二氧化碳(CO_(2))捕集与封存技术有利于减少CO_(2)的排放量,近年来针对CO_(2)地质封存形成了从纳米尺度到油气藏尺度的大量研究成果,大多数研究只针对单一维度多孔介质中流动行为开展研究,且物理实验方法受许多不确定性因素影响,十分耗...二氧化碳(CO_(2))捕集与封存技术有利于减少CO_(2)的排放量,近年来针对CO_(2)地质封存形成了从纳米尺度到油气藏尺度的大量研究成果,大多数研究只针对单一维度多孔介质中流动行为开展研究,且物理实验方法受许多不确定性因素影响,十分耗费时间和成本。为了从微观角度深入理解CO_(2)地质封存过程中的渗流行为,提高CO_(2)地质埋存量,基于追踪两相界面动态变化的VOF(Volume of Fluid)方法,分别建立了2D和3D模型,开展了超临界CO_(2)-水两相流动数值模拟研究,对比了不同润湿性、毛细管数、黏度比条件下的CO_(2)团簇分布特征、CO_(2)饱和度变化规律,揭示了孔隙尺度CO_(2)埋存的内在机理。研究结果表明:①随着岩石对CO_(2)润湿性增加,CO_(2)波及范围扩大,同时CO_(2)团簇的卡断频率减少,CO_(2)埋存量增加;②随着毛细管数的增加,驱替模式由毛细指进转变为稳定驱替,CO_(2)埋存量增加;③随着注入超临界CO_(2)黏度逐渐接近水的黏度,两相流体之间的流动阻力降低,促进了“润滑效应”,CO_(2)相的渗流能力提高,CO_(2)埋存量增加;④润湿性、毛细管数、黏度比在不同维度多孔介质模型中对CO_(2)饱和度的影响程度不同。结论认为,基于VOF方法的CO_(2)-水两相渗流模拟研究在孔隙尺度上揭示了CO_(2)地质封存过程中的渗流机理,对CCUS技术的发展有指导意义,也为更大尺度的CO_(2)地质封存研究提供了理论指导和技术支撑。展开更多
The design of a pressurized capillary rheometer operating at prescribed temperature is described to measure the viscosity of magnetic fluids （MFs） containing Fe3O4 magnetic nanoparticles （MNPs）. The equipment cons...The design of a pressurized capillary rheometer operating at prescribed temperature is described to measure the viscosity of magnetic fluids （MFs） containing Fe3O4 magnetic nanoparticles （MNPs）. The equipment constant of the rheometer was obtained using liquids with predetermined viscosities. Experimentally measured viscosities were used to evaluate different equations for suspension viscosities. Deviation of measured suspension viscosities from the Einstein equation was found to be basically due to the influence of spatial distribution and aggregation of Fe3O4 MNPs. By taking account of the coating layer on MNPs and the aggregation of MNPs in MFs, a modified Einstein equation was proposed to fit the experimental data. Moreover, the influence of external magnetic field on viscosity was also taken into account. Viscosities thus predicted are in good agreement with experimental data. Temperature effect on suspension viscosity was shown experimentally to be due to the shear-thinning behavior of the MFs.展开更多
以咸水层封存二氧化碳(CO_2)为研究背景,利用流体体积函数(Volume of Fluid,VOF)多相流模型建立孔隙尺度多孔介质计算模型,研究了超临界二氧化碳(Sc-CO_2)注入到含水多孔介质中的两相运移规律。对比分析了毛细管数、地质封存压力、Sc-C...以咸水层封存二氧化碳(CO_2)为研究背景,利用流体体积函数(Volume of Fluid,VOF)多相流模型建立孔隙尺度多孔介质计算模型,研究了超临界二氧化碳(Sc-CO_2)注入到含水多孔介质中的两相运移规律。对比分析了毛细管数、地质封存压力、Sc-CO_2注射温度、两相表面张力系数、接触角等因素对两相运移速率以及驱替效率的影响,同时将不同毛细管数下的驱替效率与实验数据进行了对比。研究结果表明,随着毛细管数的增大,驱替效率先减小然后趋于稳定,数值模拟与实验数据吻合良好;在同一孔隙率下,在壁面表现为亲水性时,壁面润湿性越好,驱替速率越快,但驱替效率有所下降;同时毛细管数越小、地质封存压力越低、注射温度越高、张力系数越小驱替速率越快,且驱替效率越高。展开更多
