Using China's ground observations,e.g.,forest inventory,grassland resource,agricultural statistics,climate,and satellite data,we estimate terrestrial vegetation carbon sinks for China's major biomes between 19...Using China's ground observations,e.g.,forest inventory,grassland resource,agricultural statistics,climate,and satellite data,we estimate terrestrial vegetation carbon sinks for China's major biomes between 1981 and 2000.The main results are in the following:(1)Forest area and forest biomass car-bon(C)stock increased from 116.5×10^(6) ha and 4.3 Pg C(1 Pg C=10^(15) g C)in the early 1980s to 142.8×10^(6) ha and 5.9 Pg C in the early 2000s,respectively.Forest biomass carbon density increased form 36.9 Mg C/ha(1 Mg C=10^(6) g C)to 41.0 Mg C/ha,with an annual carbon sequestration rate of 0.075 Pg C/a.Grassland,shrub,and crop biomass sequestrate carbon at annual rates of 0.007 Pg C/a,0.014―0.024 Pg C/a,and 0.0125―0.0143 Pg C/a,respectively.(2)The total terrestrial vegetation C sink in China is in a range of 0.096―0.106 Pg C/a between 1981 and 2000,accounting for 14.6%―16.1%of carbon dioxide(CO_(2))emitted by China's industry in the same period.In addition,soil carbon sink is estimated at 0.04―0.07 Pg C/a.Accordingly,carbon sequestration by China's terrestrial ecosystems(vegetation and soil)offsets 20.8%―26.8%of its industrial CO_(2) emission for the study period.(3)Considerable uncertainties exist in the present study,especially in the estimation of soil carbon sinks,and need further intensive investigation in the future.展开更多
At present, the actual mechanism of the photoluminescence （PL） of fluorescent carbon dots （CDs） is still an open debate among researchers. Because of the variety of CDs, it is highly important to summarize the PL ...At present, the actual mechanism of the photoluminescence （PL） of fluorescent carbon dots （CDs） is still an open debate among researchers. Because of the variety of CDs, it is highly important to summarize the PL mechanism for these kinds of carbon materials; doing so can guide the development of effective synthesis routes and novel applications. This review will focus on the PL mechanism of CDs. Three types of fluorescent CDs were involved： graphene quantum dots （GQDs）, carbon nanodots （CNDs）, and polymer dots （PDs）. Four reasonable PL mechanisms have been confirmed： the quantum confinement effect or conjugated 7x-domains, which are determined by the carbon core; the surface state, which is determined by hybridization of the carbon backbone and the connected chemical groups; the molecule state, which is determined solely by the fluorescent molecules connected on the surface or interior of the CDs; and the crosslink- enhanced emission （CEE） effect. To give a thorough summary, the category and synthesis routes, as well as the chemical/physical properties for the CDs, are briefly introduced in advance.展开更多
This article reviews the progress made in CO2 separation and capture research and engineering. Various technologies, such as absorption, adsorption, and membrane separation, are thoroughly discussed. New concepts such...This article reviews the progress made in CO2 separation and capture research and engineering. Various technologies, such as absorption, adsorption, and membrane separation, are thoroughly discussed. New concepts such as chemical-looping combustion and hydrate-based separation are also introduced briefly. Future directions are suggested. Sequestration methods, such as forestation, ocean fertilization and mineral carbonation techniques are also covered. Underground injection and direct ocean dump are not covered.展开更多
The chemical characteristics（water-soluble ions and carbonaceous species） of PM2.5 in Guangzhou were measured during a typical haze episode.Most of the chemical species in PM2.5 showed significant difference between...The chemical characteristics（water-soluble ions and carbonaceous species） of PM2.5 in Guangzhou were measured during a typical haze episode.Most of the chemical species in PM2.5 showed significant difference between normal and haze days.The highest contributors to PM2.5 were organic carbon（OC）,nitrate,and sulfate in haze days and were OC,sulfate,and elemental carbon（EC） in normal days.The concentrations of secondary species such as,NO3^-,SO4^2-,and NH4^＋ in haze days were 6.5,3.9,and 5.3 times higher than those in normal days,respectively,while primary species（EC,Ca^2＋,K^＋） show similar increase from normal to haze days by a factor about 2.2-2.4.OC/EC ratio ranged from 2.8 to 6.2 with an average of 4.7 and the estimation on a minimum OC/EC ratio showed that SOC（secondary organic carbon） accounted more than 36.6% for the total organic carbon in haze days.The significantly increase in the secondary species（SOC,NO3^-,SO4^2-,and NH4^＋）,especially in NO3^-,caused the worst air quality in this region.Simultaneously,the result illustrated that the serious air pollution in haze episodes was strongly correlated with the meteorological conditions.During the sampling periods,air pollution and visibility had a good relationship with the air mass transport distance;the shorter air masses transport distance,the worse air quality and visibility in Guangzhou,indicating the strong domination of local sources contributing to haze formation.High concentration of the secondary aerosol in haze episodes was likely due to the higher oxidation rates of sulfur and nitrogen species.展开更多
