The concept of“carbon neutrality”poses a huge challenge for chemical engineering and brings great opportunities for boosting the development of novel technologies to realize carbon offsetting and reduce carbon emiss...The concept of“carbon neutrality”poses a huge challenge for chemical engineering and brings great opportunities for boosting the development of novel technologies to realize carbon offsetting and reduce carbon emissions.Developing high-efficient,low-cost,energy-efficient and eco-friendly microfluidicbased microchemical engineering is of great significance.Such kind of“green microfluidics”can reduce carbon emissions from the source of raw materials and facilitate controllable and intensified microchemical engineering processes,which represents the new power for the transformation and upgrading of chemical engineering industry.Here,a brief review of green microfluidics for achieving carbon neutral microchemical engineering is presented,with specific discussions about the characteristics and feasibility of applying green microfluidics in realizing carbon neutrality.Development of green microfluidic systems are categorized and reviewed,including the construction of microfluidic devices by bio-based substrate materials and by low carbon fabrication methods,and the use of more biocompatible and nondestructive fluidic systems such as aqueous two-phase systems(ATPSs).Moreover,low carbon applications benefit from green microfluidics are summarized,ranging from separation and purification of biomolecules,high-throughput screening of chemicals and drugs,rapid and cost-effective detections,to synthesis of fine chemicals and novel materials.Finally,challenges and perspectives for further advancing green microfluidics in microchemical engineering for carbon neutrality are proposed and discussed.展开更多
We report on the transmission spectra of a sausage-like microresonator(SLM)in aqueous environment,where a fiber taper is used as a light coupler.The transmission spectra show an interesting dependence on the coupling ...We report on the transmission spectra of a sausage-like microresonator(SLM)in aqueous environment,where a fiber taper is used as a light coupler.The transmission spectra show an interesting dependence on the coupling position between the SLM and the fiber taper.When the SLM is moved along the fiber taper,the line shape can evolve periodically among symmetric dips,asymmetric Fano-like resonance line shapes,and symmetric peaks.A coupled-mode theory with feedback is developed to explain the observation.The observation of Fano-like resonance in aqueous environment holds great potential in biochemical sensing.展开更多
A new fluorescent sensor (1) for Pb2+ containing a 1,4-dicyano-2,5-bis(styryl)benzene fluorophore and 2-(N,N’-bis(carboxylmethyl))amino-1-carboxylmethoxylbenzene as receptor has been synthesized. The sensor selective...A new fluorescent sensor (1) for Pb2+ containing a 1,4-dicyano-2,5-bis(styryl)benzene fluorophore and 2-(N,N’-bis(carboxylmethyl))amino-1-carboxylmethoxylbenzene as receptor has been synthesized. The sensor selectively responds to Pb2+ in the aqueous environment, and brings about similar and significant changes in one- and two-photon excited emission spectra: λmax red-shift from 460 (519) to 590 nm. The selective response is pH-independent in a large physiological pH range, and two-photon action cross section (Φδ ) is 51 GM (1 GM = 1×10-50 cm4·s·photon-1·molecule-1) at 740 nm.展开更多
文摘为建立水样中多种有机锡化合物的快速灵敏检测方法,采用顶空固相微萃取-气质联用（HS-SPME-GCMS）技术,通过Plackett-Burman法和BoxBehnken设计优化了测定条件参数。衍生化和萃取温度、萃取时间和缓冲液p H是影响有机锡测定值的关键因素,衍生/萃取温度60℃、萃取时间30 min、缓冲液p H 4.6是测定的最佳条件。优化后的方法灵敏度高、选择性好,线性范围1~1000ng/L,回收率在82.3%~104.7%之间,相对标准偏差均小于9%,该方法适用于快速检测水环境中多种有机锡化合物。
基金the supports of the National Science Foundation of China (22008130, 22025801)the China Postdoctoral Science Foundation (2020M682124)+1 种基金the Qingdao Postdoctoral Researchers Applied Research Project Foundation (RZ2000001426)the Scientific Research Foundation for Youth Scholars from Qingdao University (DC1900014265) for this work
文摘The concept of“carbon neutrality”poses a huge challenge for chemical engineering and brings great opportunities for boosting the development of novel technologies to realize carbon offsetting and reduce carbon emissions.Developing high-efficient,low-cost,energy-efficient and eco-friendly microfluidicbased microchemical engineering is of great significance.Such kind of“green microfluidics”can reduce carbon emissions from the source of raw materials and facilitate controllable and intensified microchemical engineering processes,which represents the new power for the transformation and upgrading of chemical engineering industry.Here,a brief review of green microfluidics for achieving carbon neutral microchemical engineering is presented,with specific discussions about the characteristics and feasibility of applying green microfluidics in realizing carbon neutrality.Development of green microfluidic systems are categorized and reviewed,including the construction of microfluidic devices by bio-based substrate materials and by low carbon fabrication methods,and the use of more biocompatible and nondestructive fluidic systems such as aqueous two-phase systems(ATPSs).Moreover,low carbon applications benefit from green microfluidics are summarized,ranging from separation and purification of biomolecules,high-throughput screening of chemicals and drugs,rapid and cost-effective detections,to synthesis of fine chemicals and novel materials.Finally,challenges and perspectives for further advancing green microfluidics in microchemical engineering for carbon neutrality are proposed and discussed.
基金National Natural Science Foundation of China(NSFC)(11674059,61275215)Fujian Provincial College Funds for Distinguished Young Scientists(JA14070)+1 种基金Natural Science Foundation of Fujian Province(2016J01008,2016J01009)Open Project of Key Laboratory of Quantum Information Chinese Academy of Sciences(CAS)(KQI201601)
文摘We report on the transmission spectra of a sausage-like microresonator(SLM)in aqueous environment,where a fiber taper is used as a light coupler.The transmission spectra show an interesting dependence on the coupling position between the SLM and the fiber taper.When the SLM is moved along the fiber taper,the line shape can evolve periodically among symmetric dips,asymmetric Fano-like resonance line shapes,and symmetric peaks.A coupled-mode theory with feedback is developed to explain the observation.The observation of Fano-like resonance in aqueous environment holds great potential in biochemical sensing.
基金Supported by the National Natural Science Foundation of China (Grant Nos. 20705621 & 20706008)the National Basic Research Project of China (Grant No. 2009CB724706)+1 种基金the Ministry of Education of China, Changjiang Scholars Innovative Research Team in University (Grant No. IRT0711)Cultivation Fund of the Key Scientific and Technical Innovation Project (Grant No. 707016)
文摘A new fluorescent sensor (1) for Pb2+ containing a 1,4-dicyano-2,5-bis(styryl)benzene fluorophore and 2-(N,N’-bis(carboxylmethyl))amino-1-carboxylmethoxylbenzene as receptor has been synthesized. The sensor selectively responds to Pb2+ in the aqueous environment, and brings about similar and significant changes in one- and two-photon excited emission spectra: λmax red-shift from 460 (519) to 590 nm. The selective response is pH-independent in a large physiological pH range, and two-photon action cross section (Φδ ) is 51 GM (1 GM = 1×10-50 cm4·s·photon-1·molecule-1) at 740 nm.
