The main goal of the present paper is to assess the available information so as to obtain a general procedure for dealing with the critical enhancement of the thermodynamic and transport properties of supercritical CO...The main goal of the present paper is to assess the available information so as to obtain a general procedure for dealing with the critical enhancement of the thermodynamic and transport properties of supercritical CO_2 and CO_2 containing binary mixtures for practical and scientific applications. The present review provides comprehensive analysis of the thermodynamic and transport properties of supercritical carbon dioxide and CO_2 containing binary mixtures(experiment and theory) and their various technological and scientific applications in different natural and industrial processes. The available information for the thermodynamic and transport properties(experiment and theory) enhancement(anomaly) of supercritical carbon dioxide and SC CO_2 + solute mixtures is comprehensively reviewed. The effect of long-range order parameter fluctuations on the thermodynamic and transport properties of supercritical fluids(SC CO_2) will be discussed. Simplified scaling type equation based on mode-coupling theory of critical dynamics with two critical amplitudes and one cutoff wave number as fluid-specific parameters was used to accurately predict of the transport properties of supercritical carbon dioxide. The recommended values of the specific parameters(asymptotic critical amplitudes) of the carbon dioxide for practical(prediction of the thermodynamic and transport properties of the supercritical CO_2 for technological applications) and scientific use were provided. The role of the critical line shapes of the carbon dioxide containing binary mixture(SC CO_2+solvent) in determination of the critical behavior of the mixture near the critical point of pure supercritical solvent(CO_2) is discussed. Krichevskii parameter concept for a description of thermodynamic behavior of dilute near-critical SC CO_2+solute mixtures is also discussed. The structural and thermodynamic properties of the carbon dioxide containing binary mixtures near the critical point of pure solvent(CO_2) are discussed.展开更多
A new lowcost apparatus used to study the character of coal combustion in place of thermograimetric analyzer was developed based on the CO2 release In order to prove the new idea, CO2 concentration of four coa...A new lowcost apparatus used to study the character of coal combustion in place of thermograimetric analyzer was developed based on the CO2 release In order to prove the new idea, CO2 concentration of four coal samples during ignition, combustion and burnout was measured by means of the apparatus developed by the authors The characters of special machanism based on the relation between the temperature and CO2 concentration (tCO2), also the derivative curve DtCO2 were obtained The change of CO2 can indirectly estimate the coal combustion characters展开更多
The overuse of antibiotics has led to the severe contamination of water bodies,posing a considerable hazard to human health.Therefore,the development of an accurate and rapid point-of-care testing(POCT)platform for th...The overuse of antibiotics has led to the severe contamination of water bodies,posing a considerable hazard to human health.Therefore,the development of an accurate and rapid point-of-care testing(POCT)platform for the quantitative detection of antibiotics is necessary.In this study,Cerium oxide(CeO_(2))and Ferrosoferric oxide(Fe_(3)O_(4))nanoparticles were simultaneously encapsulated into N-doped nanofibrous carbon microspheres to form of a novel nanozyme(CeFe-NCMzyme)with a porous structure,high surface area,and N-doped carbon material properties,leading to a considerable enhancement of the peroxidase(POD)-like activity compared with that of the CeO_(2)or Fe3O4 nanoparticles alone.The POD-like activity of CeFe-NCMzyme can be quenched using L-Cysteine(Cys)and subsequently restored by the addition of a quinolone antibiotic(norfloxacin,NOR).Therefore,CeFe-NCMzyme was used as a colorimetric sensor to detect NOR via an“On-Off”model of POD-like activity.The sensor possessed a wide linear range of 0.05–20.0μM(R^(2)=0.9910)with a detection limit of 35.70 nM.Furthermore,a smartphone-assisted POCT platform with CeFe-NCMzyme was fabricated for quantitative detection of NOR based on RGB analysis.With the use of the POCT platform,a linear range of 0.1–20.0μM and a detection limit of 54.10 nM were obtained.The spiked recoveries in the water samples were ranged from 97.73%to 102.01%,and the sensor exhibited good accuracy and acceptable reliability.This study provides a portable POCT platform for the on-site and quantitative monitoring of quinolone antibiotics in real samples,particularly in resource-constrained settings.展开更多
