An acid molten salt was formed by means of mixing 1 -methyl- 3 -ethylimidazolium chloride with AlCl3 and LiAlCl4 at ambient temperature. The solubility of LiAlCl4 in the acid molten salt was measured. Variations of sp...An acid molten salt was formed by means of mixing 1 -methyl- 3 -ethylimidazolium chloride with AlCl3 and LiAlCl4 at ambient temperature. The solubility of LiAlCl4 in the acid molten salt was measured. Variations of specific conductivity, density and kinetic viscosity of molten salt with mole ratio o f MeEtlmCl/A1lCl3/LiAlCl4 were observed. A solubility maximum of LiAlCl4 with 5 4% in molar fraction was shown at a mole ratio of AlCl43/MeEtlmCl = 1 .2. An increase in density and viscosity, and a decrease in specific conductivity were found with increasing the concentrations of LiAlCl4 and AlCl3. The dependence of specific conductivity of this acid molten salt upon temperature was found to display Vogel-Tammanm-Fucher behavior. However, Arrhenius behavior was observed at two special mole ratios of MeEtImCl/AlCl3/LiAlCl4 = 1:1.5:0.05 and 1. 1.5:0. 10. The conductivity equations of this molten salt at various compositions were constructed. The ion interaction in the acid molten salt was studied using 7Li and 27Al nuclear magnetic resonance spectroscopic methods. The effect of concentrations of LiAlCl4 and AlCl3 on the ion interaction was also discussed.展开更多
Microstructure and tensile properties of Ti-23Al-17Nb （at%） alloy sheets rolled in （a2 ＋ B2 ＋ O） phase field with the various heat treatments were studied. Before rolling the microstructure of the billet is B2 p...Microstructure and tensile properties of Ti-23Al-17Nb （at%） alloy sheets rolled in （a2 ＋ B2 ＋ O） phase field with the various heat treatments were studied. Before rolling the microstructure of the billet is B2 phase particles embedded in O phase continuity matrix. The B2 phases are deformed more greatly than a2/O phases during the same rolling step. The （a2 ＋B2） two phase equiaxed microstrueture can be obtained by solution treatment in （a2 ＋ B2） phase field. The B2 phases become the continuous matrix by recrystallization and growing up of B2 and thus anisotropy caused by rolling can be decreased. The microstructure obtained by solution treatment has better tensile properties than the microstructure gained by subsequent aging treatment in （O＋ B2） phase field because the O phases precipitate as the block structure during aging and results in the B2 matrix continuity being broken down.展开更多
Diethylaluminum azide (DEAA) is an important compound in organoaluminum andes. But the synthesis and property of DEAA were reported a little. The DEAA is a liquid compound in literature that was synthesed by the react...Diethylaluminum azide (DEAA) is an important compound in organoaluminum andes. But the synthesis and property of DEAA were reported a little. The DEAA is a liquid compound in literature that was synthesed by the reaction of diethyl aluminum chloride (DEAC) and sodium azide. The solid product as a colorless crystal was first obtained by the reaction of DEAC and sodium azide in our work. The solid product was characterized as DEAA by IR spectrum and H NMR spectrum. The yield of crystal DEAA was increased as NaN3/DEAC (mol/mol) increased. When NaN3/DEAC = 1. 3 the yield of DEAA is increased from 74% in literature to 83%. The melting point of DEAA is 28 - 29℃ that was determined with two methods in the work. The DEAA containing trace DEAC (about 0. 2% of DEAC) is liquid which has been full proved by varied tests in this paper. The melting point of DEAA is - 130℃ in literature because the DEAA is not pure that may contain DEAC. The - 130℃ may be eutectic point of eutectic mixture forming of DEAA and DEAC. 27,Al NMR of DEAA is determined. At δ = 6. 4 there is a peak that 1/2 of the peak is 834Hz. The structure of crystal DEAA is inferred from 27Al NMR.展开更多
文摘An acid molten salt was formed by means of mixing 1 -methyl- 3 -ethylimidazolium chloride with AlCl3 and LiAlCl4 at ambient temperature. The solubility of LiAlCl4 in the acid molten salt was measured. Variations of specific conductivity, density and kinetic viscosity of molten salt with mole ratio o f MeEtlmCl/A1lCl3/LiAlCl4 were observed. A solubility maximum of LiAlCl4 with 5 4% in molar fraction was shown at a mole ratio of AlCl43/MeEtlmCl = 1 .2. An increase in density and viscosity, and a decrease in specific conductivity were found with increasing the concentrations of LiAlCl4 and AlCl3. The dependence of specific conductivity of this acid molten salt upon temperature was found to display Vogel-Tammanm-Fucher behavior. However, Arrhenius behavior was observed at two special mole ratios of MeEtImCl/AlCl3/LiAlCl4 = 1:1.5:0.05 and 1. 1.5:0. 10. The conductivity equations of this molten salt at various compositions were constructed. The ion interaction in the acid molten salt was studied using 7Li and 27Al nuclear magnetic resonance spectroscopic methods. The effect of concentrations of LiAlCl4 and AlCl3 on the ion interaction was also discussed.
文摘Microstructure and tensile properties of Ti-23Al-17Nb （at%） alloy sheets rolled in （a2 ＋ B2 ＋ O） phase field with the various heat treatments were studied. Before rolling the microstructure of the billet is B2 phase particles embedded in O phase continuity matrix. The B2 phases are deformed more greatly than a2/O phases during the same rolling step. The （a2 ＋B2） two phase equiaxed microstrueture can be obtained by solution treatment in （a2 ＋ B2） phase field. The B2 phases become the continuous matrix by recrystallization and growing up of B2 and thus anisotropy caused by rolling can be decreased. The microstructure obtained by solution treatment has better tensile properties than the microstructure gained by subsequent aging treatment in （O＋ B2） phase field because the O phases precipitate as the block structure during aging and results in the B2 matrix continuity being broken down.
文摘Diethylaluminum azide (DEAA) is an important compound in organoaluminum andes. But the synthesis and property of DEAA were reported a little. The DEAA is a liquid compound in literature that was synthesed by the reaction of diethyl aluminum chloride (DEAC) and sodium azide. The solid product as a colorless crystal was first obtained by the reaction of DEAC and sodium azide in our work. The solid product was characterized as DEAA by IR spectrum and H NMR spectrum. The yield of crystal DEAA was increased as NaN3/DEAC (mol/mol) increased. When NaN3/DEAC = 1. 3 the yield of DEAA is increased from 74% in literature to 83%. The melting point of DEAA is 28 - 29℃ that was determined with two methods in the work. The DEAA containing trace DEAC (about 0. 2% of DEAC) is liquid which has been full proved by varied tests in this paper. The melting point of DEAA is - 130℃ in literature because the DEAA is not pure that may contain DEAC. The - 130℃ may be eutectic point of eutectic mixture forming of DEAA and DEAC. 27,Al NMR of DEAA is determined. At δ = 6. 4 there is a peak that 1/2 of the peak is 834Hz. The structure of crystal DEAA is inferred from 27Al NMR.
