Lithium(Li)metal is considered as one of the most promising anode materials for next-generation high-energy-density storage systems.However,the practical application of Li metal anode is hindered by interfacial instab...Lithium(Li)metal is considered as one of the most promising anode materials for next-generation high-energy-density storage systems.However,the practical application of Li metal anode is hindered by interfacial instability and air instability due to the highly reactivity of Li metal.Unstable interface in Li metal batteries(LMBs)directly dictates Li dendrite growth,“dead Li”and low Coulombic efficiency,resulting in inferior electrochemical performance of LMBs and even safety issues.In addition,its sensitivity to ambient air leads to the severe corrosion of Li metal anode,high requirements of production and storage,and increased manufacturing cost.Plenty of efforts in recent years have overcome many bottlenecks in these fields and hastened the practical applications of high-energy-density LMBs.In this review,we focus on emerging methods of these two aspects to fulfill a stable and low cost electrode.In this perspective,design artificial solid electrolyte interphase(SEI)layers,construct three-dimensional conductive current collectors,optimize electrolytes,employ solid-state electrolytes,and modify separators are summarized to be propitious to ameliorate interfacial stability.Meanwhile,ex situ/in situ formed protective layers are highlighted in favor of heightening air stability.Finally,several possible directions for the future research on advanced Li metal anode are addressed.展开更多
Based on meteorological sounding data in 2011 -2014 and air pollution data in 2013 and 2014 from an environmental monitoring station in Xingtai City, the characteristics of inversion layer and air pollution and their ...Based on meteorological sounding data in 2011 -2014 and air pollution data in 2013 and 2014 from an environmental monitoring station in Xingtai City, the characteristics of inversion layer and air pollution and their correlation in Xingtai City were discussed. The results show that term perature inversion was very serious at 07：00 in Xingtai City, and days with temperature inversion accounted for above 90%. There were obvious seasonal variations in air pollution in Xingtai City, and air pollution was the most serious in winter but the slightest in summer. The primary air pollu- tants in Xingtai City are PM10 and PM2.5, and the primary air pollutants and AQI had close correlation with parameters of inversion layer. Stable ground inversion layer could hinder air convection and air capacity, so that air pollution become more serious with the discharge of pollutants. Inversion layer nearly appearing all the year around is an important meteorological reason for serious air pollution in Xingtai City.展开更多
基金National Natural Science Foundation of China(51772272)Natural Science Funds for Distinguished Young Scholar of Zhejiang Province(LR20E020001)+2 种基金China Postdoctoral Science Foundation(2020M671785 and 2020T130597)Natural Science Foundation of Zhejiang Province(LY18E020009,LY21E020005,and 2020C01130)the Foundation of State Key Laboratory of Coal Conversion(J20-21-909).
文摘Lithium(Li)metal is considered as one of the most promising anode materials for next-generation high-energy-density storage systems.However,the practical application of Li metal anode is hindered by interfacial instability and air instability due to the highly reactivity of Li metal.Unstable interface in Li metal batteries(LMBs)directly dictates Li dendrite growth,“dead Li”and low Coulombic efficiency,resulting in inferior electrochemical performance of LMBs and even safety issues.In addition,its sensitivity to ambient air leads to the severe corrosion of Li metal anode,high requirements of production and storage,and increased manufacturing cost.Plenty of efforts in recent years have overcome many bottlenecks in these fields and hastened the practical applications of high-energy-density LMBs.In this review,we focus on emerging methods of these two aspects to fulfill a stable and low cost electrode.In this perspective,design artificial solid electrolyte interphase(SEI)layers,construct three-dimensional conductive current collectors,optimize electrolytes,employ solid-state electrolytes,and modify separators are summarized to be propitious to ameliorate interfacial stability.Meanwhile,ex situ/in situ formed protective layers are highlighted in favor of heightening air stability.Finally,several possible directions for the future research on advanced Li metal anode are addressed.
基金Supported by the Government Science and Technology Planning Project of Xingtai City,Hebei Province,China(2014ZZ006-1)Scientific Research and Development Project of Hebei Meteorological Bureau(14ky29)
文摘Based on meteorological sounding data in 2011 -2014 and air pollution data in 2013 and 2014 from an environmental monitoring station in Xingtai City, the characteristics of inversion layer and air pollution and their correlation in Xingtai City were discussed. The results show that term perature inversion was very serious at 07：00 in Xingtai City, and days with temperature inversion accounted for above 90%. There were obvious seasonal variations in air pollution in Xingtai City, and air pollution was the most serious in winter but the slightest in summer. The primary air pollu- tants in Xingtai City are PM10 and PM2.5, and the primary air pollutants and AQI had close correlation with parameters of inversion layer. Stable ground inversion layer could hinder air convection and air capacity, so that air pollution become more serious with the discharge of pollutants. Inversion layer nearly appearing all the year around is an important meteorological reason for serious air pollution in Xingtai City.
