A geometric model for calculating the viscosity of multi-component melt fromrelated binary physicochemistry properties was derived based on Chou's thermodynamic geometricmodel. The model derived was employed to pr...A geometric model for calculating the viscosity of multi-component melt fromrelated binary physicochemistry properties was derived based on Chou's thermodynamic geometricmodel. The model derived was employed to predict the viscosity of Au-Ag-Cu alloys. The results showthat the calculated viscosity for Au-Ag-Cu alloys meet the experimental data very well. In addition,the viscosity of Bi-Sn-In systems was also predicted with this model.展开更多
The influence of the slip mode on the microstructure evolution and compressive flow behavior at different strains in an extruded dilute Mg−0.5Bi−0.5Sn−0.5Mn alloy was analyzed through electron backscatter diffraction,...The influence of the slip mode on the microstructure evolution and compressive flow behavior at different strains in an extruded dilute Mg−0.5Bi−0.5Sn−0.5Mn alloy was analyzed through electron backscatter diffraction,X-ray diffraction,transmission electron microscopy,and hot compression tests.The results showed that at a low strain of 0.05,the basal,pyramidaland<c+a>slip modes were simultaneously activated.Nevertheless,at the middle stage of deformation(strain of 0.1,0.2 and 0.5),theslip mode was difficult to be activated and<c+a>slip mode became dominant.The deformation process between strains of 0.2 and 0.5 was primarily characterized by the softening effect resulting from the simultaneous occurrence of continuous dynamic recrystallization and discontinuous dynamic recrystallization.Ultimately,at strain of 0.8,a dynamic equilibrium was established,with the flow stress remaining constant due to the interplay between the dynamic softening brought about by discontinuous dynamic recrystallization and the work-hardening effect induced by the activation of the basalslip mode.展开更多
The influence of micro-Ca/In alloying on the microstructural charac teristics,electrochemical behaviors and discharge properties of extruded dilute Mg-0.5Bi-0.5Sn-based(wt.%)alloys as anodes for Mg-air batteries are e...The influence of micro-Ca/In alloying on the microstructural charac teristics,electrochemical behaviors and discharge properties of extruded dilute Mg-0.5Bi-0.5Sn-based(wt.%)alloys as anodes for Mg-air batteries are evaluated.The grain size and texture intensity of the Mg-Bi-Sn-based alloys are significantly decreased after the Ca/In alloying,particularly for the In-containing alloy.Note that,in addition to nanoscale Mg_(3)Bi_(2)phase,a new microscale Mg_(2)Bi_(2)Ca phase forms in the Ca-containing alloy.The electrochemical test results demonstrate that Ca/In micro-alloying can enhance the electrochemical activity.Using In to alloy the Mg-Bi-Sn-based alloy is effective in restricting the cathodic hydrogen evolution(CHE)kinetics,leading to a low self-corrosion rate,while severe CHE occurred after Ca alloying.The micro-alloying of Ca/In to Mg-Bi-Sn-based alloy strongly deteriorates the compactness of discharge products film and mitigates the"chunk effect"(CE),hence the cell voltage,anodic efficiency as well as discharge capacity are greatly improved.The In-containing alloy exhibits outstanding discharge performance under the combined effect of the modified microstructure and discharge products,thus making it a potential anode material for primary Mg-air battery.展开更多
Through an investigation of the microstructure and mechanical properties of extruded Mg–5Bi–x Sn(BT5x, x = 0, 2, 4, and 6 wt%) alloys,this study demonstrates that the addition of Sn to an Mg–5Bi binary alloy signif...Through an investigation of the microstructure and mechanical properties of extruded Mg–5Bi–x Sn(BT5x, x = 0, 2, 4, and 6 wt%) alloys,this study demonstrates that the addition of Sn to an Mg–5Bi binary alloy significantly improves the tensile strength of the extruded alloy.All the extruded alloys exhibit a typical basal fiber texture and a partially dynamically recrystallized(DRXed) microstructure consisting of fine DRXed grains and coarse un DRXed grains. As the Sn content increases from 0 wt% to 6 wt%, the average size of the DRXed grains decreases from 4.2 to 2.8 μm owing to the increase in the amount of precipitates via their grain-boundary pinning effect. The extruded B5 and BT52 alloys contain numerous Mg_(3)Bi_(2) precipitates, but