为研究动力电池组内各单体电池的健康状态SOH(State of Health),对电池极化内阻和欧姆内阻特性进行分析.根据电池欧姆内阻提出相对健康状态的评价方法,并结合电池工作时内阻对端电压的影响,采用端电压对电池组内单体电池健康状态进行评...为研究动力电池组内各单体电池的健康状态SOH(State of Health),对电池极化内阻和欧姆内阻特性进行分析.根据电池欧姆内阻提出相对健康状态的评价方法,并结合电池工作时内阻对端电压的影响,采用端电压对电池组内单体电池健康状态进行评价.最后进行了对比实验验证,实验结果证明了所提方法的准确性和可行性.展开更多
The Mg-Hg-Ga alloys are widely used in high power the seawater batteries. Mg-5%Hg-5%Ga alloy was melted and heat treatments at 573-773 K were performed for different times. The electrochemical and corrosion behaviors ...The Mg-Hg-Ga alloys are widely used in high power the seawater batteries. Mg-5%Hg-5%Ga alloy was melted and heat treatments at 573-773 K were performed for different times. The electrochemical and corrosion behaviors of the Mg-5%Hg-5%Ga alloy were studied by means of potentiodynamic, galvanostatic and electrochemical impedance spectroscopy(EIS). Scanning electron microscopy(SEM), energy dispersive spectrometry(EDS) and X-ray diffractometry(XRD) were employed to characterize the microstructures of the alloy. The results demonstrate that the best electrochemical activity occurs in the Mg-5%Hg-5%Ga alloy with homogeneously dispersed Mg21Ga5Hg3 compound in α-Mg matrix. The most negative mean potential at 100 mA/cm2 polarization current density can reach -1.928 V. The largest corrosion current density 19.37 mA/cm2 of the Mg-5%Hg-5%Ga alloy appears in the Mg-5%Hg-5%Ga alloy with intergranular eutectic α-Mg and Mg21Ga5Hg3.展开更多
文摘为研究动力电池组内各单体电池的健康状态SOH(State of Health),对电池极化内阻和欧姆内阻特性进行分析.根据电池欧姆内阻提出相对健康状态的评价方法,并结合电池工作时内阻对端电压的影响,采用端电压对电池组内单体电池健康状态进行评价.最后进行了对比实验验证,实验结果证明了所提方法的准确性和可行性.
文摘The Mg-Hg-Ga alloys are widely used in high power the seawater batteries. Mg-5%Hg-5%Ga alloy was melted and heat treatments at 573-773 K were performed for different times. The electrochemical and corrosion behaviors of the Mg-5%Hg-5%Ga alloy were studied by means of potentiodynamic, galvanostatic and electrochemical impedance spectroscopy(EIS). Scanning electron microscopy(SEM), energy dispersive spectrometry(EDS) and X-ray diffractometry(XRD) were employed to characterize the microstructures of the alloy. The results demonstrate that the best electrochemical activity occurs in the Mg-5%Hg-5%Ga alloy with homogeneously dispersed Mg21Ga5Hg3 compound in α-Mg matrix. The most negative mean potential at 100 mA/cm2 polarization current density can reach -1.928 V. The largest corrosion current density 19.37 mA/cm2 of the Mg-5%Hg-5%Ga alloy appears in the Mg-5%Hg-5%Ga alloy with intergranular eutectic α-Mg and Mg21Ga5Hg3.