基金Supported by the National Natural Science Foundation of China(Grant Nos.90211016,40638039,40228001,and 40021101)the Key MOE Research Project(Grant No.306019)
文摘Using China's ground observations,e.g.,forest inventory,grassland resource,agricultural statistics,climate,and satellite data,we estimate terrestrial vegetation carbon sinks for China's major biomes between 1981 and 2000.The main results are in the following:(1)Forest area and forest biomass car-bon(C)stock increased from 116.5×10^(6) ha and 4.3 Pg C(1 Pg C=10^(15) g C)in the early 1980s to 142.8×10^(6) ha and 5.9 Pg C in the early 2000s,respectively.Forest biomass carbon density increased form 36.9 Mg C/ha(1 Mg C=10^(6) g C)to 41.0 Mg C/ha,with an annual carbon sequestration rate of 0.075 Pg C/a.Grassland,shrub,and crop biomass sequestrate carbon at annual rates of 0.007 Pg C/a,0.014―0.024 Pg C/a,and 0.0125―0.0143 Pg C/a,respectively.(2)The total terrestrial vegetation C sink in China is in a range of 0.096―0.106 Pg C/a between 1981 and 2000,accounting for 14.6%―16.1%of carbon dioxide(CO_(2))emitted by China's industry in the same period.In addition,soil carbon sink is estimated at 0.04―0.07 Pg C/a.Accordingly,carbon sequestration by China's terrestrial ecosystems(vegetation and soil)offsets 20.8%―26.8%of its industrial CO_(2) emission for the study period.(3)Considerable uncertainties exist in the present study,especially in the estimation of soil carbon sinks,and need further intensive investigation in the future.
文摘At present, the actual mechanism of the photoluminescence （PL） of fluorescent carbon dots （CDs） is still an open debate among researchers. Because of the variety of CDs, it is highly important to summarize the PL mechanism for these kinds of carbon materials; doing so can guide the development of effective synthesis routes and novel applications. This review will focus on the PL mechanism of CDs. Three types of fluorescent CDs were involved： graphene quantum dots （GQDs）, carbon nanodots （CNDs）, and polymer dots （PDs）. Four reasonable PL mechanisms have been confirmed： the quantum confinement effect or conjugated 7x-domains, which are determined by the carbon core; the surface state, which is determined by hybridization of the carbon backbone and the connected chemical groups; the molecule state, which is determined solely by the fluorescent molecules connected on the surface or interior of the CDs; and the crosslink- enhanced emission （CEE） effect. To give a thorough summary, the category and synthesis routes, as well as the chemical/physical properties for the CDs, are briefly introduced in advance.
文摘This article reviews the progress made in CO2 separation and capture research and engineering. Various technologies, such as absorption, adsorption, and membrane separation, are thoroughly discussed. New concepts such as chemical-looping combustion and hydrate-based separation are also introduced briefly. Future directions are suggested. Sequestration methods, such as forestation, ocean fertilization and mineral carbonation techniques are also covered. Underground injection and direct ocean dump are not covered.
基金supported by the National Excellent Youth Foundation of China (No. 20625722)the China Postdoctoral Science Foundation (No. 20080430396)
文摘The chemical characteristics（water-soluble ions and carbonaceous species） of PM2.5 in Guangzhou were measured during a typical haze episode.Most of the chemical species in PM2.5 showed significant difference between normal and haze days.The highest contributors to PM2.5 were organic carbon（OC）,nitrate,and sulfate in haze days and were OC,sulfate,and elemental carbon（EC） in normal days.The concentrations of secondary species such as,NO3^-,SO4^2-,and NH4^＋ in haze days were 6.5,3.9,and 5.3 times higher than those in normal days,respectively,while primary species（EC,Ca^2＋,K^＋） show similar increase from normal to haze days by a factor about 2.2-2.4.OC/EC ratio ranged from 2.8 to 6.2 with an average of 4.7 and the estimation on a minimum OC/EC ratio showed that SOC（secondary organic carbon） accounted more than 36.6% for the total organic carbon in haze days.The significantly increase in the secondary species（SOC,NO3^-,SO4^2-,and NH4^＋）,especially in NO3^-,caused the worst air quality in this region.Simultaneously,the result illustrated that the serious air pollution in haze episodes was strongly correlated with the meteorological conditions.During the sampling periods,air pollution and visibility had a good relationship with the air mass transport distance;the shorter air masses transport distance,the worse air quality and visibility in Guangzhou,indicating the strong domination of local sources contributing to haze formation.High concentration of the secondary aerosol in haze episodes was likely due to the higher oxidation rates of sulfur and nitrogen species.
