The aim of this paper is to investigate the effect of nitrite intercalated Mg-Al layered double hydroxides(Mg-Al LDH-NO_(2))on mortar durability under the coexisting environment of Cl−and SO_(4)^(2-).Cl−and SO_(4)^(2-...The aim of this paper is to investigate the effect of nitrite intercalated Mg-Al layered double hydroxides(Mg-Al LDH-NO_(2))on mortar durability under the coexisting environment of Cl−and SO_(4)^(2-).Cl−and SO_(4)^(2-) binding properties of Mg-Al LDH-NO_(2) in simulated concrete pore solutions,Cl−and SO_(4)^(2-) diffusion properties of mortars with Mg-Al LDHNO 2 were examined.The steel corrosion and resistance of mortar against SO_(4)^(2-) attack were also evaluated.The results indicate that Mg-Al LDH-NO_(2) can effectively adsorb the Cl−and SO_(4)^(2-) in simulated concrete pore solution,and inhibit the diffusion of Cl−and SO_(4)^(2-) into cement mortars.The presence of SO_(4)^(2-) can greatly affect the uptake amount of Cl−,and there is a coupled effect of Cl−and SO_(4)^(2-) on their penetration into mortar specimens.In addition,Mg-Al LDH-NO_(2) can greatly upgrade the resistance of mortars against SO_(4)^(2-) attack and well prevent the steel from corrosion.However,Cl−will aggravate the SO_(4)^(2-) attack and SO_(4)^(2-) can initially decrease and then increase the steel corrosion.展开更多
The study aims to explore the corrosion behaviors of 13Cr steel in the high-temperature steam environment.The corrosion behaviors of 13Cr steel were tested in CO2 auxiliary steam drive environment simulated with the H...The study aims to explore the corrosion behaviors of 13Cr steel in the high-temperature steam environment.The corrosion behaviors of 13Cr steel were tested in CO2 auxiliary steam drive environment simulated with the HTHP autoclave.The corrosion morphology and product composition were explored by SEM,EDS,XRD and XPS.The exploration results showed the corrosion rate of 13Cr steel in the high-temperature steam environment was less than 0.04 mm/a.The corrosion behaviors of 13Cr steel were mainly affected by temperature and chloride ion concentration.Temperature inhibited steam condensation and the compactness of Cr-rich layer.With the increase in temperature,more droplets were adsorbed on the surface of 13Cr steel and the compactness of the Crrich layer is worse.Chloride ions affects the activity of Fe atoms in the metal matrix.When chloride concentration increased,Fe^2+concentration in the solution and FeCO3 content in the rich-Cr layer were increased and the rich-Cr layer became looser.展开更多
Aims Drought and salinity are severe abiotic stress factors,which limit plant growth and productivity,particularly in desert regions.In this study,we employed two desert poplars,Populus euphratica Oliver and Populus p...Aims Drought and salinity are severe abiotic stress factors,which limit plant growth and productivity,particularly in desert regions.In this study,we employed two desert poplars,Populus euphratica Oliver and Populus pruinosa Schrenk seedlings,to compare their tolerance to drought,salinity and combined stress.Methods We investigated species-specific responses of P.euphratica and P.pruinosa in growth,photosynthetic capacity and pigment contents,nonstructural carbohydrate concentrations,Cl−allocation,osmotic regulation and the accumulation of reactive oxygen species(ROS)under drought,salinity and the combined stress.Important Findings Populus pruinosa exhibited greater growth inhibitory effects,photosynthesis decline,stomatal closure and ROS accumulation,and lower antioxidant enzyme activities and osmotic regulation compared with P.euphratica under drought,salinity and especially under their combined stress.On the other hand,salt-stressed P.euphratica plants restricted salt transportation from roots to leaves,and allocated more Cl−to coarse roots and less to leaves,whereas salt-stressed P.pruinosa allocated more Cl−to leaves.It was shown that there is species-specific variation in these two desert poplars,and P.pruinosa suffers greater negative effects compared with P.euphratica under drought,salinity and especially under the combined stress.Therefore,in ecological restoration and afforestation efforts,species-specific responses and tolerances of these two poplar species to drought and salinity should be considered under climate change with increasing drought and soil salinity developing.展开更多
