分别在南京的两个钢铁厂收集降尘并采集周边表土,并用ICP-AES和磁化率仪分析得到16种元素含量和表土、地面尘的磁化率。结果表明,两个钢铁工业区的大气降尘的年沉降通量分别为190t km-2a-1和407 t km-2a-1,这可能会影响着周边地区土壤...分别在南京的两个钢铁厂收集降尘并采集周边表土,并用ICP-AES和磁化率仪分析得到16种元素含量和表土、地面尘的磁化率。结果表明,两个钢铁工业区的大气降尘的年沉降通量分别为190t km-2a-1和407 t km-2a-1,这可能会影响着周边地区土壤的形成;Al、K、Na、Ti、V在降尘中的含量显著低于表土,而Ca,Fe,Zn,Mn,Pb,Cu在降尘中含量要显著高于表土;表土的磁化率除水田外均大于100×10-8m3kg-1,并且地面尘的磁化率要远远高于表土的磁化率。研究表明,钢铁工业区降尘对其周边土壤中污染元素的积累有明显影响,突出地表现在土壤表层重金属含量升高,而磁化率可以很好地表征这种表聚的特点。展开更多
This study analyzed the concentrations and chemical forms of Zn,Cu,Pb,Sb,Cd and Mn in airborne particles,road dusts and soils collected along three expressways in Jiangxi Province,China,with different traffic densitie...This study analyzed the concentrations and chemical forms of Zn,Cu,Pb,Sb,Cd and Mn in airborne particles,road dusts and soils collected along three expressways in Jiangxi Province,China,with different traffic densities,and identified the levels and sources of heavy metal contamination.The concentrations of Zn,Cu,Pb,Sb,and Cd except Mn in airborne particles,road dusts and soils were all in direct proportion to traffic volume.Cd concentrations were low compared with other metals.For instance,the concentrations of Zn,Cu,Pb,Sb,Mn and Cd were 6.6,0.7,2.2,0.1,0.1 and 0.1μg·m-3in PM10along the Changjiu Expressway,792.8,241.4,248.3,9.6,340.5and 8.0 mg·kg-1in road dusts,and 201.1,143.2,59.5,9.5,338.9 and 2.3 mg·kg-1in soils,respectively,but in the case of the ratio of concentration to the environmental background value,most serious contamination was caused by Cd.The sources of the heavy metals were judged by comparisons of the chemical forms of the heavy metals in different environmental media.Pb and Mn in airborne particles were both derived from traffic;Pb in road dusts and soils resulted mainly from the use of leaded gasoline in the past;and Mn in road dusts and soils was derived from parent rocks.Zn,Cu,Sb and Cd in airborne particles,road dusts and soils were derived primarily from traffic,and differences in chemical forms of the heavy metals in different media were due to the interaction between heavy metals in airborne particles and organic matter and other surfaces in road dusts and soils.We also discussed the change of chemical forms of heavy metals in particles of different sizes and under different weather conditions.Bioavailability of heavy metals in airborne particles was much higher than that in road dusts and soils,especially Pb(0.676 in airborne particles,0.159 in road dusts and 0.095 in soils).展开更多
文摘分别在南京的两个钢铁厂收集降尘并采集周边表土,并用ICP-AES和磁化率仪分析得到16种元素含量和表土、地面尘的磁化率。结果表明,两个钢铁工业区的大气降尘的年沉降通量分别为190t km-2a-1和407 t km-2a-1,这可能会影响着周边地区土壤的形成;Al、K、Na、Ti、V在降尘中的含量显著低于表土,而Ca,Fe,Zn,Mn,Pb,Cu在降尘中含量要显著高于表土;表土的磁化率除水田外均大于100×10-8m3kg-1,并且地面尘的磁化率要远远高于表土的磁化率。研究表明,钢铁工业区降尘对其周边土壤中污染元素的积累有明显影响,突出地表现在土壤表层重金属含量升高,而磁化率可以很好地表征这种表聚的特点。
文摘This study analyzed the concentrations and chemical forms of Zn,Cu,Pb,Sb,Cd and Mn in airborne particles,road dusts and soils collected along three expressways in Jiangxi Province,China,with different traffic densities,and identified the levels and sources of heavy metal contamination.The concentrations of Zn,Cu,Pb,Sb,and Cd except Mn in airborne particles,road dusts and soils were all in direct proportion to traffic volume.Cd concentrations were low compared with other metals.For instance,the concentrations of Zn,Cu,Pb,Sb,Mn and Cd were 6.6,0.7,2.2,0.1,0.1 and 0.1μg·m-3in PM10along the Changjiu Expressway,792.8,241.4,248.3,9.6,340.5and 8.0 mg·kg-1in road dusts,and 201.1,143.2,59.5,9.5,338.9 and 2.3 mg·kg-1in soils,respectively,but in the case of the ratio of concentration to the environmental background value,most serious contamination was caused by Cd.The sources of the heavy metals were judged by comparisons of the chemical forms of the heavy metals in different environmental media.Pb and Mn in airborne particles were both derived from traffic;Pb in road dusts and soils resulted mainly from the use of leaded gasoline in the past;and Mn in road dusts and soils was derived from parent rocks.Zn,Cu,Sb and Cd in airborne particles,road dusts and soils were derived primarily from traffic,and differences in chemical forms of the heavy metals in different media were due to the interaction between heavy metals in airborne particles and organic matter and other surfaces in road dusts and soils.We also discussed the change of chemical forms of heavy metals in particles of different sizes and under different weather conditions.Bioavailability of heavy metals in airborne particles was much higher than that in road dusts and soils,especially Pb(0.676 in airborne particles,0.159 in road dusts and 0.095 in soils).