their size and number density are smaller and higher, respectively, in the latter alloy.Numerous Mg_(2)Sn precipitates as well as Mg_(3)Bi_(2)precipitates are present in the extruded BT54 and BT56 alloys, and the number density of the Mg_(2)Sn precipitates is higher in the latter alloy because of its higher Sn content. The addition of 2 wt% Sn to the B5 alloy significantly improves the yield strength(YS) and ultimate tensile strength(UTS) of the extruded alloy—by 76 and 57 MPa, respectively. This drastic improvement is the combined outcome of enhanced grain-boundary hardening, precipitation hardening, and solid-solution hardening effects induced by the refined DRXed grains, numerous precipitates, and Sn solute atoms, respectively. The further addition of 2 wt% or 4 wt% Sn to the BT52 alloy leads to moderate increments in the YS and UTS of the extruded alloy. Specifically, each addition of 2 wt% Sn increases the YS and UTS by ~26 and ~20 MPa, respectively, which is attributed mainly to the additional precipitation hardening effect induced by the Mg_(2)Sn precipitates.展开更多
The surface tension of a promising lead-free solder Au-Bi-Sn alloys was investigated both by the sessile-drop method and calculation. Experimental measurements were carried out for two cross-sections with the constant...The surface tension of a promising lead-free solder Au-Bi-Sn alloys was investigated both by the sessile-drop method and calculation. Experimental measurements were carried out for two cross-sections with the constant gold to bismuth ration of 1:1 and 1:2. For all the investigated compositions, decrease of the surface tension is observed with increasing temperature. Meanwhile, the surface tension values were also calculated based on Butler’s equation, with using the newest research on thermodynamics data of Au-Bi-Sn ternary system. Compared with the experimental results, a good agreement was obtained.展开更多
Bi2Sn2O7是一种特殊的烧绿石结构复杂氧化物,具有可见响应光催化性能,其带隙约为2.61 e V。采用水热法合成出棒状Bi2Sn2O7和颗粒组成的球形Bi2Sn2O7光催化材料,发现通过改变反应物的添加次序,可以产生不同的成核形式,从而导致产物的最...Bi2Sn2O7是一种特殊的烧绿石结构复杂氧化物,具有可见响应光催化性能,其带隙约为2.61 e V。采用水热法合成出棒状Bi2Sn2O7和颗粒组成的球形Bi2Sn2O7光催化材料,发现通过改变反应物的添加次序,可以产生不同的成核形式,从而导致产物的最终形貌不同。在可见光激发下,以罗丹明B为目标降解物进行了产物光催化性能的表征。由纳米颗粒组成的球状Bi2Sn2O7表现出更强的光催化性能,100 min时降解率达98%。通过光催化过程中的自由基淬灭反应,发现Bi2Sn2O7降解有机污染物的主要活性物种为超氧自由基和空穴。展开更多
基金This work is financially supported by the National Natural Science Foundation of China (Nos. 59674028 and 20101006).
文摘A geometric model for calculating the viscosity of multi-component melt fromrelated binary physicochemistry properties was derived based on Chou's thermodynamic geometricmodel. The model derived was employed to predict the viscosity of Au-Ag-Cu alloys. The results showthat the calculated viscosity for Au-Ag-Cu alloys meet the experimental data very well. In addition,the viscosity of Bi-Sn-In systems was also predicted with this model.
基金supported by the National Natural Science Foundation of China (No.51901153)Shanxi Scholarship Council of China (No.2019032)+2 种基金Natural Science Foundation of Shanxi Province,China (No.202103021224049)the Shanxi Zhejiang University New Materials and Chemical Research Institute Scientific Research Project,China (No.2022SX-TD025)the Open Project of Salt Lake Chemical Engineering Research Complex,Qinghai University,China (No.2023-DXSSKF-Z02)。
文摘The influence of the slip mode on the microstructure evolution and compressive flow behavior at different strains in an extruded dilute Mg−0.5Bi−0.5Sn−0.5Mn alloy was analyzed through electron backscatter diffraction,X-ray diffraction,transmission electron microscopy,and hot compression tests.The results showed that at a low strain of 0.05,the basal,pyramidaland<c+a>slip modes were simultaneously activated.Nevertheless,at the middle stage of deformation(strain of 0.1,0.2 and 0.5),theslip mode was difficult to be activated and<c+a>slip mode became dominant.The deformation process between strains of 0.2 and 0.5 was primarily characterized by the softening effect resulting from the simultaneous occurrence of continuous dynamic recrystallization and discontinuous dynamic recrystallization.Ultimately,at strain of 0.8,a dynamic equilibrium was established,with the flow stress remaining constant due to the interplay between the dynamic softening brought about by discontinuous dynamic recrystallization and the work-hardening effect induced by the activation of the basalslip mode.
