Among the current technologies for post-combustion CO2 capture,amine-based chemical absorption appears to be the most technologically mature and commercially viable method.This review highlights the opportunities and ...Among the current technologies for post-combustion CO2 capture,amine-based chemical absorption appears to be the most technologically mature and commercially viable method.This review highlights the opportunities and challenges in post-combustion CO2 capture using amine-based chemical absorption technologies.In addition,this review provides current types and emerging trends for chemical solvents.The issues and performance of amine solvents are reviewed and addressed in terms of thermodynamics,kinetics,mass transfer,regeneration and solvent management.This review also looks at emerging and future trends in post-combustion CO2 capture using chemical solvents in the near to mid-term.展开更多
At 200 ℃ and 50 mPa, the oxidative carbonylation of amines catalyzed by organic gold complexes HAuCl 4, Au(PPh 3)Cl, Au(PPh 3) 2Cl, Au(PPh 3)NO 3 and [Au(PPh 3)] 2S afforded R(NHCO 2CH 3) n with a high conversion and...At 200 ℃ and 50 mPa, the oxidative carbonylation of amines catalyzed by organic gold complexes HAuCl 4, Au(PPh 3)Cl, Au(PPh 3) 2Cl, Au(PPh 3)NO 3 and [Au(PPh 3)] 2S afforded R(NHCO 2CH 3) n with a high conversion and selectivity. The best results were obtained when using the catalyst Au(PPh 3)Cl in the presence of PPh 3. The catalytic efficiency of catalytic Au(PPh 3)Cl was compared to Pd(PPh 3) 2Cl 2, e.g. the conversion was 97.2% and selectivity was 89% when using catalyst Au(PPh 3)Cl in the presence of PPh 3, while the conversion was 98.8% and selectivity was 86% when using catalyst Pd(PPh 3) 2Cl 2 in the presence of PPh 3. The experimental results suggested that Au complexes might be promising catalysts instead of Pd catalysts for the oxidative carbonylation of amines to carbamates.展开更多
基金Supported by the National Natural Science Foundation of China(21276068,U1362112and 21376067,21476064)the National Key Technology R&D Program(2012BAC26B01)+4 种基金Innovative Research Team Development Plan of the Ministry of Education of the People's Republic of China(IRT1238)Specialized Research Fund for the Doctoral Program of Higher Education(20130161110025)Technology Development contract(Shanyan 12-34)Innovative Research Program for Graduate Student of Hunan Province,China(CX2013B158)Key project of international®ional scientific and technological cooperation of Hunan Provincial science and technology plan(2014WK2037)
文摘Among the current technologies for post-combustion CO2 capture,amine-based chemical absorption appears to be the most technologically mature and commercially viable method.This review highlights the opportunities and challenges in post-combustion CO2 capture using amine-based chemical absorption technologies.In addition,this review provides current types and emerging trends for chemical solvents.The issues and performance of amine solvents are reviewed and addressed in terms of thermodynamics,kinetics,mass transfer,regeneration and solvent management.This review also looks at emerging and future trends in post-combustion CO2 capture using chemical solvents in the near to mid-term.
文摘At 200 ℃ and 50 mPa, the oxidative carbonylation of amines catalyzed by organic gold complexes HAuCl 4, Au(PPh 3)Cl, Au(PPh 3) 2Cl, Au(PPh 3)NO 3 and [Au(PPh 3)] 2S afforded R(NHCO 2CH 3) n with a high conversion and selectivity. The best results were obtained when using the catalyst Au(PPh 3)Cl in the presence of PPh 3. The catalytic efficiency of catalytic Au(PPh 3)Cl was compared to Pd(PPh 3) 2Cl 2, e.g. the conversion was 97.2% and selectivity was 89% when using catalyst Au(PPh 3)Cl in the presence of PPh 3, while the conversion was 98.8% and selectivity was 86% when using catalyst Pd(PPh 3) 2Cl 2 in the presence of PPh 3. The experimental results suggested that Au complexes might be promising catalysts instead of Pd catalysts for the oxidative carbonylation of amines to carbamates.