The stability constants of Sb^5+with Cl−as well as thermodynamics of the Sb−S−Cl−H2O system were calculated.The stability constants of Sb5+with Cl−were obtained by theoretical calculations of the absorbance of a Sb5+-...The stability constants of Sb^5+with Cl−as well as thermodynamics of the Sb−S−Cl−H2O system were calculated.The stability constants of Sb5+with Cl−were obtained by theoretical calculations of the absorbance of a Sb5+-containing solution at different Cl^−concentrations,which was detected by spectrophotometric analysis at certain wavelengths of light(380 nm).The logarithmic values versus 10 of stability constants of Sb^5+with Cl−were 1.795,3.150,4.191,4.955,5.427 and 5.511,respectively,and partly filled the data gaps in the hydrometallurgy of antimony.The presence and distribution of pentavalent antimony compounds under different conditions were analyzed based on equilibrium calculations.Thermodynamic equilibrium calculations were performed for Sb−S−Cl−H2O system,which included the complex behavior of Sb with Cl,and the equilibrium equations of related reactions in this system were integrated into the potential−pH diagram.展开更多
Combining the H2 production with brine remediation is regarded as a sustainable approach to achieving clean H2 energy. However, designing stable Cl− oxidation reaction (COR) electrocatalyst is the key to realize this ...Combining the H2 production with brine remediation is regarded as a sustainable approach to achieving clean H2 energy. However, designing stable Cl− oxidation reaction (COR) electrocatalyst is the key to realize this route. Herein, a type of oxygen-modified Co nanoparticles anchored graphitic carbon nanofibers catalyst (Co/GCFs) was synthesized through a two-step strategy of adsorption and pyrolysis. The Co/GCFs-2.4 exhibits high selectivity and stability for COR at neutral electrolyte. It is worth noting that unlike the water oxidation, the chemical valence of cobalt has not changed during the COR. Further results demonstrated that the oxygen-modified Co nanoparticles provide active sites for selective COR, meanwhile, the graphitic carbon gives rise to strong catalytic stability. Thanks to the superior COR and H2 production activity of Co/GCFs-2.4, a two-electrode brine electrocatalysis system employing Co/GCFs-2.4 as both cathode and anode for H2 production exhibited robust stability, efficient and high Faraday efficiency (98%-100%). We propose that this work provides a novel strategy for designing efficient and stable catalysts with electrocatalytic COR and HER activities at neutral brine water for practically coupling with H2 production by water electrolysis and brine water remediation.展开更多
This study was to examine the sedative–hypnotic effect of YZG-330 and its influence on Cl−influx in mouse cortical cells.In a sleep time-prolongation test in which mice were administered a threshold dosage of sodium ...This study was to examine the sedative–hypnotic effect of YZG-330 and its influence on Cl−influx in mouse cortical cells.In a sleep time-prolongation test in which mice were administered a threshold dosage of sodium pentobarbital(ip),YZG-330(0.125,0.5 and 2 mg/kg,po)prolonged the sleep time by 25%(P40.05),64%(Po0.01)and 506%(Po0.001),respectively.Thereafter,treatment with YZG-330 permitted mice that had woken up after the threshold dose of sodium pentobarbital(ip)to fall asleep again.A Cl−-sensitive fluorescent probe,N-(ethoxycarbonylmethyl)-methoxyquinolinium bromide(MQAE),was used to determine the effect of YZG-330 on Cl−influx.YZG-330(0.3,0.6 and 1.5 mM)increased Cl−influx in mouse cortical cells in a concentration-dependent manner.These data suggest that YZG-330 has a hypnotic effect in mice,and the effect may be related to an increase in Cl−influx in cortical cells.展开更多
