove that the air velocity is the key factor that determines the type of combustion. Also, it is shown that secondary disasters are unlikely for oxygen rich combustion with a limited fire load.
