BaBa1.03Ce0.8Tm0.2O3-aceramic with orthorhombic perovskite structure was prepared by conventional solid-state reaction. The conductivity and ionic transport number of BaBa1.03Ce0.8Tm0.2O3-a a were measured by ac imped...BaBa1.03Ce0.8Tm0.2O3-aceramic with orthorhombic perovskite structure was prepared by conventional solid-state reaction. The conductivity and ionic transport number of BaBa1.03Ce0.8Tm0.2O3-a a were measured by ac impedance spectroscopy and gas concentration cell methods in the temperature range of 500-900 ℃ in wet hydrogen and wet air. Using the ceramic as solid electrolyte and porous platinum as electrodes, the hydrogen-air fuel cell was constructed, and the cell performance was examined at 500-900℃. The results indicate that the specimen is a pure ionic conductor with the ionic transport number of 1 at 500-900 ℃ in wet hydrogen. In wet air, the specimen is a mixed conductor of proton, oxide ion and electron hole. The protonic transport numbers are 0.071-0.018, and the oxide ionic transport numbers are 0.273-0.365. The conductivities of Bal.03Ceo.sTmo.203 a under wet hydrogen, wet air or fuel cell atmosphere are higher than those of BaBa1.03Ce0.8Tm0.2O3-a a （RE=Y, Eu, Ho） reported previously by us. The fuel cell can work stably. At 900℃ the maximum power output density is 122.7 mWocm 2, which is higher than that of our previous cell using BaBa1.03Ce0.8Tm0.2O3-a（RE=Y, Eu, Ho） as electrolyte.展开更多
The perovskite-type oxide solid solution Ba0.98Ce0.8Tm0.2O3-α was prepared by high temperature solid-state reaction and its single phase character was confirmed by X-ray diffraction. The conduction property of the sa...The perovskite-type oxide solid solution Ba0.98Ce0.8Tm0.2O3-α was prepared by high temperature solid-state reaction and its single phase character was confirmed by X-ray diffraction. The conduction property of the sample was investigated by alternating current impedance spectroscopy and gas concentration cell methods under different gases atmospheres in the temperature range of 500-900 ℃. The performance of the hydrogen-air fuel cell using the sample as solid electrolyte was measured. In wet hydrogen, the sample is a pure protonic conductor with the protonic transport number of 1 in the range of 500-600 ℃, a mixed conductor of proton and electron with the protonic transport number of 0.945-0.933 above 600 ℃. In wet air, the sample is a mixed conductor of proton, oxide ion, and electronic hole. The protonic transport numbers are 0.010-0.021, and the oxide ionic transport numbers are 0.471-0.382. In hydrogen-air fuel cell, the sample is a mixed conductor of proton, oxide ion and electron, the ionic transport numbers are 0.942 0.885. The fuel cell using Ba0.98Ce0.8Tm0.2O3-α as solid electrolyte can work stably. At 900 ℃, the maximum power output density is 110,2 mW/cm2, which is higher than that of our previous cell using Ba0.98Ce0.8Tm0.2O3-α （x〈≤1, RE=Y, Eu, Ho） as solid electrolyte.展开更多
基金Project supported by the National Natural Science Foundation of China （No. 20771079）, Qing Lan Project and the Natural Science Foundation of Education Department of Jiangsu Province （No. 07KJB 150126）.
文摘BaBa1.03Ce0.8Tm0.2O3-aceramic with orthorhombic perovskite structure was prepared by conventional solid-state reaction. The conductivity and ionic transport number of BaBa1.03Ce0.8Tm0.2O3-a a were measured by ac impedance spectroscopy and gas concentration cell methods in the temperature range of 500-900 ℃ in wet hydrogen and wet air. Using the ceramic as solid electrolyte and porous platinum as electrodes, the hydrogen-air fuel cell was constructed, and the cell performance was examined at 500-900℃. The results indicate that the specimen is a pure ionic conductor with the ionic transport number of 1 at 500-900 ℃ in wet hydrogen. In wet air, the specimen is a mixed conductor of proton, oxide ion and electron hole. The protonic transport numbers are 0.071-0.018, and the oxide ionic transport numbers are 0.273-0.365. The conductivities of Bal.03Ceo.sTmo.203 a under wet hydrogen, wet air or fuel cell atmosphere are higher than those of BaBa1.03Ce0.8Tm0.2O3-a a （RE=Y, Eu, Ho） reported previously by us. The fuel cell can work stably. At 900℃ the maximum power output density is 122.7 mWocm 2, which is higher than that of our previous cell using BaBa1.03Ce0.8Tm0.2O3-a（RE=Y, Eu, Ho） as electrolyte.
文摘The perovskite-type oxide solid solution Ba0.98Ce0.8Tm0.2O3-α was prepared by high temperature solid-state reaction and its single phase character was confirmed by X-ray diffraction. The conduction property of the sample was investigated by alternating current impedance spectroscopy and gas concentration cell methods under different gases atmospheres in the temperature range of 500-900 ℃. The performance of the hydrogen-air fuel cell using the sample as solid electrolyte was measured. In wet hydrogen, the sample is a pure protonic conductor with the protonic transport number of 1 in the range of 500-600 ℃, a mixed conductor of proton and electron with the protonic transport number of 0.945-0.933 above 600 ℃. In wet air, the sample is a mixed conductor of proton, oxide ion, and electronic hole. The protonic transport numbers are 0.010-0.021, and the oxide ionic transport numbers are 0.471-0.382. In hydrogen-air fuel cell, the sample is a mixed conductor of proton, oxide ion and electron, the ionic transport numbers are 0.942 0.885. The fuel cell using Ba0.98Ce0.8Tm0.2O3-α as solid electrolyte can work stably. At 900 ℃, the maximum power output density is 110,2 mW/cm2, which is higher than that of our previous cell using Ba0.98Ce0.8Tm0.2O3-α （x〈≤1, RE=Y, Eu, Ho） as solid electrolyte.