Aiming at the complex corrosion degradation factors of reinforced concrete and clearing the deterioration mechanism in the constant stress state,a new type of constant current accelerated corrosion method in the salin...Aiming at the complex corrosion degradation factors of reinforced concrete and clearing the deterioration mechanism in the constant stress state,a new type of constant current accelerated corrosion method in the saline soil environment was developed.The three-dimensional paraffin isolation specimens and the three-dimensional penetration specimens were taken as the research objects,and the Cl−content and AC impedance Bode diagram were measured.The macro morphology and micro analysis were also used to evaluate the corrosion degradation laws of the two groups of specimens.A constant current three-factor system accelerated model was established for the current acceleration factor,chloride ion,and sulfate ion acceleration factor.The experimental results show that,in the constant stress test of the saline soil environmental conditions,the paraffin isolation layer can effectively isolate corrosive chloride ions,which is a brand-new research method of single factor variable control in the constant stress test.According to the basic corrosion data,the law of constant current acceleration test is summarized and divided into five corrosion degradation stages,and each stage has significant changes in the accelerated corrosion efficiency.The corrosion degradation of a constant stress test is the combined effect of constant current,positive and negative penetration of chloride ions and sulfate ions.展开更多
基金Project(51478164)supported by the National Natural Science Foundation of ChinaProject(BK20181306)supported by Natural Science Foundation of Jiangsu Province,China。
文摘The aim of this paper is to investigate the effect of nitrite intercalated Mg-Al layered double hydroxides(Mg-Al LDH-NO_(2))on mortar durability under the coexisting environment of Cl−and SO_(4)^(2-).Cl−and SO_(4)^(2-) binding properties of Mg-Al LDH-NO_(2) in simulated concrete pore solutions,Cl−and SO_(4)^(2-) diffusion properties of mortars with Mg-Al LDHNO 2 were examined.The steel corrosion and resistance of mortar against SO_(4)^(2-) attack were also evaluated.The results indicate that Mg-Al LDH-NO_(2) can effectively adsorb the Cl−and SO_(4)^(2-) in simulated concrete pore solution,and inhibit the diffusion of Cl−and SO_(4)^(2-) into cement mortars.The presence of SO_(4)^(2-) can greatly affect the uptake amount of Cl−,and there is a coupled effect of Cl−and SO_(4)^(2-) on their penetration into mortar specimens.In addition,Mg-Al LDH-NO_(2) can greatly upgrade the resistance of mortars against SO_(4)^(2-) attack and well prevent the steel from corrosion.However,Cl−will aggravate the SO_(4)^(2-) attack and SO_(4)^(2-) can initially decrease and then increase the steel corrosion.
基金The research was financially supported by the National Science and Technology Major Project of China(Grant No.2016ZX05012-001).
文摘The study aims to explore the corrosion behaviors of 13Cr steel in the high-temperature steam environment.The corrosion behaviors of 13Cr steel were tested in CO2 auxiliary steam drive environment simulated with the HTHP autoclave.The corrosion morphology and product composition were explored by SEM,EDS,XRD and XPS.The exploration results showed the corrosion rate of 13Cr steel in the high-temperature steam environment was less than 0.04 mm/a.The corrosion behaviors of 13Cr steel were mainly affected by temperature and chloride ion concentration.Temperature inhibited steam condensation and the compactness of Cr-rich layer.With the increase in temperature,more droplets were adsorbed on the surface of 13Cr steel and the compactness of the Crrich layer is worse.Chloride ions affects the activity of Fe atoms in the metal matrix.When chloride concentration increased,Fe^2+concentration in the solution and FeCO3 content in the rich-Cr layer were increased and the rich-Cr layer became looser.
基金supported by the Natural Science Foundation of China(U1803231)and the Talent Program of the Hangzhou Normal University(2016QDL020).