文摘二氧化碳(CO_(2))捕集与封存技术有利于减少CO_(2)的排放量,近年来针对CO_(2)地质封存形成了从纳米尺度到油气藏尺度的大量研究成果,大多数研究只针对单一维度多孔介质中流动行为开展研究,且物理实验方法受许多不确定性因素影响,十分耗费时间和成本。为了从微观角度深入理解CO_(2)地质封存过程中的渗流行为,提高CO_(2)地质埋存量,基于追踪两相界面动态变化的VOF(Volume of Fluid)方法,分别建立了2D和3D模型,开展了超临界CO_(2)-水两相流动数值模拟研究,对比了不同润湿性、毛细管数、黏度比条件下的CO_(2)团簇分布特征、CO_(2)饱和度变化规律,揭示了孔隙尺度CO_(2)埋存的内在机理。研究结果表明:①随着岩石对CO_(2)润湿性增加,CO_(2)波及范围扩大,同时CO_(2)团簇的卡断频率减少,CO_(2)埋存量增加;②随着毛细管数的增加,驱替模式由毛细指进转变为稳定驱替,CO_(2)埋存量增加;③随着注入超临界CO_(2)黏度逐渐接近水的黏度,两相流体之间的流动阻力降低,促进了“润滑效应”,CO_(2)相的渗流能力提高,CO_(2)埋存量增加;④润湿性、毛细管数、黏度比在不同维度多孔介质模型中对CO_(2)饱和度的影响程度不同。结论认为,基于VOF方法的CO_(2)-水两相渗流模拟研究在孔隙尺度上揭示了CO_(2)地质封存过程中的渗流机理,对CCUS技术的发展有指导意义,也为更大尺度的CO_(2)地质封存研究提供了理论指导和技术支撑。
基金supported by the National Natural Science Foundation of China(NNSFC,Nos.20476065 and 20736004)the Scientific Research Foundation for the Returned Overseas Chinese Scholars of State Education Ministry,the State Key Laboratory of Multiphase Reaction of the Chinese Academy of Science(No.2003-5)the Key Laboratory of Organic Synthesis of Jiangsu Province,the Chemical Experiment Center of Soochow University and R&D Foundation of Nanjing Medical University(NY0586).
文摘The design of a pressurized capillary rheometer operating at prescribed temperature is described to measure the viscosity of magnetic fluids （MFs） containing Fe3O4 magnetic nanoparticles （MNPs）. The equipment constant of the rheometer was obtained using liquids with predetermined viscosities. Experimentally measured viscosities were used to evaluate different equations for suspension viscosities. Deviation of measured suspension viscosities from the Einstein equation was found to be basically due to the influence of spatial distribution and aggregation of Fe3O4 MNPs. By taking account of the coating layer on MNPs and the aggregation of MNPs in MFs, a modified Einstein equation was proposed to fit the experimental data. Moreover, the influence of external magnetic field on viscosity was also taken into account. Viscosities thus predicted are in good agreement with experimental data. Temperature effect on suspension viscosity was shown experimentally to be due to the shear-thinning behavior of the MFs.
文摘以咸水层封存二氧化碳(CO_2)为研究背景,利用流体体积函数(Volume of Fluid,VOF)多相流模型建立孔隙尺度多孔介质计算模型,研究了超临界二氧化碳(Sc-CO_2)注入到含水多孔介质中的两相运移规律。对比分析了毛细管数、地质封存压力、Sc-CO_2注射温度、两相表面张力系数、接触角等因素对两相运移速率以及驱替效率的影响,同时将不同毛细管数下的驱替效率与实验数据进行了对比。研究结果表明,随着毛细管数的增大,驱替效率先减小然后趋于稳定,数值模拟与实验数据吻合良好;在同一孔隙率下,在壁面表现为亲水性时,壁面润湿性越好,驱替速率越快,但驱替效率有所下降;同时毛细管数越小、地质封存压力越低、注射温度越高、张力系数越小驱替速率越快,且驱替效率越高。
