In the present work,a multi-element nanoglass(m-NG)of FeCoCrMoCBY is obtained first time by the laser ablation combined with inert gas condensation(laser-IGC)technique.Compared with the conventional rapid-quenched met...In the present work,a multi-element nanoglass(m-NG)of FeCoCrMoCBY is obtained first time by the laser ablation combined with inert gas condensation(laser-IGC)technique.Compared with the conventional rapid-quenched metallic glass(MG)with identical composition,the Fe-based m-NG demonstrates a superior performance as a self-supported electrocatalyst for hydrogen evolution reaction(HER)in acidic solution.The enhanced HER activity of m-NG is proposed to be closely related to its high en-ergy states,which is originated from the unique inhomogeneous nanostructures with a high density of low-coordinated atoms.Additionally,the Fe-based m-NG exhibits an outstanding comprehensive catalytic performance even beyond the commercial Pt/C catalyst in long-term test due to its self-optimization ability.This work not only opens the way to the preparation of m-NGs by the novel laser-IGC technique,but also makes a great contribution to developing low-cost,high-efficient,and super-durable HER electrocat-alysts in acidic environment.展开更多
Efficient catalysis of functinnatized β-cyctodextrins bearing aninoatkytimino groups for atdot condensations of nitrobenzatdehydes and acetone has been effected and substantiated by preparative experiments
The nucleonic ~1S_0 superfluidity is investigated by solving the gap equation for the Reid soft-core potential as the nucleon-nucleon interaction in neutron star(NS) matter which is considered to be made up of p, e, ...The nucleonic ~1S_0 superfluidity is investigated by solving the gap equation for the Reid soft-core potential as the nucleon-nucleon interaction in neutron star(NS) matter which is considered to be made up of p, e, μ and condensed antikaon matter. We mainly study the influence of the soft pion-induced potential on the nucleonic^1S_0 pairing gaps in the above NS matter. It is found that the intensities of the nucleonic ~1S_0 pairing gaps including the soft pion-induced potential are smaller than those calculated in the case of not including the soft pion-induced potential. Furthermore, the nucleonic ~1S_0 pairing gaps with the soft pion-induced potential fall into decline with the deepening of the optical potential of antikaons in the above NS matter, whereas they increase with the parameter η for the fixed optical potential of antikaons. Due to the appearance of the soft pion-induced potential, the maximum values of nucleonic ~1S_0 pairing gaps at parameter η = 0.20,0.55 are suppressed by1.7%-6.8% with respect to the case without soft pion-induced potential in the above NS matter.展开更多
基金the support of the Karlsruhe Nano Micro Facility for the microstructure characterization.This work was supported by the National Key R&D Program of China(No.2021YFB3802800)the National Natural Science Foundation of China(Nos.52101195,12261160364,52222104,51571119)+2 种基金the Fundamental Research Funds for the Central Universities(Nos.30919011404,30920021156,30919011107)the Natural Science Foundation of Jiangsu Province(Grant No.BK20200019)T.F.acknowledges the support from the Qing Lan project and the distinguished professor project of Jiangsu province.
文摘In the present work,a multi-element nanoglass(m-NG)of FeCoCrMoCBY is obtained first time by the laser ablation combined with inert gas condensation(laser-IGC)technique.Compared with the conventional rapid-quenched metallic glass(MG)with identical composition,the Fe-based m-NG demonstrates a superior performance as a self-supported electrocatalyst for hydrogen evolution reaction(HER)in acidic solution.The enhanced HER activity of m-NG is proposed to be closely related to its high en-ergy states,which is originated from the unique inhomogeneous nanostructures with a high density of low-coordinated atoms.Additionally,the Fe-based m-NG exhibits an outstanding comprehensive catalytic performance even beyond the commercial Pt/C catalyst in long-term test due to its self-optimization ability.This work not only opens the way to the preparation of m-NGs by the novel laser-IGC technique,but also makes a great contribution to developing low-cost,high-efficient,and super-durable HER electrocat-alysts in acidic environment.
文摘Efficient catalysis of functinnatized β-cyctodextrins bearing aninoatkytimino groups for atdot condensations of nitrobenzatdehydes and acetone has been effected and substantiated by preparative experiments
基金Supported by the Open Foundation of Guizhou Provincial Key Laboratory of Radio Astronomy and Data Processingthe Youth Innovation Promotion Association of the Chinese Academy of Sciences under Grant No 2016056+1 种基金the Development Project of Science and Technology of Jilin Province under Grant No 20180520077JHthe National Natural Science Foundation of China under Grant Nos 11805022 and 11803057
文摘The nucleonic ~1S_0 superfluidity is investigated by solving the gap equation for the Reid soft-core potential as the nucleon-nucleon interaction in neutron star(NS) matter which is considered to be made up of p, e, μ and condensed antikaon matter. We mainly study the influence of the soft pion-induced potential on the nucleonic^1S_0 pairing gaps in the above NS matter. It is found that the intensities of the nucleonic ~1S_0 pairing gaps including the soft pion-induced potential are smaller than those calculated in the case of not including the soft pion-induced potential. Furthermore, the nucleonic ~1S_0 pairing gaps with the soft pion-induced potential fall into decline with the deepening of the optical potential of antikaons in the above NS matter, whereas they increase with the parameter η for the fixed optical potential of antikaons. Due to the appearance of the soft pion-induced potential, the maximum values of nucleonic ~1S_0 pairing gaps at parameter η = 0.20,0.55 are suppressed by1.7%-6.8% with respect to the case without soft pion-induced potential in the above NS matter.
