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Effects of Nickel Distribution on the Strengthening and Toughening of Alumina Ceramics 被引量:3
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作者 Mohamed.M.El-Sayed Seleman 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2008年第5期723-728,共6页
Three types of composite materials were designed and fabricated by hot pressing powder blends of alumina with 20 vol. pct nickel particles. The composites differ in the shape, size and distribution of the nickel parti... Three types of composite materials were designed and fabricated by hot pressing powder blends of alumina with 20 vol. pct nickel particles. The composites differ in the shape, size and distribution of the nickel particles. Composite microstructures are described and measurements of density, hardness, flexure strength, and fracture toughness are reported. The results showed that the fracture strength of the composite with dispersed nickel particles is higher than the other two composites (network microstructure and mixed microstructure) and the alumina matrix. For all the composites studied, tougher materials than the monolithic alumina were produced. The fracture toughness of the composite with a network microstructure is much higher than that of the other composites. The toughening mechanisms were described based on the observation of the fracture surfaces and the crack-particle interactions. Moreover, the parameters for microstructural tailoring of these materials have been deduced. The toughening of the produced composites was explained in light of the interracial bond strength. 展开更多
关键词 alumina-nickel composites nickel morphology Interfacial bonding Fracturetoughness Flexure strength
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工业用Ni/Al_2O_3催化剂的再生 被引量:4
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作者 徐国林 史克英 +2 位作者 商永臣 范业梅 徐恒泳 《应用化学》 CAS CSCD 北大核心 1995年第4期114-115,共2页
工业用Ni/Al_2O_3催化剂的再生徐国林,史克英,商永臣,范业梅,徐恒泳(哈尔滨师范大学化学系哈尔滨150080)关键词矾土负载镍,催化剂,合成气,再生镍负载型催化剂在化学工业上具有极其广泛的用途,本文提出了这类催... 工业用Ni/Al_2O_3催化剂的再生徐国林,史克英,商永臣,范业梅,徐恒泳(哈尔滨师范大学化学系哈尔滨150080)关键词矾土负载镍,催化剂,合成气,再生镍负载型催化剂在化学工业上具有极其广泛的用途,本文提出了这类催化剂再生过程中活性物种的疏活作用,... 展开更多
关键词 催化剂 再生 氧化铝
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丙烯齐聚催化剂活性中心的电子顺磁共振考察 被引量:2
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作者 阎子峰 宋林花 王秋莹 《石油学报(石油加工)》 EI CAS CSCD 北大核心 1999年第1期79-85,共7页
硅酸铝担载的镍催化剂是一类性能十分优越的丙烯齐聚催化剂。应用EPR技术系统地考察了这种催化剂在抽空、氢还原及丙烯活化等预处理条件下活性组分、价态及配位方式的变化。发现在该催化剂上丙烯齐聚反应是一个复杂过程,存在诸多反... 硅酸铝担载的镍催化剂是一类性能十分优越的丙烯齐聚催化剂。应用EPR技术系统地考察了这种催化剂在抽空、氢还原及丙烯活化等预处理条件下活性组分、价态及配位方式的变化。发现在该催化剂上丙烯齐聚反应是一个复杂过程,存在诸多反应中间体(物种Ⅴ,Ⅵ,Ⅶ等);Ni+与丙烯分子作用形成的物种[Ni(C3H6)]+导致丙烯齐聚反应诱导期的消失。 展开更多
关键词 丙烯 齐聚反应 EPR谱 硅酸铝 催化剂 顺磁共振
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