A series of samples of hexagonal boron nitride-aluminum nitride ceramic composites with different amounts of CaF2 as sintering aid were prepared by spark plasma sintered at 1700-1850 ℃ for 5 min.The addition of CaF2 ...A series of samples of hexagonal boron nitride-aluminum nitride ceramic composites with different amounts of CaF2 as sintering aid were prepared by spark plasma sintered at 1700-1850 ℃ for 5 min.The addition of CaF2 effectively lowered the sintering temperature and promoted the densification of AlN-BN composites.With the increase of sintering temperature,the density increased,and the contiguity of AlN grains enhanced in AlN-BN composites.Thermal conductivity of AlN-BN composites increased with the increase in CaF2 content and sintering temperature,and there is a maximum value of 78.6 W·m^-1·K^-1 when the sample with 3wt% CaF2 sintered at 1800 ℃.展开更多
基金Funded by New Century Excellent Talents in University of the Ministry of Education of China (No. NCET-04-0722)Doctoral Fund of Ministry of Education of China (No. 20060497003)
文摘A series of samples of hexagonal boron nitride-aluminum nitride ceramic composites with different amounts of CaF2 as sintering aid were prepared by spark plasma sintered at 1700-1850 ℃ for 5 min.The addition of CaF2 effectively lowered the sintering temperature and promoted the densification of AlN-BN composites.With the increase of sintering temperature,the density increased,and the contiguity of AlN grains enhanced in AlN-BN composites.Thermal conductivity of AlN-BN composites increased with the increase in CaF2 content and sintering temperature,and there is a maximum value of 78.6 W·m^-1·K^-1 when the sample with 3wt% CaF2 sintered at 1800 ℃.