基金supported by the National Natural Science Foundation of China(Grant Nos.:51901153)Shanxi Scholarship Council of China(Grant No.:2019032)+1 种基金Natural Science Foundation of Shanxi(Grant No.:202103021224049)the Science and Technology Major Project of Shanxi Province(Grant No.:20191102008,20191102007)。
文摘The influence of micro-Ca/In alloying on the microstructural charac teristics,electrochemical behaviors and discharge properties of extruded dilute Mg-0.5Bi-0.5Sn-based(wt.%)alloys as anodes for Mg-air batteries are evaluated.The grain size and texture intensity of the Mg-Bi-Sn-based alloys are significantly decreased after the Ca/In alloying,particularly for the In-containing alloy.Note that,in addition to nanoscale Mg_(3)Bi_(2)phase,a new microscale Mg_(2)Bi_(2)Ca phase forms in the Ca-containing alloy.The electrochemical test results demonstrate that Ca/In micro-alloying can enhance the electrochemical activity.Using In to alloy the Mg-Bi-Sn-based alloy is effective in restricting the cathodic hydrogen evolution(CHE)kinetics,leading to a low self-corrosion rate,while severe CHE occurred after Ca alloying.The micro-alloying of Ca/In to Mg-Bi-Sn-based alloy strongly deteriorates the compactness of discharge products film and mitigates the"chunk effect"(CE),hence the cell voltage,anodic efficiency as well as discharge capacity are greatly improved.The In-containing alloy exhibits outstanding discharge performance under the combined effect of the modified microstructure and discharge products,thus making it a potential anode material for primary Mg-air battery.
基金supported by the National Research Foundation of Korea (NRF) grant funded by the Ministry of Science, ICT and Future Planning (MSIP, South Korea) (No.2019R1A2C1085272)by the Materials and Components Technology Development Program of the Ministry of Trade, Industry and Energy (MOTIE, South Korea) (No. 20011091)。
文摘Through an investigation of the microstructure and mechanical properties of extruded Mg–5Bi–x Sn(BT5x, x = 0, 2, 4, and 6 wt%) alloys,this study demonstrates that the addition of Sn to an Mg–5Bi binary alloy significantly improves the tensile strength of the extruded alloy.All the extruded alloys exhibit a typical basal fiber texture and a partially dynamically recrystallized(DRXed) microstructure consisting of fine DRXed grains and coarse un DRXed grains. As the Sn content increases from 0 wt% to 6 wt%, the average size of the DRXed grains decreases from 4.2 to 2.8 μm owing to the increase in the amount of precipitates via their grain-boundary pinning effect. The extruded B5 and BT52 alloys contain numerous Mg_(3)Bi_(2) precipitates, but their size and number density are smaller and higher, respectively, in the latter alloy.Numerous Mg_(2)Sn precipitates as well as Mg_(3)Bi_(2)precipitates are present in the extruded BT54 and BT56 alloys, and the number density of the Mg_(2)Sn precipitates is higher in the latter alloy because of its higher Sn content. The addition of 2 wt% Sn to the B5 alloy significantly improves the yield strength(YS) and ultimate tensile strength(UTS) of the extruded alloy—by 76 and 57 MPa, respectively. This drastic improvement is the combined outcome of enhanced grain-boundary hardening, precipitation hardening, and solid-solution hardening effects induced by the refined DRXed grains, numerous precipitates, and Sn solute atoms, respectively. The further addition of 2 wt% or 4 wt% Sn to the BT52 alloy leads to moderate increments in the YS and UTS of the extruded alloy. Specifically, each addition of 2 wt% Sn increases the YS and UTS by ~26 and ~20 MPa, respectively, which is attributed mainly to the additional precipitation hardening effect induced by the Mg_(2)Sn precipitates.
基金supported by the National Natural Science Foundation of China (No. 50972010)the Fundamental Research Funds for the Central Universities (No. FRF-TP-09-021B)the Austrian Science Foundation (No. P20488-N19)
文摘The surface tension of a promising lead-free solder Au-Bi-Sn alloys was investigated both by the sessile-drop method and calculation. Experimental measurements were carried out for two cross-sections with the constant gold to bismuth ration of 1:1 and 1:2. For all the investigated compositions, decrease of the surface tension is observed with increasing temperature. Meanwhile, the surface tension values were also calculated based on Butler’s equation, with using the newest research on thermodynamics data of Au-Bi-Sn ternary system. Compared with the experimental results, a good agreement was obtained.
文摘Bi2Sn2O7是一种特殊的烧绿石结构复杂氧化物,具有可见响应光催化性能,其带隙约为2.61 e V。采用水热法合成出棒状Bi2Sn2O7和颗粒组成的球形Bi2Sn2O7光催化材料,发现通过改变反应物的添加次序,可以产生不同的成核形式,从而导致产物的最终形貌不同。在可见光激发下,以罗丹明B为目标降解物进行了产物光催化性能的表征。由纳米颗粒组成的球状Bi2Sn2O7表现出更强的光催化性能,100 min时降解率达98%。通过光催化过程中的自由基淬灭反应,发现Bi2Sn2O7降解有机污染物的主要活性物种为超氧自由基和空穴。