文摘Aims Drought and salinity are severe abiotic stress factors,which limit plant growth and productivity,particularly in desert regions.In this study,we employed two desert poplars,Populus euphratica Oliver and Populus pruinosa Schrenk seedlings,to compare their tolerance to drought,salinity and combined stress.Methods We investigated species-specific responses of P.euphratica and P.pruinosa in growth,photosynthetic capacity and pigment contents,nonstructural carbohydrate concentrations,Cl−allocation,osmotic regulation and the accumulation of reactive oxygen species(ROS)under drought,salinity and the combined stress.Important Findings Populus pruinosa exhibited greater growth inhibitory effects,photosynthesis decline,stomatal closure and ROS accumulation,and lower antioxidant enzyme activities and osmotic regulation compared with P.euphratica under drought,salinity and especially under their combined stress.On the other hand,salt-stressed P.euphratica plants restricted salt transportation from roots to leaves,and allocated more Cl−to coarse roots and less to leaves,whereas salt-stressed P.pruinosa allocated more Cl−to leaves.It was shown that there is species-specific variation in these two desert poplars,and P.pruinosa suffers greater negative effects compared with P.euphratica under drought,salinity and especially under the combined stress.Therefore,in ecological restoration and afforestation efforts,species-specific responses and tolerances of these two poplar species to drought and salinity should be considered under climate change with increasing drought and soil salinity developing.
基金Projects(51904048,51922108)supported by the National Natural Science Foundation of ChinaProject(2019JJ20031)supported by the Hunan Natural Science Foundation,ChinaProject(gjj170507)supported by the Scientific Research Foundation of Jiangxi Provincial Department of Education,China。
文摘The stability constants of Sb^5+with Cl−as well as thermodynamics of the Sb−S−Cl−H2O system were calculated.The stability constants of Sb5+with Cl−were obtained by theoretical calculations of the absorbance of a Sb5+-containing solution at different Cl^−concentrations,which was detected by spectrophotometric analysis at certain wavelengths of light(380 nm).The logarithmic values versus 10 of stability constants of Sb^5+with Cl−were 1.795,3.150,4.191,4.955,5.427 and 5.511,respectively,and partly filled the data gaps in the hydrometallurgy of antimony.The presence and distribution of pentavalent antimony compounds under different conditions were analyzed based on equilibrium calculations.Thermodynamic equilibrium calculations were performed for Sb−S−Cl−H2O system,which included the complex behavior of Sb with Cl,and the equilibrium equations of related reactions in this system were integrated into the potential−pH diagram.
基金This work was financially supported by the National Natural Science Foundation of China(No.51902312)Natural Science Foundation of Anhui Province(Nos.1908085QC139 and 1908085QB83)+4 种基金the Youth Science Fund of Anhui Agricultural University(No.2018zd25)the Science Foundation for Distinguished Young Scholars of Anhui Province(No.2008085J13)the Key research and development Project of Anhui Province(No.1804h07020148)the Fundamental Research Funds for the Central Universities(Nos.JZ2019HGBH0204 and PA2019GDPK0061)The authors thank the 1W1B station for XAFS measurement in Beijing Synchrotron Radiation Facility.
文摘Combining the H2 production with brine remediation is regarded as a sustainable approach to achieving clean H2 energy. However, designing stable Cl− oxidation reaction (COR) electrocatalyst is the key to realize this route. Herein, a type of oxygen-modified Co nanoparticles anchored graphitic carbon nanofibers catalyst (Co/GCFs) was synthesized through a two-step strategy of adsorption and pyrolysis. The Co/GCFs-2.4 exhibits high selectivity and stability for COR at neutral electrolyte. It is worth noting that unlike the water oxidation, the chemical valence of cobalt has not changed during the COR. Further results demonstrated that the oxygen-modified Co nanoparticles provide active sites for selective COR, meanwhile, the graphitic carbon gives rise to strong catalytic stability. Thanks to the superior COR and H2 production activity of Co/GCFs-2.4, a two-electrode brine electrocatalysis system employing Co/GCFs-2.4 as both cathode and anode for H2 production exhibited robust stability, efficient and high Faraday efficiency (98%-100%). We propose that this work provides a novel strategy for designing efficient and stable catalysts with electrocatalytic COR and HER activities at neutral brine water for practically coupling with H2 production by water electrolysis and brine water remediation.
