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Ce、La对Mg-Al合金力学性能影响的价电子理论研究 被引量:4
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作者 张伟 王彦春 +1 位作者 张寿庭 刘伟东 《轻金属》 CSCD 北大核心 2008年第8期51-54,58,共5页
基于EET理论,计算了Mg-Al合金中Al2Ce、Al4Ce和Al2La、Al4La的价电子结构,研究了价电子结构与合金第二相强化、高温稳定性及晶粒细化的关系。研究表明,几种第二相的最强键共价电子对数nA值远大于基体α-Mg的nA值,极大的阻碍了位错运动... 基于EET理论,计算了Mg-Al合金中Al2Ce、Al4Ce和Al2La、Al4La的价电子结构,研究了价电子结构与合金第二相强化、高温稳定性及晶粒细化的关系。研究表明,几种第二相的最强键共价电子对数nA值远大于基体α-Mg的nA值,极大的阻碍了位错运动和晶界滑移,提高了合金的强度;第二相的单位体积成键能力FV值也远大于γ-Mg17Al12相的FV值,它们的稳定性更好,有利于改善合金的高温性能;Ce、La提高了液态合金中邻近原子间键合强度,增加了基体的形核率,减缓了晶粒长大速度,进而细化了晶粒,提高合金的力学性能。 展开更多
关键词 al2ce al4ce al2La al4La MG-al合金 价电子结构 力学性能
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Effect of Cooling Rate on Microstructure and Mechanical Properties of Sand-Casted Al-5.OMg-0.6Mn-0.25Ce Alloy
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作者 Hua-Ping Tang Qu-Dong Wang +4 位作者 Chuan Lei Kui Wang Bing Ye Hai-Yan Jiang Wen-Jiang Ding 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 2019年第12期1549-1564,共16页
This study examines the relationship among cooling rate,microstructure and mechanical properties of a sand-casted Al-5.0 Mg-0.6 Mn-0.25 Ce(wt%)alloy subjected to T4 heat treatment(430℃×12 h+natural aging for 5 d... This study examines the relationship among cooling rate,microstructure and mechanical properties of a sand-casted Al-5.0 Mg-0.6 Mn-0.25 Ce(wt%)alloy subjected to T4 heat treatment(430℃×12 h+natural aging for 5 days),and the tested alloys with wall thickness varying from 5 to 50 mm were prepared.The results show that as the cooling rate increases from0.22 to 7.65 K/s,the average secondary dendritic arm spacing(SDAS,λ2)decreases from 94.8 to 27.3μm.The relation between SDAS and cooling rate can be expressed by an equation:λ2=53.0 Rc-0345.Additionally,an increase in cooling rate was shown not only to reduce the amount of the secondary phases,but also to promote the transition from Al10 Mn2 Ce toα-Al24(Mn,Fe)6Si2 phase.Tensile tests show that as the cooling rate increases from 0.22 to 7.65 K/s,the ultimate tensile strength(UTS)increases from 146.3 to 241.0 MPa and the elongation(EL)increases sharply from 4.4 to 12.2%for the ascast alloys.Relations of UTS and EL with SDAS were determined,and both the UTS and EL increase linearly with(1/λ2)0.5and that these changes can be explained by strengthening mechanisms.Most eutectic Al3Mg2 phases were dissolved during T4 treatment,which in turn further improve the YS,UTS and EL.However,the increment percent of YS,UTS and EL is affected by the cooling rate. 展开更多
关键词 al-Mg-Mn cast alloys Cooling rate MICROSTRUCTURE al10Mn2ce Mechanical properties
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