基金supported by Russian Foundation of Basic Research (RFBR) grants № 19-08-00056 and №18-08-00500
文摘The main goal of the present paper is to assess the available information so as to obtain a general procedure for dealing with the critical enhancement of the thermodynamic and transport properties of supercritical CO_2 and CO_2 containing binary mixtures for practical and scientific applications. The present review provides comprehensive analysis of the thermodynamic and transport properties of supercritical carbon dioxide and CO_2 containing binary mixtures(experiment and theory) and their various technological and scientific applications in different natural and industrial processes. The available information for the thermodynamic and transport properties(experiment and theory) enhancement(anomaly) of supercritical carbon dioxide and SC CO_2 + solute mixtures is comprehensively reviewed. The effect of long-range order parameter fluctuations on the thermodynamic and transport properties of supercritical fluids(SC CO_2) will be discussed. Simplified scaling type equation based on mode-coupling theory of critical dynamics with two critical amplitudes and one cutoff wave number as fluid-specific parameters was used to accurately predict of the transport properties of supercritical carbon dioxide. The recommended values of the specific parameters(asymptotic critical amplitudes) of the carbon dioxide for practical(prediction of the thermodynamic and transport properties of the supercritical CO_2 for technological applications) and scientific use were provided. The role of the critical line shapes of the carbon dioxide containing binary mixture(SC CO_2+solvent) in determination of the critical behavior of the mixture near the critical point of pure supercritical solvent(CO_2) is discussed. Krichevskii parameter concept for a description of thermodynamic behavior of dilute near-critical SC CO_2+solute mixtures is also discussed. The structural and thermodynamic properties of the carbon dioxide containing binary mixtures near the critical point of pure solvent(CO_2) are discussed.
文摘A new lowcost apparatus used to study the character of coal combustion in place of thermograimetric analyzer was developed based on the CO2 release In order to prove the new idea, CO2 concentration of four coal samples during ignition, combustion and burnout was measured by means of the apparatus developed by the authors The characters of special machanism based on the relation between the temperature and CO2 concentration (tCO2), also the derivative curve DtCO2 were obtained The change of CO2 can indirectly estimate the coal combustion characters
基金This work was financially supported by Natural Science Foundation of Jiangxi Province(Grant Nos.:20224ACB203016 and 20224BAB203022)Science and Technology Research Project of Jiangxi Provincial Department of Education(Grant No.:GJJ2201322)+1 种基金the National Natural Science Foundation of China(Grant Nos.:32060577 and 32360619)Natural Science Foundation for Distinguished Young Scholars of Hunan Province(Gtant No.:2023JJ10099).
文摘The overuse of antibiotics has led to the severe contamination of water bodies,posing a considerable hazard to human health.Therefore,the development of an accurate and rapid point-of-care testing(POCT)platform for the quantitative detection of antibiotics is necessary.In this study,Cerium oxide(CeO_(2))and Ferrosoferric oxide(Fe_(3)O_(4))nanoparticles were simultaneously encapsulated into N-doped nanofibrous carbon microspheres to form of a novel nanozyme(CeFe-NCMzyme)with a porous structure,high surface area,and N-doped carbon material properties,leading to a considerable enhancement of the peroxidase(POD)-like activity compared with that of the CeO_(2)or Fe3O4 nanoparticles alone.The POD-like activity of CeFe-NCMzyme can be quenched using L-Cysteine(Cys)and subsequently restored by the addition of a quinolone antibiotic(norfloxacin,NOR).Therefore,CeFe-NCMzyme was used as a colorimetric sensor to detect NOR via an“On-Off”model of POD-like activity.The sensor possessed a wide linear range of 0.05–20.0μM(R^(2)=0.9910)with a detection limit of 35.70 nM.Furthermore,a smartphone-assisted POCT platform with CeFe-NCMzyme was fabricated for quantitative detection of NOR based on RGB analysis.With the use of the POCT platform,a linear range of 0.1–20.0μM and a detection limit of 54.10 nM were obtained.The spiked recoveries in the water samples were ranged from 97.73%to 102.01%,and the sensor exhibited good accuracy and acceptable reliability.This study provides a portable POCT platform for the on-site and quantitative monitoring of quinolone antibiotics in real samples,particularly in resource-constrained settings.