基金National Natural Science Foundation of China(51904085,51904086,U20A20272)Supported by Zhuzhou Smelting Group Co.,Ltd(ZYKJ20220408003)+1 种基金Natural Science Foundation of Hebei Province(E2021402056)Science and Technology Research and Development Program of Handan City(21422101235)。
基金from National S&T Major Special Project on Major New Drug Innovation(Item Number:2012ZX09103-101-001)the National Natural Science Foundation(No.81202521).
文摘This study was to examine the sedative–hypnotic effect of YZG-330 and its influence on Cl−influx in mouse cortical cells.In a sleep time-prolongation test in which mice were administered a threshold dosage of sodium pentobarbital(ip),YZG-330(0.125,0.5 and 2 mg/kg,po)prolonged the sleep time by 25%(P40.05),64%(Po0.01)and 506%(Po0.001),respectively.Thereafter,treatment with YZG-330 permitted mice that had woken up after the threshold dose of sodium pentobarbital(ip)to fall asleep again.A Cl−-sensitive fluorescent probe,N-(ethoxycarbonylmethyl)-methoxyquinolinium bromide(MQAE),was used to determine the effect of YZG-330 on Cl−influx.YZG-330(0.3,0.6 and 1.5 mM)increased Cl−influx in mouse cortical cells in a concentration-dependent manner.These data suggest that YZG-330 has a hypnotic effect in mice,and the effect may be related to an increase in Cl−influx in cortical cells.
基金Funded by the National Natural Science Foundation of China (U21A20150,52208249,51878153,52008196,and 52178216)the National Natural Science Foundation of China Youth Science (52108219)+3 种基金the Deterioration Characteristics and Mechanisms of Cement Concrete with CWPM under Coupled Thermo-Hydro-Chemical Effect,the Youth Science and Technology Foundation of Gansu Province (22JR5RA288)the Research and Demonstration of Key Technologies of Green and Smart Highways in Gansu Province (21ZD3GA002)the Natural Science Innovation Foundation of Gansu Higher Education Institutions (2022CYZC-25)the Support from Research on Key Technologies of Durability Repair of Highway Concrete Bridges,Key Projects of Chongqing Science and Technology Bureau (cstc2021jscx-jbgs0029)。
文摘Aiming at the complex corrosion degradation factors of reinforced concrete and clearing the deterioration mechanism in the constant stress state,a new type of constant current accelerated corrosion method in the saline soil environment was developed.The three-dimensional paraffin isolation specimens and the three-dimensional penetration specimens were taken as the research objects,and the Cl−content and AC impedance Bode diagram were measured.The macro morphology and micro analysis were also used to evaluate the corrosion degradation laws of the two groups of specimens.A constant current three-factor system accelerated model was established for the current acceleration factor,chloride ion,and sulfate ion acceleration factor.The experimental results show that,in the constant stress test of the saline soil environmental conditions,the paraffin isolation layer can effectively isolate corrosive chloride ions,which is a brand-new research method of single factor variable control in the constant stress test.According to the basic corrosion data,the law of constant current acceleration test is summarized and divided into five corrosion degradation stages,and each stage has significant changes in the accelerated corrosion efficiency.The corrosion degradation of a constant stress test is the combined effect of constant current,positive and negative penetration of chloride ions and sulfate ions.
基金supported by DK 097460 from the National Institutes of Health,USA,Research Starter Award from the Pharmaceutical Research and Manufacturers of America Foundation,Seed Grant Award from the University of North Carolina Center for Functional GI&Motility Disorders,USA,National Key Research and Development Program,China(No.2016YFC1302203)Beijing Natural Science Foundation,China(No.5172006,ZLF)。
